本研究於台灣南部某工業區進行空氣污染物、氨氣及揮發性有機物(Volatile Organic Compounds, VOCs)檢測，探討污染物濃度於冬、夏兩季之時空分布；利用異味威脅值(Odor threat value,OTV)檢視園區內VOC物種濃度與其嗅位閾值之比值，探討易造成異味之VOC物種，且於園區內異味發生區域進行定點官能測定及VOCs檢測，探討可能之氣味特徵、物種及來源。
空氣污染物方面，依季節分布之結果顯示，冬季濃度均較夏季高，因冬季之大氣混和層高度較低，污染物與大氣的混和及擴散效果不佳，反觀夏季對流旺盛，污染物擴散較冬季快，導致各污染物監測值較低；時段分布之結果顯示，冬、夏兩季之逐時濃度變化相似，PM10、CO、NOX及SO2皆於車流量尖峰時段(06–10時及17–20時)有峰值產生，O3於日間(10–18時)為高值時段，入夜後濃度降至低值時段，THC、CH4及NMHC則無顯著日夜變化趨勢；園區內空氣品質指標污染物均為PM10，其最大排放源為車輛行駛揚塵，顯示移動污染源對園區空氣品質有顯著影響。
氨氣方面，檢測結果濃度介於0.012–0.098 ppm，遠低於法規標準(1 ppm)，亦均遠低於氨氣之嗅味閾值(1.5 ppm)，顯示園區內氨氣逸散幾乎不會對周界大氣造成異味影響。
VOCs特徵對異味影響，檢出物種中嗅味閾值較低的有甲基丙烯酸甲酯(50 ppb)、間,對-二甲苯(41 ppb)及苯乙烯(35 ppb)；其中甲基丙烯酸甲酯異味威脅值達2.08(0.20–2.08)為嗅味閾值濃度2倍，污染源為園區中某塑膠工廠。而園區中VOCs特徵以甲醇(8.0–55.4 ppb)、異戊烷(0.7–66.9 ppb)、甲苯(2.6–10.1 ppb)、丙酮(6.0–9.3 ppb)及甲基丙烯酸甲酯(0.1–8.7 ppb)為主。
異味濃度與VOCs檢測結果，以I測點異味濃度40最高，其檢出物種異味威脅值以甲苯0.21(濃度70.3 ppb)最高，其餘3測點(II–IV點)雖異味濃度不高，但仍為可感知等級，而各檢出物種異味威脅值均很低，顯示異味鮮少來自VOCs所貢獻。

This study measured Ambient concentrations of air pollutants, ammonia and Volatile Organic Compounds (VOCs) in industrial park in Southern Taiwan. The spatial distribution was investigated during different time periods and seasons. Use odor threat value( OTV), ie the ratio of species detectable concentration and their odor threshold to investigate the odor species and emission sources in industrial park. Also, this study measured odor and VOCs concentration in odor occur area. Investigate the possible odor characteristics, species and sources.
The season distribution of air pollutants showed concentration in winter higher than summer, due to low atmospheric mixing layer height in winter caused poor diffusion effects of pollutants. In contrast, exuberant convection in summer resulted in lower air pollutant monitoring values. The time period distribution showed the results which PM10, CO, NOX and SO2 concentrations occurred peaks during high traffic period (6:00–10:00 and 17:00–20:00). The concentration of O3 as a high vaiue during daytime(10：00–18：00), at night fell to a low value. The concentrations of THC, CH4 and NMHC had no significant diurnal variation. The index pollutant of air quality was PM10, which the largest emissions source was vehicle dust, showed a significant impact on mobile sources of air quality in industrial park.
The concentrations of ammonia between 0.012–0.098 ppm, far below the regulatory standards (1 ppm) and ammonia odor threshold (1.5 ppm), showed ammonia did not cause odor in industrial park.
The characteristics of VOCs impact on odor showed detection species in low odor threshold included methyl methacrylate (50 ppb), m, p–xylene (41 ppb) and styrene (35 ppb), which methyl methacrylate odor threat value of 2.08 (0.20–2.08) was twice higher than odor threshold, and the pollution sources was plastic plant in industrial park. The characteristics of VOCs showed most abundant species included methanol (8.0–55.4 ppb), isopentane (0.7–66.9 ppb), toluene (2.6–10.1 ppb), acetone (6.0–9.3 ppb) and methyl methacrylate (0.1–8.7 ppb).
The result of odor and VOCs concentration showed site I with the highest odor concentration of 40, witch the highest odor threat value of detection species was toluene of 0.21 (concentration of 70.3 ppb). Although odor concentration of the remaining three sampling points (site II–IV) were low, but still were appreciable levels. However, the odor threat value of detection species were very low, showed odor rarely contributed from VOCs.

摘要 i
ABSTRACT iii
目錄 v
表目錄 ix
圖目錄 xiii
第一章 前言 1
1.1 研究源起 1
1.2 研究目的 2
第二章 文獻回顧 3
2.1 高雄地區近年空氣品質及氣象概況 3
2.1.1高雄地區氣象概述 3
2.1.2 空氣污染物種類、特性及來源推估 6
2.1.3 空氣污染指標(PSI) 10
2.2大氣中揮發性有機物(VOCS) 14
2.2.1 移動源揮發性有機物排放特徵 16
2.2.2 固定源揮發性有機物排放特徵 17
2.2.3 園區產業概述 18
2.3 異味污染物 20
2.3.1 異味物質來源 21
2.3.2 異味物質對健康之影響 25
2.3.3 異味之官能測定與管制 27
2.3.4 異味處理 29
第三章 研究方法 31
3.1 研究架構 31
3.2 採樣規劃 32
3.2.1 採樣位置 32
3.2.2 採樣時程規劃 34
3.3 採樣與分析方法 35
3.3.1 空氣品質連續監測 35
3.3.2 空氣中揮發性有機物檢測 42
3.3.3 空氣中氨氣檢測 46
3.3.4 異味官能測定 47
3.4 品保與品管作業(QA/QC) 48
3.4.1 空白試驗 (Blank Test) 48
3.4.2 檢量線 (Calibration Curve) 49
3.4.3 方法偵測極限 (Method Detection Limit, MDL) 49
3.4.4 準確度 (Accuracy) 50
3.4.5 精密度 (Precision) 51
第四章 結果與討論 55
4.1 氣象條件 55
4.2 園區空氣品質分析 59
4.2.1 空氣污染物濃度季節變化 59
4.2.2 空氣污染物濃度逐時變化 61
夏季園區各空氣污染物濃度逐時變化 61
冬季園區各空氣污染物濃度逐時變化 68
4.2.3 空氣污染物濃度與鄰近空品測站比較 75
4.3 園區氨氣濃度分析 76
4.4 園區揮發性有機物濃度分析 77
4.4.1 園區夏季揮發性有機物濃度分析 77
4.4.2 園區冬季揮發性有機物濃度分析 82
4.5 園區異味調查 87
4.5.1 異味物質調查 89
4.5.2異味物質來源分析 91
4.5.3 園區異味濃度分析 94
異味濃度與VOCs分析 94
異味緊急應變檢測 99
第五章 結論與建議 101
5.1 結論 101
5.2 建議 103
參考文獻 105
附錄A 111
附錄B 119
附錄C 129

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