本研究由某水庫原水背景資料可知，A淨水場原水有機物含量偏高。處理後水的鋁含量主要因淨水程序使用之鋁鹽混凝劑殘留存在，由於混凝效率會直接影響到水中殘餘鋁濃度值。
A淨水場原水經杯瓶試驗後，水中殘留鋁型態主要以顆粒鋁（約佔60 %以上）形態存在，先以此原水進行前氧化搭配混凝試驗。在氧化試驗中，將改變次氯酸鈉及高錳酸鉀氧化劑量及氧化攪拌時間，分析氧化後水中溶解鋁及顆粒鋁含量，以了解不同氧化劑對溶解鋁及顆粒鋁氧化程度之影響。再以不同混凝劑對清水中總鋁的抑制效果分析，結果由高到低依序為：氯化鐵＞PACl＞硫酸鋁混凝劑，結果顯示使用次氯酸鈉氧化劑濃度在0.73～1.5 mg/L及高錳酸鉀氧化劑濃度在0.8～1.27 mg/L後，再添加PACl混凝劑15 mg/L下，對水中重金屬可符合飲用水水質標準對水中鋁濃度小於0.4 mg/L之規範。

According to the background investigation of the raw water from a certain reservoir, the raw water of a water treatment plant was found had a higher organic content. The aluminum contents of treated drinking water were due to the residue usage of aluminum coagulant existed during the water purification program. Because the efficiency of coagulation would directly affect the concentration of residue aluminum , the improving strategy of residual aluminum in drinking water was related to the dosage of coagulants added and efficiency of coagulation.

The tests results by jar test showed the main type of Al in water was existed as particles (about 60%). To understand the solution and oxidation degrees by changing the amount of sodium hypochlorite and potassium permanganate and mixing time with different oxidants were discussed. Analyzing the Al inhibitory effect by adding different coagulant, the results ranking from high to low were ferric chloride, PACl and aluminum sulfate. By using 0.73-1.5 mg/L sodium hypochlorite and 0.8-1.27 mg/L potassium permanganate, then added 15 mg/L PACl, the concentration of Al in treated water could be less than 0.4 mg/L which could pass the water quality of drinking water standard.

論文審定書 i
摘　要 ii
Abstract iii
目 錄 iv
表 次 vi
圖 次 vii
第一章　前　言 1
1-1　研究緣起 1
1-2　研究內容 2
第二章　研究背景與文獻整理 3
2-1　淨水場原水來源及供水現況 3
2-2　原水及清水鋁性質及控制方法 9
2-3　聚氯化鋁的化學性質與混凝機制 12
2-4　混凝藥劑及特性 16
2-5 混凝劑去除原水濁度之效能評估 18
2-6 高錳酸鉀氧化劑特性 20
第三章　研究方法及步驟 22
3-1　研究方法 22
3-2　水質項目與分析方法 24
3-3　採樣前置作業與品保品管作業 26
3-4　杯瓶試驗方法 26
3-5　分析儀器及設備 34
第四章　結果與討論 35
4-1　A淨水場豐水期與枯水期間各處理程序出水水質 35
4-2　不同氧化劑與不同混凝劑下之重金屬去除效率 48
第五章　結論與建議 66
5-1　結論 66
5-2　建議 68
參考文獻
附錄Ⅰ A淨水場原水水質分析報表
附錄Ⅱ A淨水場各處理水質分析報表

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