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博碩士論文 etd-0624110-143303 詳細資訊
Title page for etd-0624110-143303
論文名稱
Title
氧化鎳及銀奈米晶粒之旋轉與界面研究
The rotation process and interfaces of the nano NiO and Ag grains
系所名稱
Department
材料與光電科學學系
Department of Materials and Optoelectronic Science
畢業學年期
Year, semester
98 學年度 第 2 學期
The spring semester of Academic Year 98
語文別
Language
英文
English
學位類別
Degree
碩士
Master
頁數
Number of pages
68
研究生
Author
紀一真
Yi-jen Ji
指導教授
Advisor
甘德新
D. Gan
召集委員
Convenor
沈博彥
P. Shen
口試委員
Advisory Committee
張六文
L. Chang
口試日期
Date of Exam
2010-06-14
繳交日期
Date of Submission
2010-06-24
關鍵字
Keywords
傾斜晶界、扭轉晶界、銀、氯化鈉、穿透式電子顯微鏡、氧化鎳、奈米薄膜、晶粒旋轉
NaCl, TEM, nanofilm, grain rotation, Tilt boundary, Twist boundary, NiO, Ag
統計
Statistics
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The thesis/dissertation has been browsed 5659 times, has been downloaded 10 times.
中文摘要
本實驗利用奈米薄膜旋轉方式探究奈米晶粒旋轉及各樣界面形成的原因。以反應式離子濺鍍在NaCl (100)、(110) 、(111) 和(112)的單晶基材上生成氧化鎳和銀磊晶之奈米薄膜，將各樣的薄膜重疊在適當的低溫進行熱處理使得奈米晶粒旋轉至一穩定界面。並利用電子顯微鏡測定其旋轉過程及各穩定界面。在疊膜間發現許多新界面，並分析其晶向關係與結構。奈米晶粒初始以快速之速率旋轉，在接近穩定位置時減緩。其速率隨溫度增加而增加，在200oC以上更快速。
Abstract
A nanofilm rotation method is developed to study the rotation of nanograins and the formation of various low energy interfaces. Epitaxial NiO and Ag nanofilms are prepared by ion beam sputtering onto the (100), (110), (111) and (112) surfaces of NaCl single crystal. By overlapping of the above films with an angle difference, and annealing at relatively low temperatures the nanograins are induced to rotate till a stable interface is reached. The rotation process and the stable interfaces are determined by transmission electron microscopy. Many new interfaces between mixed planes are found, and their orientation relationships and structures are analyzed. The rotation speed increase with temperature and is fast above 200oC.
目次 Table of Contents
Contents…………….…………………………...…………….....………..…………………….….I
List of Figures…..……………………..……………………………….……………..……….......II
List of Table…….……………………..……………………………….……………..…...….......III
Abstract (Chinese)…………………………………………………….…………...……….....…VII
Abstract……………………………………………………………………………….………...VIII
1. Introduction………………...…………..……….….………………………...…..……..............1
1.2. Purpose………...…………..……….…………….………………………...…..……..............3
2. Experimental details…………………………….……………………………..…....…….….…4
2.1. NiO system………………………………………………………………………………...4
2.1.1. NiO-A.………………………………………………...………………………….....4
2.1.2. NiO-B……………………………………...……………………………………......5
2.2. Ag system……………………………………………………………………………….…5
2.1.1. Ag-A.…………………………………………………...……………………….......6
2.1.2. Ag-B…………………………………………………...………………………........6
3. Result and discussions…………………………………………………………………………..6
3.1. Rotation between the same planes...………..……………………………………………..6
3.1.1. Epitaxial NiO films on NaCl surfaces………………………..……………………..6
3.1.2. Epitaxial silver films on NaCl surfaces………………..………..…………………..7
3.1.3. Rotation without NaCl substrate……………..…………...……..…………………..7
3.1.4. Twist boundary of the same crystallographic plane…………….…………………..7
3.1.5. Rotations of the same crystallographic planes………………….…………………..8
3.2. Interfaces of mixed planes…………………………………........….……...…….………..9
3.2.1. NiO/NaCl and Ag/NaCl Interfaces…………........…………………..….…………..9
3.2.2. Twist boundaries………........………………………………………….….……….10
3.2.3. Interfaces between mixed crystallographic planes………………………..…….…10
3.2.4. Tilt boundaries…..…………………………………………….…………..…….…12
5. Conclusions………………….....................................................................................….…......14
References…...………..................................................................................................................16
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