本研究於台灣高雄某工業區進行空氣污染物、揮發性有機物(Volatile Organic Compounds, VOCs)及二甲基硫(DMS)之檢測，探討園區污染物高濃度物種異味特徵及冬、夏兩季之時空及時段分布，且利用模式模擬(ISCST3)了解DMS對於周圍住宅區之影響。

空氣污染物分析方面，照季節分布之結果顯示，園區內指標污染物為PM10，夏季各空氣污染物濃度較低，主要因對流旺盛，污染物擴散佳，且高雄地區於夏季有較多降雨機率，有利對於污染物的洗滌，冬(春)季則因大氣混和層高度較低，不利於污染物與大氣的混和，擴散不佳而造成濃度較高；時段分布之顯示，冬(春)、夏兩季各空氣污染物逐時變化趨勢相似，PM10、CO、NOX 及THC 皆於日間活動強度較強或上下班車流量尖峰時段而有高值產生；O3 則於日間為高濃度時段，夜間濃度明顯下降；NOX 變化趨勢則與O3 相反；CH4 及SO2 則無明顯變化趨勢。

檢視園區內季節及時段主要VOC組成物為醇類及芳香族，醇類以甲醇為主，芳香族則為甲苯，物種濃度亦未超出嗅味閾值(3.3、0.33 ppm)，對於園區內異味影響並不明顯；園區外也以甲醇貢獻為主，均未超出其嗅味閾值，對於園區外影響亦不明顯。

園區內二甲基硫(DMS)，高濃度區域發生於D2 點，發現於A 點西北方有半導體產業，顯示為園區DMS主要排放源。



於兩廠區同時排放進行模擬，A廠與B廠管道DMS檢測濃度為1.43 ppm及0.0195 ppm，同時排放的擴散模擬結果顯示，最大著地濃度在廠區下風200公尺處，濃度約為0.0035ppm；擴散至下風300公尺國宅處之濃度為0.025 ppm，高出其嗅覺閾值(0.001 ppm)。

　 In this study the sampling and analyses of airborne pollutants, volatile organic compounds (VOCs) and dimethyl sulfide (DMS) has been carried out in an industrial zone in Kaohsiung, Taiwan for investigating the odor characteristics and time and space variations of these pollutants. The impact of DMS on surrounding residential areas has also been investigated via mode simulation (ISCST3).
　
　 In terms of air pollutant analysis, the result indicates that the indicative pollutant in the industrial zone is PM10. The concentrations of all air pollutants (PM10, CO, NOX and THC) are lower in summer than in winter and spring because strong convection in summer has contributed to diffusion of the pollutants, and because higher rainfalls in summer are favorable for the washing of pollutants. The concentrations of PM10, CO, NOX and THC are higher during daytime with peaks during rush hours; O3 concentration is high during daytime and significantly lower in night-time; the variation trend of NOX is just the opposite to that of O3; there are no obvious variation trends for CH4 and SO2.
　
　 VOCs in the industrial park during all seasons are mainly composed of alcohols and aromatic. Alcohols are predominately methanol, and for aromatic it is toluene. The concentrations of these species are lower than olfactory threshold (3.3, 0.33 ppm) such that they have no significant impact on the odor in the industrial zone; the VOCs outside the industrial zone are mainly methanol, which is also lower than the olfactory threshold such that its impact on the outside of industrial zone is insignificant.
　
　The high concentration area of dimethyl dulfide (DMS) inside the industrial zone is located at monitoring point D2. There are semiconductor companies found in the northwest to point A, which are the main sources of DMS emission in this industrial zone.
　
　The transport of DMS from the emission sources using ISC3 code have been simulated simultaneously for two factories, with the measured concentrations of DMS detected in the pipelines of factory A (1.43 ppm) and factory B (0.0195 ppm) as the input values of the code. The simulation results indicates that the maximum ground level concentration is around 0.0035 ppm at 200 m downwind of the factory; and the concentration becomes 0.025 ppm after diffusing downwind 300 m to the residential area, which is higher than the olfactory threshold (0.001 ppm).

目錄
誌謝 i
摘要 ii
ABSTRACT iv
目錄 vi
表目錄 ix
圖目錄 xi
第一章 前言 1
1.1 研究源起 1
1.2 研究目的 2
第二章 文獻回顧 3
2.1園區概況 3
2.2大氣揮發性有機物 (VOCs)之性質 3
2.3大氣揮發性有機物 (VOCs)排放源 4
2.3.1大氣揮發性有機物 (VOCs) 移動源排放特徵 4
2.3.2大氣揮發性有機物 (VOCs) 固定源排放特徵 6
2.4 近年高雄市空氣品質及氣象概述 8
2.4.1 高雄地區氣象概況 8
2.5 空氣污染指標(PSI) 10
2.6 空氣污染指標(AQI) 12
2.7 異味物質二甲基硫(DMS)來源與特性 19
2.7.1 二甲基硫基本特性 19
2.7.2 二甲基硫來源 20
2.7.3 二甲基硫處理 21
2.8 臭/異味物質特性及來源 23
2.8.1 臭/異味物質對健康之影響 27
2.8.2高斯擴散模式應用 29
第三章 研究方法 31
3.1研究架構與流程 31
3.2 採樣規劃 32
3.2.1 採樣點位置 32
3.2.2 採樣時程規劃 33
3.3 採樣分析方法 35
3.3.1 空氣中揮發性有機物檢測 35
3.3.2 空氣品質連續監測 39
3.3.3二甲基硫(DMS)檢測 44
3.4 ISCST3模式 46
3.4.3高斯擴散方程式 49
3.4.2大氣混合層高度 50
3.4.3 受體資料 52
第四章 結果與討論 53
4.1 園區內空氣品質分析 53
4.1.1 空氣污染物濃度季節變化 53
4.1.2 園區內空氣污染物濃度逐時變化 55
4.2 園區內揮發性有機物濃度分析 61
4.2.1 揮發性有機物之季節分布 61
4.2.2 揮發性有機物之時段分布 61
4.3 園區外揮發性有機物濃度分析 99
4.4 園區內二甲基硫(DMS)分析 101
4.4.1 園區內DMS分布 101
4.4.2 園區內DMS模擬 104
第五章 結論與建議 108
5.1 結論 108
5.2 建議 111
參考文獻 112

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