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博碩士論文 etd-0626106-120422 詳細資訊
Title page for etd-0626106-120422
論文名稱
Title
1. 芳香基甲基疊氮之熱解研究 2. 苯甲酸 3-(1-丙烯基)-2-噻吩甲酸酐之熱解研究 3. 芳香基亞胺之光解與熱解研究
1. Pyrolytic Study of Arylmethylazides 2. Pyrolytic Study of Benzoic 3-(1-Propenyl)-2-thiophenecarboxylic Anhydride 3. Pyrolytic and Photolytic Studies of Arylimine
系所名稱
Department
化學系
Department of Chemistry
畢業學年期
Year, semester
94 學年度 第 2 學期
The spring semester of Academic Year 94
語文別
Language
中文
Chinese
學位類別
Degree
博士
Ph.D.
頁數
Number of pages
229
研究生
Author
許躍騰
Yao-Teng Hsu
指導教授
Advisor
周金興
none
召集委員
Convenor
葉茂榮
none
口試委員
Advisory Committee
董騰元, 張彥誠, 曾誠齊
none; none; none
口試日期
Date of Exam
2006-06-23
繳交日期
Date of Submission
2006-06-26
關鍵字
Keywords
芳香基甲基疊氮、瞬間真空熱裂解、光化學、α-氧代-鄰-菎哢二甲烷、芳香基亞胺
photochemistry, arylimine, flash vacuum pyrolysis, arylmethylazides, α-oxo-ortho-quinodimethane
統計
Statistics
本論文已被瀏覽 5735 次，被下載 15 次
The thesis/dissertation has been browsed 5735 times, has been downloaded 15 times.
中文摘要
1. 以芳香基甲基疊氮化合物33b與34b進行熱解反應，可經由3,3-
Abstract
1. FVP of arylmethylazides (33b、34b) via 3,3-sigmatropic rearrangement gave nitrogen-containing heterocyclic compounds (2b、4b). FVP of 35 gave 3-benzyl-2-thiophenecarbaldehyde (65) by 1,2 H shift of nitrene 32 followed by hydrolysis.
2. FVP of benzoic 3-(1-propenyl)-2-thiophenecarboxylic anhydride (67) gave 7-hydroxybenzo[b]thiophene (70) and cyclopenteno[b]thiophene (71). Compound 71 is difficult to synthesize by normal organic synthetic methods. The formation of 7-hydroxybenzo[b]thiophene (70) suggesting the existence of 68.
3. FVP of arylimine gave phenanthridine (3)、3-methylpyrrolo[2,3-c] quinoline (69) and thieno[2,3-c]quinoline (134). Such a method can synthesize tricyclic products in one step. On the other hand, photolytic study of arylimine gave compounds 156、184、164、180、185 and 186.
目次 Table of Contents
第一章 芳香基甲基疊氮之熱解研究
壹、 緒論...............................................1
貳、結果與討論.........................................11
參、結論...............................................31
肆、實驗部份...........................................36
伍、參考文獻...........................................65
第二章 苯甲酸 3-(1-丙烯基)-2-噻吩甲酸酐之熱解研究
壹、 緒論..............................................69
貳、結果與討論.........................................88
參、結論...............................................96
肆、實驗部份...........................................97
伍、參考文獻..........................................100
第三章 芳香基亞胺之光解與熱解研究
壹、 緒論.............................................103
貳、結果與討論........................................111
參、結論..............................................176
肆、實驗部份..........................................180
伍、參考文獻..........................................212
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