本研究採用雙層式的集光罩(solar concentrator)設計，使用有機-無機複合材料製作全像繞射元件，搭載透鏡陣列(lenticular array)蒐集任意角度入射的太陽光，運用全像干涉技術的波前重建原理，繞射出平面波。
　　材料製程採用溶膠-凝膠法(sol-gel)製備具光聚合能力之全像儲存材料，以四乙基矽氧烷(TEOS)作為前驅物形成二氧化矽(SiO2)的網狀結構，並在網狀結構的孔洞內部填入單體、光起始劑(photoinitiator)、高折射率金屬前驅物(HRIS)，再藉由矽烷偶合劑(coupling agent)連接有機與無機相，形成有機-無機複合材料。
　　實驗中使用綠光532nm的雷射光源記錄干涉條紋在全像光儲存材料上，利用調整全像光儲存材料的厚度和折射率，使半滿足布拉格條件(Bragg condition)的繞射選擇性，大致和可見光的波段相同，由於垂直入射太陽能電池表面有最小的反射率，因此大部分的繞射光都會垂直入射至太陽能電池中，使發電量提升。

　　Optical concentrators for the solar cells have been extensively developed. They can be roughly divided into 3 types: the diffraction type, the refraction type and the reflection type. However, not all the devices are thin enough to match the requirement of the thin film solar cells. In this study, an approach using holographic techniques to fabricate an optical concentrator for a solar cell is described. A hologram combined with a lenticular lens forms this concentrator. The lenticular lens collects the sunlights from arbitrary incident angles. Sunlight is then focused by the lenticular lens. The focused sunlight is launched into the hologram and generates diffracted light waves. Since the diffracted waves are almost normally incident into the solar cell, the reflectivity of the diffraction light on the solar cell’s surface is minimized. This makes most of the solar energy concentrated inside the solar cell. The overall setup is thin enough to meet the requirement of the thin film solar cell.
　　Optical storage materials based on a photopolymerizable silica and an ethylene glycol phenyl ether acrylate (EGPEA) were prepared by sol-gel process and their optical properties were measured in this study. This material served as hologram to generate the diffracted plane waves. To enhance the diffraction efficiency, we add zirconium isopropoxide ( Zr(OiPr)4) and methacrylic acid (MA) which served as high refractive index species (HRIS). Upon photopolymerization, concentration-gradient driven diffusion transport of the whole MA:Zr complex is expected to occur. This phenomenon enlarge the refractive index modulations Δn between light regions and dark regions.

目錄
論文審定書　i
誌謝　ii
摘要　iii
ABSTRACT　iv
目錄　v
圖目錄　viii
表目錄　x

第一章 緒論 1
　1.1 前言 1
　1.2 太陽能集光罩的種類 2
　1.3研究動機 5
第二章 基礎理論與文獻回顧 6
　2.1 全像術 6
　　2.1.1 全像術簡介 6
　　2.1.2 全像干涉 6
　　2.1.3 波前紀錄與波前重建之數學模型 7
　2.2 體積全像片的指標參數Q 9
　2.3 光學性質 10
　2.4 全像光儲存材料種類　11
　2.5 鹵化銀感光劑全像片 13
　2.6感光高分子的種類 17
　2.7光聚合 18
　　2.7.1光聚合反應 18
　　2.7.2光柵形成原理 19
　2.8溶膠-凝膠法 21
　　2.8.1溶膠-凝膠法之發展與簡介 21
　　2.8.2溶膠-凝膠法之優缺點 23
　　2.8.3影響溶膠-凝膠法之因素 23
第三章 光學系統架構與模擬 27
　3.1光學模擬 27
　　3.1.1 繞射選擇性之模擬分析 28
　　3.1.2 光學透鏡陣列的反射率分析 30
　3.2全像術光學系統 32
　　3.2.1 H2之製作流程 34
第四章 材料製程與分析 37
　4.1材料製程 37
　　4.1.1實驗藥品 37
　　4.1.2全像光儲存材料的製備 40
　4.2材料光學性質分析 41
　　4.2.1全像干涉-記錄 41
　　4.2.2全像干涉-讀取 42
第五章 結果與討論 43
　5.1材料分析與光學性質量測 43
　　5.1.1 HRIS的效應 43
　　5.1.2 高階繞射效率分析 45
　　5.1.3 綠光入射角度的影響 46
　　5.1.4原子力顯微鏡分析 47
　　5.1.5 n&k薄膜分析儀 48
　5.2集光罩之特性分析 49
　　5.2.1毛玻璃的波前重建 49
　　5.2.2 H1穿透率與曝光量之曲線 49
第七章 建議未來工作 56
　7.1 H2繞射效率的提升 56
　7.2提升H1的繞射效率 56
　7.3尋找適合的H2材料 56

參考文獻 57

[1] G. Lifante, F. Cusso, F. Meseguer, and F. Jaque, Applied Optics. 22(1983) 3966-3970.
[2] R. McCluney, Applied Optics. 22(1983) 3433-3439.
[3] R. Leutz, A. Suzuki, A. Akisawa, and T. Kashiwagi, Journal of Optics A: Pure and Applied Optics. 2(2000) 112-116.
[4] A. Abdurakhmanov, R. A. Zakhidov, A. M. Ikramov, A. V. Khaidarov, and A. U. Borisov,Applied Solar Energy. 22(1986) 18-21
[5] G. Rosenberg, R. K. Kostuk, and M. Zecchino, Laser Focus World. 440(2008) 41-44.
[6] C.F. Chen, C.H. Lin, H.T.Jan & Y.L. Yang, Optics Communication.282(2009) 360-366.
[7] A.M. Weber, W.K. Smothers, T.J. Trout, and D.J. Mickish, S.A. Benton, ed., SPIE OE/Laser Conference Proceedings.1212–04(1990) 30–39.
[8] R.T. Ingwall and H.L. Fielding,in Applications of Holography, L. Huff, ed., Proc. SPIE. 523(1985) 306–312.
[9] R. P. Friedman, J. M. Gordon, and H. Ries, Solar Energy.51(1993) 317-325
[10] W.B. Stine and M. Geyer,. Available at http://www.powerfromthesun.net/index.htm (access on the 05/02/2010).
[11] R. Leutz, A. Suzuki, A. Akisawa, and T. Kashiwagi, Solar Energy. 65(1999) ==379-388.
[12] Y. Tripanagnostopoulos, C. Siabekou and J.K. Tonui, Solar Energy. 81(2007) 661-675.
[13] Rainhart L. G. and Schimmel W. P. , Solar Energy. 17(1975) 259–264
[14] A. Abdurakhmanov, R.A. Zakhidov, A.M. Ikramov, A.V. Khaidarov, and A.U. Borisov, Geliotekhnika. 22(1986) 17–20.
[15] C. Linsen, G.Jishu, Optical Technique. 6(1993) 29–31.
[16] N. Aebischer, C. Bainier, M. Guignard, and D. Courjon, in Industrial and Commercial Applications of Holography, M. Chang, ed., Proc. SPIE. 353 (1982) 61–67.
[17] J.E. Ludman, J.L. Sampson, R.A. Bradbury, J.G. Martin, J.R. Riccobono, G. Sliker, and E. Rallis, in Practical Holography VI, S.A. Benton, ed., 1667(1992) 182–189.
[18] W.H. Bloss, M. Griesinger, and E.R. Reinhardt, App Opt. 21(1982) 3739–3742.
[19] J. R. Riccobono and J.E. Ludman Solar Holography
[20] D. Gabor, G.W. Stroke, U.S. Patents.785(1963) 279
[21] W. J. Gamgogi, W. A. Gerstadt, S. R Mackara, Proc. SPIE V.1555(1991) 256-267
[22] C.D. Wu , master thesis, National Sun Yat-sen University, Taiwan.(2013)
[23] H. Kogelnik, Bell System Tech.48(1969) 2909-2915
[24] Z.Z. Lee, master thesis, National Sun Yat-sen University, Taiwan.(2013)
[25] R. Curran, T. Shankoff, Appl. Opt. 9(1970) 1651-1657.
[26] A. Villamarín, J.Atencia, M.V. Collados, M.Quintanilla. Appl. Opt. 48(2009) No. 22 / 1
[27] J.O. White, M.C.Golomb, B. Fischer, A. Yariv, Appl. Phys. Lett. 40(1982) 450-452.
[28] P. Hariharan, Basics of holography, Cambridge University Press.(2002)
[29] Arago F 1839 C. R. Acad. Sci., Paris 9 255.
[30] P.Cheben ,T. Belenguer ,A. N´u˜nez ,F. Del Monte and D Levy , Opt. Lett. 21(1996) 1857
[31] P. Cheben, M L. Calvo, Appl. Phys. Lett. 78(2001) 1490
[32] F. Del Monte, O. Martínez, J. A. Rodrigo, M. L. Calvo, and P. Cheben, Adv. Mater. 18(2006) 2014–2017
[33] M. Feuillade, C. C.Barghorn, L. Mager, C. Carré, A. Fort, Chem. Phys. Lett. 398(2004) 151-156.
[34] L. Carretero, A. Murciano, S. Blaya, M. Ulibarrena, A. Fimia, Opt. Express. 12(2004) 1780-1787.
[35] A.Murciano, S.Blaya, L.Carretero, M.Ulibarrena, A.Fimia, Appl. Phys. 81(2005)167–169.
[36] K.G. Yager, and C.J. Barrett, Current opinion in solid state and materials Science. 5(6)(2001) 487-494.
[37] L. Kulikovsky et al, ACS applied materials & interfaces. 1(8) (2009) 1739-1746.
[38] D. Sabol, M. R. Gleeson,J. Appl. Phys. 107(2010) 053113-1-8
[39] M. Feuillade, C.C. Barghorn, Chem. Phys. Lett. 398(2004)151
[40] A. M. Ebelmen, Chim. Phys., 1846,57.
[41] T. Saegusa, Y. Chujo, J. Macromol. Sci., chem. 27(1990) 1603-1612.
[42] G.Cappelletti, et al, The Journal of Physical Chemistry B.109(10)(2005) 4448-4454.
[43] C.J. Brinker, G.W. Scherer, Sol-gel science: the physics and chemistry of sol-gel processing, Academic Pr.(1990)witz b
[44] M.A. Fardad , E.M. Yeatman , E.J.C. Dawnay , Mino Green , F. Horowitz, Journal of Non-Crystalline Solids. 183(1995) 260-267.
[45] H. Jiang, X.C. Yuan, Y. Zhou, Y. Chan, Y. Lam, Opt. Commun.185(2000) 19-24.
[46] Ó. M. Matos, M.L. Calvo, J.A. Rodrigo, P. Cheben, F. Del Monte, Appl. Phys. Lett. 91(2007) 141115-141115-141113.
[47] G.Schottner, Chem. Mater. 13(2001) 3422-3435
[48] R.K. Iler, The chemistry of silica: solubility, polymerization, colloid and surface properties, and biochemistry, Wiley New York.(1979)
[49] R. Winter, J.B. Chan, R. Frattini, J. Jonas, J. Non-Cryst. Solids. 105(1988) 214-222.
[50] W.H. Su, B.H. Tseng, W.T. Chen, SPIE 6(2013)
[51] The Company Kvant s.r.o,2009, http://www.kvant.sk/en/sk/pfg-04.htm
[52] M. Halle, Holographic photochemistry, October 8 (1998)