我們利用實驗室先前所合成的(Ph-OPO)Na2•(DME)2的化合物作為ligand，分別與一當量和0.5當量的FeCl2反應，都順利合成出兩個順磁性錯合物，也分別做了Evans method和SQUID的實驗，分別對其液態和固態做磁性上的測量，並且也進一步加以討論其磁性現象。
接著我們將原有的H2(Ph-OPO)，做進一步的設計，把在donor atom磷上的取代基，由phenyl改為tert-butyl，得到一新的雙苯酚磷化物2,2’-tert-butylphosphinobis(4,6-di-tert-butylphenolate) [(tBu-OPO)2-]，嘗試藉由取代基不同的立體障礙與陰電效應，希望能夠得到不同結果，並且拿H2(Ph-OPO)與H2(tBu-OPO)，跟一系列鋅(Zn)金屬化合物的反應，利用X-ray及不同核種的NMR鑑定其組成。

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苯酚膦化物鐵、鋅錯合物
壹、緒論..................................................................................................................1
貳、結果與討論......................................................................................................4
1. [(Ph-OPO)Fe]2·(THF)2的合成與鑑定......................................................4
2. (Ph-OPOH)2Fe·(THF)2的合成與鑑定.....................................................14
3. Zn(tBu-OPOLi)2·(THF)2的合成與鑑定…………………………..……20
4. Zn(tBu-OPOH)2·CH3CN的合成與鑑定..................................................26
5. Zn(Ph-OPOH)2的合成與鑑定.................................................................31
6. Zn2(tBu-OPO)2·THF的合成與鑑定........................................................33
7. Zn2(Ph-OPO)2·(THF)2的合成與鑑定......................................................40
參、結論................................................................................................................46
肆、實驗部分........................................................................................................37
一、一般程序............................................................................. ................49
二、儀器........................................................................................................49
三、實驗步驟................................................................................................50
1. 合成2-bromo-4,6-di-tert-butyl-phenol (HYS1-200) .....................51
2. 合成 (Ph-OPO)H2 (HYS1-155)......................................................51
3. 合成(Ph-OPO)Na2·(DME)2 (HYS1-107) .......................................51
4. 合成H2(tBu-OPO) (HYS2-228) ...................................................52
5. 合成[(Ph-OPO)Fe]2·(THF)2 (HYS1-221) ......................................52
6. 合成(Ph-OPOH)2Fe·(THF)2 (HYS2-245) ......................................53
7. 合成Zn(tBu-OPOLi)2·(THF)2 (HYS2-206) …...............................53
8. 合成Zn(tBu-OPOH)2·CH3CN (HYS2-202)....................................54
9. 合成Zn(Ph-OPOH)2 (HYS2-252、253) .........................................55
10. 合成Zn2(tBu-OPO)2·THF (HYS2-223) .........................................56
11. 合成Zn2(Ph-OPO)2·(THF)2 (HYS2-251) ......................................57
伍、參考文獻........................................................................................................58

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