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論文名稱 Title |
2-(疊氮甲基)引朵,3-(疊氮甲基)比啶及2-(疊氮乙基)苯之熱裂解研究 Pyrolytic Study of 2-Azidomethylindole, 3-Azidomethylpyridine and 2-Azidomethylbenzene |
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系所名稱 Department |
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畢業學年期 Year, semester |
語文別 Language |
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學位類別 Degree |
頁數 Number of pages |
61 |
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研究生 Author |
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指導教授 Advisor |
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召集委員 Convenor |
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口試委員 Advisory Committee |
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口試日期 Date of Exam |
2000-06-23 |
繳交日期 Date of Submission |
2000-06-27 |
關鍵字 Keywords |
胺亞遊基、熱裂解反應 pyrolysis, nitrene |
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統計 Statistics |
本論文已被瀏覽 5722 次,被下載 2802 次 The thesis/dissertation has been browsed 5722 times, has been downloaded 2802 times. |
中文摘要 |
本論文探討含有疊氮甲基的引朵類及比啶類化合物進行瞬間真空熱裂解的反應,發現可經由產生胺亞遊基而得到三聚錯合物 |
Abstract |
Flash vacuum pyrolysis (FVP) of 2-(azidomethyl)indole, via a nitrene intermediate gave 1,3,5-tri-2-indolyl-2,4-diaza-1,4-pentadiene as the main product. By the same route, FVP of 3-(azidomethyl)pyridine produced 1,3,5-tri-2-pyridyl-2,4-diaza-1,4-pentadiene.On the other hand, FVP of (2-azidoethyl)benzene gave 1,2-diphenylethane and 3,5-diphenylpyridine as the pyrolysis product. |
目次 Table of Contents |
壹、 緒論.....1 貳、 結果與討論.....21 參、 實驗部份.....42 肆、 參考文獻.....58 |
參考文獻 References |
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