Responsive image
博碩士論文 etd-0627100-115713 詳細資訊
Title page for etd-0627100-115713
論文名稱
Title
2-(疊氮甲基)引朵,3-(疊氮甲基)比啶及2-(疊氮乙基)苯之熱裂解研究
Pyrolytic Study of 2-Azidomethylindole, 3-Azidomethylpyridine and 2-Azidomethylbenzene
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
61
研究生
Author
指導教授
Advisor
召集委員
Convenor

口試委員
Advisory Committee
口試日期
Date of Exam
2000-06-23
繳交日期
Date of Submission
2000-06-27
關鍵字
Keywords
胺亞遊基、熱裂解反應
pyrolysis, nitrene
統計
Statistics
本論文已被瀏覽 5722 次,被下載 2802
The thesis/dissertation has been browsed 5722 times, has been downloaded 2802 times.
中文摘要
本論文探討含有疊氮甲基的引朵類及比啶類化合物進行瞬間真空熱裂解的反應,發現可經由產生胺亞遊基而得到三聚錯合物
Abstract
Flash vacuum pyrolysis (FVP) of 2-(azidomethyl)indole, via a nitrene intermediate gave 1,3,5-tri-2-indolyl-2,4-diaza-1,4-pentadiene as the main product. By the same route, FVP of 3-(azidomethyl)pyridine produced 1,3,5-tri-2-pyridyl-2,4-diaza-1,4-pentadiene.On the other hand, FVP of (2-azidoethyl)benzene gave 1,2-diphenylethane and 3,5-diphenylpyridine as the pyrolysis product.
目次 Table of Contents
壹、 緒論.....1
貳、 結果與討論.....21
參、 實驗部份.....42
肆、 參考文獻.....58
參考文獻 References
1. Tiemann, F. Chem. Ber. 1891, 24, 4164-4166.
2. Fowler, F. W.; Hassner, A.; Levy, L. A. J. Am. Chem. Soc. 1967, 89, 2077-2082.
3. Swenton, J. S.; Ikeler, T. J.; Smyser, G. L. J. Org. Chem. 1973, 38, 1157-1166.
4. Saito, S.; Wentrup, C. Helv. Chim. Acta. 1971, 54, 273-275.
5. Calvin, M.; Splitter, J. S. Tetrahedron Lett. 1968, 12, 1445-1448.
6. Lwowski, W.; Maricich, T. J. J. Am. Chem. Soc. 1965, 3630-3637.
7. Sundberg, R. J. J. Am. Chem. Soc. 1966, 88, 3781-3789.
8. Atkinson, R. S.; Judkins, B. D.; Khan, N. J. Chem. Soc. Perkin Trans. 1 1982, 2491-2497.
9. Wentrup, C.; Crow, W. D. Tetrahedron Lett. 1968, 59, 6149-6152.
10. Sumitani, M.; Nagakura, S.; Yoshihara, K. Bull. Chem. Soc. Jpn. 1976, 49, 2995-2998.
11. Wentrup, C.; Thetaz, C. J. Am. Chem. Soc. 1976, 1258-1259.
12. Lwowski, W. Angew. Chem. Int. Ed. Engl. 1967, 6, 897-906.
13. Hashida, Y.; Matsui, K.; Tamura, S.; Imaizumi, H. Bull. Chem. Soc. Jpn. 1981, 54, 301-302.
14. Smolinsky, G.; Feuer, B. I. J. Org. Chem. 1966, 31, 3882-3884.
15. Kyba, E. P.; Abramovitch, R. A. J. Am. Chem. Soc. 1980, 102, 735-740.
16. Wentrup, C.; Winter, H. W. J. Am. Chem. Soc. 1980, 102, 6159-6161.
23. Hunter, D. H.; Sim, S. K. J. Am. Chem. Soc. 1969, 6202-6203.
24. Hunter, D. H.; Sim, S. K. Can. J. Chem. 1972, 50, 669-677.
25. Corey, E. J.; Kuhnle, N. M. Tetrahedron Lett. 1997, 38, 8631-8634.
26. Leete, E. J. Am. Chem. Soc. 1959, 20, 6023-6026.
27. Iwao, M. Heterocycles, 1993, 36, 29-32.
28. Iwao, M.; Motoi, O. Tetrahedron Lett. 1995, 36, 5929-5932.
29. Walsh, P. J.; Larter, M. L.; Phillips, M.; Ortega, F.;Aguirre, G.; Somanathan, R. Tetrahedron Lett. 1998, 39, 4785-4788.
30. Takaya, H.; Ito, M.; Koyakumaru, K.; Ohta, T. Synthesis 1994, 376-378.
31. Ohshiro, Y.; Komatsu, M.; Takamatsu, S.; Uesaka, M.; Yamamoto, S. J. Org. Chem. 1984, 49, 2691-2699.
32. Jackson, A. H.; Prasitpan, N.; Shannon, P. V. R.; Tinker, A. C. J. Chem. Soc., Perkin Trans. 1 1987, 2543-2551.
33. Martinez-Utrilla, R.; Amat-Guerri, F.; Lopez-Gonzalez, M. M. C. Tetrahedron Lett. 1983, 24, 3749-3752.
34. Pindur, U.; Eitel, M. Synthesis 1988, 364-367.
35. Dodd, R. H.; Dekhane, M. Tetrahedron 1994, 50, 6299-6306.
36. Marko, I. E.; Giles, P. R.; Tsukazaki, M.; Chelle-Regnaut, I. J. Org. Chem. 1999, 64, 2433-2439.
37. d`Angelo, J.; Casas, R.; Cave`, C.; Tetrahedron Lett. 1995, 36, 1039-1042.
38. Olah, G. A.; Watkins, M. I. J. Am. Chem. Soc. 1981, 103, 6566-6574.
39. Parsons, P. J.; Eshelby, J. J.; Crowley, P. J. J. Chem. Soc., Perkin Trans. 1 1995, 191-199.
40. Vijn, R. J.; Arts, H. J.; Green, R.; Castelijns, A. M. Synthesis 1994, 573-578
電子全文 Fulltext
本電子全文僅授權使用者為學術研究之目的,進行個人非營利性質之檢索、閱讀、列印。請遵守中華民國著作權法之相關規定,切勿任意重製、散佈、改作、轉貼、播送,以免觸法。
論文使用權限 Thesis access permission:校內校外完全公開 unrestricted
開放時間 Available:
校內 Campus: 已公開 available
校外 Off-campus: 已公開 available


紙本論文 Printed copies
紙本論文的公開資訊在102學年度以後相對較為完整。如果需要查詢101學年度以前的紙本論文公開資訊,請聯繫圖資處紙本論文服務櫃台。如有不便之處敬請見諒。
開放時間 available 已公開 available

QR Code