自1950年代開始，Karl Ziegler與Giulio Natta兩位教授開啟了配位聚合反應研究領域的大門，該學門便成為化學家們一個重要的研究題目。緊接著在1963年，這兩位教授便因為在該領域的貢獻，獲得了諾貝爾化學獎的殊榮。由Wilhelm Keim 教授與殼牌公司合作研發的SHOP製程(shell higher olefin process, SHOP)，則是另一項在聚合物化學領域裡面相當傑出的研究，該製程給了我們一個很好的烯烴寡聚物合成方法。
本實驗室的研究團隊亦致力於SHOP催化劑的開發。我們以亞胺基磷偶極體進行開發，期許合成出含有雙牙胺基膦配位基的催化劑。目前亞胺基磷偶極體之合成已經完成，新化學物質亦接受不同核種的核磁共振光譜儀進行鑑定。胺基膦鎳錯合物的合成與該錯合物的烯烴聚合反應催化活性測試尚在進行中。

Since the research field of coordination polymerization was initiated in 1950s by Karl Ziegler and Giulio Natta, it becomes an important topic for chemists. Then Ziegler and Natta were honored by Nobel Prize of chemistry in 1963. Shell Higher Olefin Process (SHOP), discovered by Wilhelm Keim, is another outstanding research for polymer chemistry. SHOP gives a good pathway to synthesize olefin oligomers.
In our group, we make effort on another type of SHOP catalyst containing a bidentate amido phosphine ligand which derived from ylides. Synthesis of new ylides was finished. These new chemicals were characterized by multiple NMR spectra. The synthesis of amido phosphine Ni(II) complexes and catalytic activity test on olefin polymerization are underway.

緒論: 1
圖一、SHOP催化劑進行烯烴聚合反應之反應機構 2
結果與討論: 3
圖二、SHOP催化劑的配位基改變 4
實驗部分： 6
一、 一般程序： 6
二、實驗儀器： 6
三、實驗步驟： 6
合成Prop-2-ynyltriphenylphosphonium Bromide9,10 [YWC 2-8] 6
合成2,6-Bis(diphenylmethyl)-4-methylaniline11 [YWC 2-11] 7
合成2,6-Bis(diphenylmethyl)-4methoxyaniline11 [YWC 2-12] 7
合成2-(2,6-Bis(diphenylmethyl)-4-methylanilino)-prop-1-enyltriphenylphosphonium Bromide (1a) [YWC 2-15] 8
合成2-(2,6-Bis(diphenylmethyl)-4-methoxyanilino)-prop-1-enyltriphenylphosphonium Bromide (1b) [YWC 2-16] 9
Deprotonation of 2-(2,6-Bis(diphenylmethyl)-4-methylanilino)-prop-1-enyltriphenylphosphonium Bromide (2a) [YWC 2-28] 9
Deprotonation of 2-(2,6-Bis(diphenylmethyl)-4-methoxyanilino)-prop-1-enyltriphenylphosphonium Bromide (2b) [YWC 2-29] 10
結論 11
參考文獻: 12

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