噻吩基甲基疊氮化合物進行瞬間真空熱解反應，經由胺亞遊基的中間體可以得到雙聚物：噻吩基-噻吩基亞甲基胺以及三聚物：N,N`-二噻吩基亞甲基-噻吩基甲基雙胺兩種產物，將三聚物進一步逕行環化脫氫可形成2,4,5-三噻吩基咪唑。而以疊氮甲基苯駢〔b〕呋喃進行瞬間真空熱解反應時，產物只有三聚物：二苯駢〔b〕呋喃基甲基-N,N'-苯駢呋喃基甲基胺的產生。

Flash vacuum pyrolysis(FVP) of azidomethylthiophene,via a nitrene intermediate,gave two products,a dimer (thienylmethylidene-thienylamine) and a trimer (N,N`-dithienyl methylidene-thienylmethylidene diamine).The trimer underwent cyclization and dehydrogenation to afford 2,4,5-trithienylimidazole. However by the same route, FVP of azidomethylbenzo[b]furan produced only a trimer(dibenzo[b]furylmethylidene-N,N'-benzo[b]furylmethyl amine).

目錄
第一章 芳香基甲基疊氮的瞬間真空熱解之研究
壹、緒論 1
貳、結果與討論 11
參、實驗部分 47
肆、參考文獻 65
第二章 2-醯胺基-3-甲基吡啶及其衍生物之熱解研究
壹、緒論 67
貳、結果與討論 76
參、實驗部分 87
肆、參考文獻 92

Part-I
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Part-II
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