目前回收業及專家學者大部分著重於回收汽車廢觸媒中高價之鉑族金屬，然而萃取完畢後剩餘之載體通常做為固體廢棄物掩埋，不僅造成掩埋場土地空間縮減，更浪費其與沸石組成相近之特色。汽車廢觸媒載體本身由二氧化矽(SiO2)及三氧化二鋁(Al2O3)構成，即為去除空氣污染物之沸石(Zeolite)組成所需元素。沸石為一具有選擇性、結構穩定、可改質及再生率佳之吸附劑，適合吸附污染物。故本研究主要目的為將固體廢棄物減量與空氣污染物去除進行跨領域結合，並發展一套快速微波再生技術。將汽車廢觸媒載體研磨後利用氫氧化鈉溶液活化及增加比表面積，透過微波法最佳操作條件下生，可將原本比表面積提升9.86 倍。後續利用含浸法將胺官能基(AMP、MEA 及混合胺)轉移至載體上，在管柱吸收CO2 試驗( 1%，1L/min )與甲醛試驗(1ppm，1L/min)，得知每克AMP、MEA 及混合胺再生觸媒，分別可吸收38.9、29.5 及36.5 毫克二氧化碳以及5.14x10-3、5.09x10-3 及4.42x10-3 毫克甲醛。針對CO2進行10次吸附脫付循環後，AMP、MEA及MIX個別吸附效果分別約維持84.6%、72.9%及80.3%。實場試驗AMP、MEA 及混合胺改良之再生沸石，分別將CO2 濃度由1229ppm 降至735ppm、1222ppm 降至745ppm 以及1230ppm 降至743ppm。

Recently, the remaining carrier was usually buried as solid wastes. It’s not only resulted in the reduction of the landfill space but also wasting its characteristics similar with zeolites. Because the components of the carrier are silicon dioxide (SiO2) and aluminum oxide (Al2O3), which are the composition of zeolite precisely. First, the microwave technology with the features of fast reaction and low cost is used to regenerate the carrier and enhance its specific surface area. Second, using the impregnation method to shift the amine functional that has the ability of adsorbing CO2 to the carrier, then manufacturing as a filter cloth. Third, the pure CO2 and formaldehyde are subjected to the column filled with the filter cloth to execute the air pollution elimination experiment. At last, the filter cloth would also be set into the air cleaner to execute the elimination experiment of CO2 and formaldehyde at the office. Through the microwave to modify surface area, surface area of catalysts raised to 9.73 times. The different amino, each adsorption capacity is 30.6 mg-CO2/g-AMP、22.6 mg-CO2/g-MEA、28.5 mg-CO2/g-MIX in test string. At the office, AMP、MEA、MIX each one reduce the CO2 concentration to 735 ppm、745 ppm and 743 ppm.

論文審定書 i
論文授權書 ii
中文摘要 iii
英文摘要 iv
目錄 v
圖目錄 ix
表目錄 xv
第一章 前言 1
1-1 研究緣起 1
1-2 研究目的 5
第二章 文獻探討 6
2-1 汽車觸媒轉化器 6
2-1-1 廢觸媒之產生 6
2-1-2 廢觸媒前處理及再生 8
2-2 室內空氣品質 10
2-2-1室內空氣污染物介紹 11
2-3 二氧化碳捕獲技術 14
2-4 胺類處理CO2技術 16
3.4-1 胺類去除CO2反應機制 17
3-4-1 胺類含浸於固體吸附材去除CO2之先例 17
2-5 空氣清淨機清除原理 19
第三章 研究與實驗方法 20
3-1 研究流程 20
3-1-1 汽車廢觸媒前處理 20
3-1-2 鹼熔法及微波法再生載體 20
3-1-3 再生載體特性分析 23
3-1-4 再生載體含浸胺類 24
3-1-5 再生載體去除管柱內CO2之試驗 25
3-2 實驗流程圖 27
3-3 分析方法與材料設備 28
3-3-1 儀器設備 28
3-3-2 實驗藥品耗材 28
3-3-3 刀磨機前處理 29
3-3-4 鍛燒爐 29
3-3-5 密閉式微波設備 30
3-3-6 環境掃描電子顯微鏡 31
3-3-7 比表面積分析儀 32
3-3-8 X光粉末繞射儀 32
3-3-9 傅立葉轉換紅外線光譜儀(ATR-FTIR) 33
3-3-10 恆溫水浴槽 34
3-3-11 感應耦合電漿質譜儀(ICP) 34
第四章 結果與討論 39
4-1 廢棄觸媒的基礎分析 39
4-2 鹼熔法再生載體 46
4-2-1 以變異數分析與模擬估計探討主要控制變因 46
4-2-2 比較不同鍛燒時間鹼熔法再生效果 49
4-2-3 鹼熔法再生載體分析 49
4-3 微波法再生載體 55
4-3-1 以變異數分析與模擬估計探討主要控制變因 55
4-3-4 比較不同功率微波法再生效果 59
4-3-5 微波法再生載體分析 59
4-4 廢汽機車觸媒載體活化再生結論 65
4-5 再生載體含浸胺類 66
4-6 2-氨基甲基丙醇(AMP) 67
4-6-1 比較不同時間含浸AMP效果 67
4-6-2 比較不同重量百分比含浸AMP效果 71
4-6-3 比較不同溫度含浸AMP效果 74
4-7 單乙醇胺(MEA) 80
4-7-1 比較不同重量百分比含浸MEA效果 80
4-7-2 比較不同時間含浸MEA效果 83
4-7-3 比較不同溫度含浸MEA效果 87
4-8 混合胺(AMP 12% w/w + MEA 18% w/w) 92
4-8-1 比較不同重量百分比含浸MIX效果 92
4-8-2 比較不同時間含浸MIX效果 95
4-8-3 比較不同溫度含浸MIX效果 99
4-9 管柱試驗 104
4-9-1 再生載體去除管柱內CO2試驗 104
4-9-2 再生載體去除管柱內甲醛試驗 107
4-9-3 CO2吸附重複試驗 109
4-10 結合空氣清淨機進行實場室內污染物去除之試驗 110
4-11 製備成本分析 114
第五章 結論與建議 116
5-1 結論 116
5-2 建議 118
第六章 參考文獻 119

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