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博碩士論文 etd-0116115-134330 詳細資訊
Title page for etd-0116115-134330
論文名稱
Title
利用高級氧化法調理與板框式壓濾電脫水技術提升 都市下水污泥之脫水成效
Enhanced Dewatering of Municipal Sewage Sludge by Application of Advanced-Oxidation Conditioning and Plate-and-Frame Filter Press Electrodewatering
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
127
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2015-01-29
繳交日期
Date of Submission
2015-02-16
關鍵字
Keywords
污泥化學調理、都市下水污泥、高級氧化法、過氧化氫、電脫水、過硫酸鈉、板框式壓濾脫水機
Plate and frame filter press, Electrodewatering, Hydrogen peroxide, Sodium persulfate, Sludge conditioning, Advanced oxidation processes, Biological municipal sludge
統計
Statistics
本論文已被瀏覽 5660 次,被下載 62
The thesis/dissertation has been browsed 5660 times, has been downloaded 62 times.
中文摘要
本研究嘗試利用硫酸亞鐵催化/活化過氧化氫或過硫酸鈉調理都市下水污泥,並結合電動力輔助板框式壓濾脫水系統進行脫水以提升污泥脫水成效,評估的要點包括:最終污泥餅含水率、污泥進樣量、電動力及污泥餅最終處置費用。試驗結果顯示,利用硫酸亞鐵催化/活化過氧化氫及過硫酸鈉調理都市下水生物污泥對於污泥脫水具有良好之成效,其毛細汲取時間(CST)及過濾比阻(SRF)分別降為原來數值之9%、11%及7%、6%,且在板框式壓濾脫水下,其污泥餅之含水率可分別下降到45%及55%。此外,不論使用過氧化氫或過硫酸鈉進行二次調理,在使用電動力輔助板框式壓濾脫水機之情況之下,其污泥進樣量都有明顯的提升,可達到提升處理量之效果。尤其在上述二種調理方式的最佳試驗組別(最終污泥餅含水率最低)之驗證試驗組別中,其都市下水生物污泥之最終污泥餅含水率分別為42%及47%,能耗則分別為14.69 kWh/ton及13.43 kWh/ton,此結果相較於前人之研究使用絮凝劑並結合板框式壓濾電脫水之試驗,其最終污泥含水率為62.62%,而其能耗為34.98 kWh/ton,本研究之含水率及能耗相對較低。綜合言之,本研究利用高級氧化程序調理結合電動力輔助板框式壓濾脫水機之試驗結果證明,利用高級氧化調理程序可明顯提升脫水之能力,並且施加電場更可以加速污泥脫水效率,得到較大的處理量,可謂同時具有技術及經濟可行性。
Abstract
The objective of this study was to condition the biological municipal sludge by using hydrogen peroxide or sodium persulfate catalyzed with persulfate, and combine the Plate-and-Frame filter press electro dewatering to evaluate the dewatering performance. The final the moisture contents of sludge cakes, sample size, electric field and the costs of sludge cake were also analyzed. The results showed that under the Plate-and-Frame filter press dewatering, the moisture contents of sludge cakes were decreasing to 45% and 55% conditioning by hydrogen peroxide and sodium persulfate respectively, and the CST of the biological municipal sludge were decreasing to 9% and 11%, and the SRF were decreasing to 7% and 6% respectively. In addition, the injection sample size and treating capacity was also increasing by uisng the Plate-and-Frame filter press electro dewatering, and the the moisture contents of sludge cakes were decreasing to 42% and 47% conditioning by hydrogen peroxide and sodium persulfate. The corresponding energy consumptions were determined to be 14.69 kWh/ton and 13.43 kWh/ton, respectively. To summarize, it was obvious that dewatering efficiencies of biological municipal sludge increased by using advanced oxidation processes, and when an electric field was applied, the dewatering efficiencies and the treating capacity also increasd. It appeared that the electrodewatering process employed in this study was technically and economically feasible for biological sludges.
目次 Table of Contents
謝誌 iii
摘要 iv
Abstract v
目錄 vi
圖目錄 x
表目錄 xiv
照片目錄 xv
第一章 前言 1
1.1 研究緣起 1
1.2研究目的 2
1.3 研究內容規劃與架構 3
第二章 文獻回顧 6
2.1 生物污泥的產生 7
2.2 生物污泥的水份分佈 8
2.3.1 生物調理(Biological Conditioning) 11
2.3.2 化學調理(Chemical Conditioning) 11
2.3.3 物理調理(Physical Conditioning) 12
2.4 高級氧化程序(Advanced Oxidation Process) 14
2.5 高級氧化調理(Advanced-Oxidation Conditioning) 20
2.6 污泥脫水程序 23
2.6.1傳統式污泥脫水機 23
2.6.2改良式污泥脫水方法 24
2.7電動力法 26
2.7.1電動力現象與原理 27
2.7.2 電滲透脫水 30
第三章 研究設備材料與方法 34
3.1 生物污泥來源 34
3.2 實驗材料與方法 35
3.2.1 實驗材料 35
3.2.2 實驗設備 36
3.2.3 電動力輔助板框式壓濾脫水系統 39
3.3研究內容 40
3.3.1 污泥調理 40
3.3.1.1 過濾比阻 (Specific Resistance to Filtration) 42
3.3.1.1.1 動力黏度(Kinematic Viscometer) 43
3.3.1.2 毛細汲取時間 (Capillary Suction Time) 45
3.3.2 電動力輔助板框式壓濾脫水系統試驗組別 46
3.3.3其他試驗及分析方法 50
第四章 結果與討論 52
4.1 都市下水污泥基本特性分析 52
4.2 都市下水污泥化學調理 54
4.3 都市下水污泥之板框式壓濾脫水部分之前驅試驗結果 56
4.4 都市下水污泥脫水試驗結果及試驗產物之品質分析 57
4.4.1 都市下水污泥脫水試驗之總濾液通量 58
4.4.2 都市下水污泥試驗之濾液酸鹼值 62
4.4.3 都市下水污泥試驗之濾液導電度 66
4.4.4 都市下水污泥脫水試驗之濾液溫度 72
4.4.5 都市下水污泥脫水試驗其質量平衡及污泥餅含水率 75
4.4.6都市下水污泥脫水試驗能耗 79
4.5 光學顯微鏡下之污泥表面結構觀察 81
4.6經濟可行性初步評估 84
4.6.1高級氧化法調理污泥之經濟可行性 84
4.6.1.1 Fenton法調理污泥 84
4.6.1.2硫酸亞鐵結合過硫酸鈉調理污泥 85
4.6.2.1 Fenton法調理污泥結合電脫水 86
4.6.2.2 硫酸亞鐵結合過硫酸鈉調理污泥結合電脫水 88
第五章 結論與建議 91
5.1 結論 91
5.2 建議 93
參考文獻 94
碩士在學期間發表之學術論文 111
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