本研究主要分析珠江河口地區全氟化合物(perfluorinated compounds, PFCs)的分佈情形，分別採集不同深度的海水及岩心沉積物樣品，以了解該區域全氟化合物的分佈情形及傳輸變化。
研究結果顯示海水中總全氟化合物濃度範圍為ND~15.10 ng/L，以全氟丁基磺酸(perfluorobutyl sulfonate, PFBS)為主要全氟化合物，與其他文獻地區水體中的全氟化合物組成較不相同，表示珠江三角洲一帶可能有PFBS的特定污染源存在。而沉積物中總全氟化合物濃度範圍為ND~2.68 ng/g，以全氟辛酸(perfluorooctanoic acid, PFOA)為主要全氟化合物，與大部分沉積物中全氟化合物的組成類似。此外於水體及沉積物中的總全氟化合物濃度皆呈現越接近表面有越高的趨勢，與全球全氟化合物排放趨勢相似。與各國文獻比對後，儘管本研究不是全氟化合物污染最嚴重的地區，但仍受高度工業化、城市化及人為活動影響。
進行沉積物中總全氟化合物濃度、總有機碳(total organic carbon, TOC)含量及平均粒徑的相關性分析，結果顯示TOC與粒徑大小呈顯著負相關(R = -0.438 , P = 0.01)；TOC與總全氟化合物濃度呈顯著正相關(R = 0.323 , P = 0.01)，與多數文獻結果相符。再進一步進行主成分分析法(principal component analysis, PCA)及階層群集分析法(hierarchical cluster analysis, HCA)，來探討沉積物中全氟化合物的組成，結果顯示大致可分為受PFOA、全氟辛烷磺酸(Perfluorooctane sulfonate, PFOS)影響的一類，以及受PFBS、全氟己烷磺酸(Perfluorohexyl sulfonate, PFHxS)、全氟癸酸(Perfluorodecanoic acid, PFDA)影響的一類。

This study investigated the concentration distribution of perfluorinated compounds (PFCs) in the Pearl River estuary of China. Collects samples of seawater and core sediments at different depths to understand the transport behavior of PFCs in the environment. Seawater and core sediment samples were collected from the Pearl River estuary of China at different depths to understand the transport behavior and contribution of PFCs in the area.
The results showed that the total concentration of PFCs in seawater ranged from n.d. to 15.10 ng/L, and the predominant compounds of PFCs in seawater samples were perfluorobutyl sulfonate (PFBS) is different from other regions, suggesting that the Pearl River Delta region may have specific sources of PFBS pollution. The results also showed that the total concentration range of PFCs in sediment was n.d. to 2.68 ng/g, and the major compounds of PFCs in the seawater samples were perfluorooctanoic acid (PFOA), which is similar to that of PFCs from other studies. In addition, the total concentration of PFCs in seawater and sediment samples decrease with the depth increasing, similar to global emission trends for total PFCs. Compared with other literatures, although the highest polluted area was not found in the sampling region of this study, but the concentration distribution is affected by high industrialization, urbanization, and humam activities.
Total organic carbon content (TOC) was significantly negatively correlated with mean particle size (r = -0.438, p = 0.01); and TOC was significantly positively correlated with total concentration of PFCs (r = 0.323, p = 0.01). The data are consistent with other previous. The sediment samples were analyzed by principal component analysis (PCA) and hierarchical cluster analysis (HCA) to identify their compositions. The results can be divided into two clusters, the one cluster included PFOA, Perfluorooctane sulfonate (PFOS); another cluster was predominated by PFBS, Perfluorohexyl sulfonate (PFHxS) and Perfluorodecanoic acid (PFDA).

致謝 ii
摘要 iii
Abstract iv
目錄 vi
圖目錄 ix
表目錄 xi
附錄目錄 xii
第一章、前言 1
1-1 研究動機 1
1-2 研究目的 2
第二章、文獻回顧 3
2-1全氟化合物的特性 3
2-2 環境中全氟化合物之傳輸及宿命 7
2-3 全氟化合物對生物健康之影響 9
2-4 全氟化合物於各國之管理規範 11
2-5 岩心沉積物及水體之應用 12
2-6 研究區域 13
第三章、實驗方法及步驟 14
3-1 實驗材料與儀器 14
3-1-1材料 14
3-1-2儀器設備 15
3-2 試藥及器具前處裡 16
3-3 採樣與保存方法 16
3-4 樣品前處理 16
3-5 分析方法 23
3-5-1粒徑分析 23
3-5-2總有機碳(TOC)分析 23
3-5-3全氟化合物分析 24
3-6 品保及品管 (QA/QC) 28
3-6-1方法回收率 28
3-6-2實驗空白分析 28
3-6-3方法偵測極限 28
3-7 主成分分析法(Principal Component Analysis, PCA) 30
3-8 階層群集分析法(Hierarchical Cluster Analysis, HCA) 30
第四章、結果與討論 32
4-1 濃度含量分佈 32
4-1-1 海水中總全氟化合物之濃度含量分佈 32
4-1-2 岩心中總全氟化合物之濃度含量 37
4-1-3 表層沉積物中總全氟化合物之濃度含量 43
4-2 組成比例及來源探討 44
4-2-1 海水中全氟化合物之組成比例 44
4-2-2 沉積物中全氟化合物之組成比例 48
4-3 與國外文獻比較探討 51
4-3-1海水中全氟化合物濃度與國外文獻探討 51
4-3-2沉積物中全氟化合物濃度與國外文獻探討 55
4-4 相關性分析 59
4-5 主成分分析結果 60
4-5-1 海水樣品之主成分分析 60
4-5-2 沉積物樣品之主成分分析 61
4-6 階層群集分析結果 64
4-6-1海水樣品之階層群集分析 64
4-6-2沉積物樣品之階層群集分析 64
第五章、結論與建議 69
5-1 結論 69
5-2 建議 70
參考文獻 71
附 錄 79

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