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博碩士論文 etd-0622113-204050 詳細資訊
Title page for etd-0622113-204050
論文名稱
Title
銀錫、鎳錫及白金錫界面反應第一相生成之研究
The First Phase Formation at the Ag/Sn、Ni/Sn and Pt/Sn Interfaces
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
112
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2013-06-25
繳交日期
Date of Submission
2013-07-22
關鍵字
Keywords
浸鍍、介金屬化合物、熱蒸鍍
Ag4Sn, evaporation, Ag3Sn, PtSn4, Ni3Sn4, PtSn
統計
Statistics
本論文已被瀏覽 5791 次,被下載 265
The thesis/dissertation has been browsed 5791 times, has been downloaded 265 times.
中文摘要
以熱蒸鍍製備Ag/Sn薄膜,藉穿透式電子顯微鏡(TEM)觀察所生成之介金屬化合物。實驗得知於30-100 ℃蒸鍍錫於Ag(001)面上時,最先生成的介金屬化合物為Ag3Sn,再加以100 ℃熱處理24小時後生成Ag4Sn相。以異質成核理論之臨界成核能障討論Ag/Sn的第一相生成應為Ag3Sn,與本研究結果相同。
鎳與白金浸鍍錫液立即取出,退錫後切出截面以TEM觀察,分別在Ni/Sn之界面觀察到Ni3Sn4為生成的第一相。
在Pt/Sn反應首先生成鬆散之PtSn4,而在界面處生成緊實的PtSn相,PtSn與Pt並無晶相關係,以異質成核理論討論,PtSn應為生成之第一相。
Abstract
Epitaxial (001)Ag film was prepared on the (001) NaCl surface,followed by Sn,by thermal evaporation .
Transmission electron microscopy(TEM) analysis showed that Ag3Sn first formed at 30-100 ℃.Further annealing at 100 ℃ for 24h turned it into Ag4Sn.The formation sequence was discussed by heterogeneous nucleation theory,which confirmed that Ag3Sn should form before Ag4Sn.
Ni and Pt was dipped into molten Sn at 240 ℃ to induce intermetallic compound formation and the cross-section was studied by TEM.Ni3Sn4 was found to form first at Ni/Sn interface.However loose PtSn4 formed first at Pt/Sn interface,but a layer of dense PtSn was found at the interface next to Pt. No orientation relationship was present.The formation sequence was also discussed by heterogeneous nucleation theory.
目次 Table of Contents
論文審定書 i
致謝 ii
摘要 iv
Abstract v
1前言 1
2 文獻回顧 3
2.1Ag/Sn界面 3
2.1.1界面反應之生成物 3
2.1.2 介金屬化合物與Ag的晶向關係 5
2.2 Ni/Sn界面 5
2.2.1界面反應之生成物 5
2.2.2 介金屬化合物與Ni之晶向關係 9
2.3 Pt/Sn界面反應 10
2.3.1 界面反應之生成物 10
2.3.2介金屬化合物與Pt之晶向關係 11
2.4 研究目的 12
3 實驗方法 13
3.1實驗儀器 13
3.1.1熱蒸鍍系統 13
3.1.2 穿透式電子顯微鏡(Transmission electron microscopy,TEM) 15
3.1.3 X 光繞射儀(X-ray diffraction) 15
3.2 實驗步驟 16
3.2.1 蒸鍍法 16
3.2.2浸鍍法 17
4結果與討論 19
4.1 Ag/Sn之界面反應 19
4.1.1 Ag/Sn在銀(001)面上之界面反應 19
4.1.2 Ag3Sn生成先於Ag4Sn之原因 20
4.2 Ni/Sn界面反應 22
4.2.1 Ni片與Sn液之界面反應 22
4.2.2 Ni薄膜與Sn液之界面反應 22
4.3 Pt/Sn界面反應 23
4.3.1 Pt層與Sn之界面反應 23
4.3.2 PtSn與PtSn4之形成 25
5 結論 27
6 參考文獻 28
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