1. 以2-[2-(2-乙烯基苯)乙烯基]噻吩 ( 2-[2-(2-vinylphenyl)ethenyl]thiophene ) ( 30 ) 及2,2-(鄰-苯亞基二乙烯)二噻吩( 2,2-(o-phenylenedivinylene)dithiophene ) ( 31 ) 進行熱解與光解反應，在照光條件下化合物30形成二環產物35,化合物31形成產物37及39,在熱解反應下，化合物30和31皆可得到具有萘 (naphthalene)架構的化合物34及37。
2. 以2-甲氧基二苯乙烯 ( 2-methoxystilbene ) ( 17 ) 及3-甲氧基二苯乙烯 ( 3-methoxystilbene ) ( 18 ) 進行熱解反應，化合物17得到單一產物2-苯苯駢[b]呋喃 ( 2-Phenylbenzo[b]furan ) ( 23 ),化合物18得到2-菲酚 ( 2-phenanthrol ) ( 27 ),4-菲酚 ( 4-phenanthrol ) ( 28 ),反式-3-氫氧基二苯乙烯( trans-3-hydroxystilbene ) ( 29 ),芴9-環酮( fluoren 9-one ) ( 30 ) 及一組異構物1-氫苯幷 ( 1H-benz[e]indene )( 11a )與3-氫苯幷茚 ( 3H-benz[e]indene ) (11b)。

1. 2-[2-(2vinylphenyl)ethenyl]thiophene ( 30 ) and 2,2-(o-phenylenedivinylene)dithiophene ( 31 ) were studied under pyrolytic and photolytic conditions, photolytic of 30 gave upon bicyclic product 35, whereas photolytic of 31 gave products 37 and 39, FVP of 30 and 31 gave 34 and 37, respectively,which all include naphthalene nucleus.
2. 2-methoxystilbene ( 17 ) and 3-methoxystilbene ( 18 ) were studied under pyrolytic conditions, FVP of 17 gave single product 2-Phenylbenzo[b]furan ( 23 ), FVP of 18 gave 2-phenanthrol ( 27 ), ( 4-phenanthrol ) ( 28 ), trans-3- hydroxystilbene ( 29 ), Fluoren 9 -one ( 30 ) and a pair of isomer 1H-benz[e]indene ( 11a ) and 3H-benz[e]indene (11b).

第一章 2-[2-(2-乙烯基苯)乙烯基]噻吩及2,2-(鄰-苯亞基二乙烯)二噻吩的熱解與光解研究
壹、 緒論..............................................1
貳、 結果與討論.......................................12
參、 結論.............................................25
肆、 實驗部份.........................................26
伍、 參考資料.........................................38

第二章 鄰位及間位-甲氧基苯乙烯的熱解研究
壹、 緒論..............................................40
貳、 結果與討論........................................48
參、 結論..............................................58
肆、 後續研究..........................................61
伍、 總結..............................................67
陸、 實驗部份..........................................68
柒、 參考文獻..........................................87

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