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博碩士論文 etd-0629107-170439 詳細資訊
Title page for etd-0629107-170439
論文名稱
Title
高雄市大氣中醛酮類化合物之濃度特徵及時空分布調查分析
Investigation of temporal and spatial characteristics of carbonyl compounds in the Atmosphere in Kaohsiung
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
149
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2007-06-14
繳交日期
Date of Submission
2007-06-29
關鍵字
Keywords
日變化、季節變化、醛酮類化合物、因子分析
Seasonal variation, Factor analysis, Diurnal variation, Carbonyl compounds
統計
Statistics
本論文已被瀏覽 5677 次,被下載 16
The thesis/dissertation has been browsed 5677 times, has been downloaded 16 times.
中文摘要
本研究利用LpDNPH−Cartridge 及微電腦空氣採樣器分析高雄市
(楠梓站及小港站)四季大氣中醛酮類化合物 (Carbonyls)之濃度特
徵,並探討醛酮類化合物濃度四季變化及日變化,最後利用因子分析
推估高雄市境內之可能污染來源。
楠梓站濃度最高為乙醛 (27.83 μg/m3) , 其次為甲醛(5.03
μg/m3);小港站濃度最高為乙醛(28.91 μg/m3),其次為甲醛(6.92
μg/m3)。小港站之總Carbonyls 濃度 (57.86 μg/m3)高於楠梓站 (49.74
μg/m3)。
季節性方面,楠梓站夏季與冬季濃度分別為65.42 μg/m3 及25.06
μg/m3,小港站夏季與冬季濃度分別為85.09 μg/m3 及37.12 μg/m3,推
估為夏季由於光化學反應較強,導致Carbonyls 濃度為最高。日變化
方面,早上及晚上時段因交通車流量較高,使得Carbonyls 濃度較高。
以因子分析法解析Carbonyls 濃度,推估出楠梓地區主要污染物
來源為移動源 (機車、柴油車與汽車)排放及固定源 (工業源、餐飲源
與化學製程)排放;小港地區污染物貢獻來源為移動源排放 (機車與
汽車)、固定源 (工業源與餐飲源)排放及二次光氧化作用生成。
Abstract
The concentrations of atmospheric carbonyls were studied by the
LpDNPH-Cartridge and the microcomputer air sampling device at Nanzi and
Siaogang sites in Kaohsiung city. Source apportionment was determined by the factor
analysis.
The results showed that the highest concentrations of carbonyls was
acetaldehyde (27.83 μg/m3) at Nanzi, followed by formaldehyde (5.03 μg/m3). At
Siaogang, the highest concentrations of carbonyls was acetaldehyde (28.91 μg/m3),
followed by formaldehyde (6.92 μg/m3). The concentrations of total carbonyls was
higher at Siaogang (57.86 μg/m3) than those at Nanzi (49.74 μg/m3) .
The concentrations of total carbonyls at Nanzi were 65.42 μg/m3 in summer and
25.06 μg/m3 in winter, and were 85.09 μg/m3 in summer and 37.12 μg/m3 in winter at
Siaogang, due to the fact that summer has stronger photochemical activities than in
winter. Additionally, peak rush hours of the traffics, either in the morning or at night,
would result in increased concentration of Carbonyls was higher.
The concentrations of atmospheric carbonyls were studied by the LpDNPH-Cartridge and the microcomputer air sampling device at Nanzi and Siaogang sites in Kaohsiung city. Source apportionment was determined by the factor analysis.

The results showed that the highest concentrations of carbonyls was acetaldehyde (27.83 μg/m3) at Nanzi, followed by formaldehyde (5.03 μg/m3). At Siaogang, the highest concentrations of carbonyls was acetaldehyde (28.91 μg/m3), followed by formaldehyde (6.92 μg/m3). The concentrations of total carbonyls was higher at Siaogang (57.86 μg/m3) than those at Nanzi (49.74 μg/m3) .

The concentrations of total carbonyls at Nanzi were 65.42 μg/m3 in summer and 25.06 μg/m3 in winter, and were 85.09 μg/m3 in summer and 37.12 μg/m3 in winter at Siaogang, due to the fact that summer has stronger photochemical activities than in winter. Additionally, peak rush hours of the traffics, either in the morning or at night, would result in increased concentration of Carbonyls was higher.

Source apportionment analysis using factor analysis shows that the principle sources at Nanzi were traffic exhausts (motor, diesel, and gasoline vehicle) and stationary sources (industry, restaurant and chemical processes). The main sources at Siaogang were traffic exhausts (motor and gasoline vehicle), stationary sources (industry and restaurant) and secondary photo-chemical reactions.
目次 Table of Contents
總目錄
頁碼
謝誌 I
中文摘要 II
英文摘要 III
總目錄 IV
表目錄 VII
圖目錄 IX
附表目錄 X
附圖目錄 X

第一章 前言 1-1
1.1 研究緣起 1-1
1.2 研究目標 1-2

第二章 相關研究及文獻回顧 2-1
2.1 高雄市近年空氣及氣象背景資料概述 2-1
2.1.1 空氣品質PSI變化趨勢 2-1
2.1.2 各空氣污染物濃度變化趨勢 2-3
2.1.3 高雄市空氣污染物排放量概估 2-8
2.1.4 高雄地區歷年氣象概述 2-11
2.2 大氣中揮發性有機物 (VOC)來源 2-14
2.2.1 大氣揮發性有機物 (VOC)性質及排放特徵 2-14
2.2.2 固定源揮發性有機物排放特性 2-17
2.2.3 移動源揮發性有機物排放特性 2-18
2.2.4 自然源VOC的流佈及影響 2-19
2.3 醛酮類化合物 (Carbonyl compound) 2-21
2.3.1 醛酮類化合物之特性 2-21
2.3.2 醛酮類化合物之來源及排放特徵 2-22
2.3.3 醛酮類化合物在大氣環境中之生成與轉化 2-25
2.3.4 醛酮類化合物及其前驅物致臭氧生成特性 2-26
2.3.5 醛酮類化合物之健康危害 2-27
2.3.6 醛酮類化合物之濃度分布 2-28
2.4 受體模式 2-29
2.4.1 主成分分析/絕對主成分分析 2-30

第三章 研究方法與步驟 3-1
3.1 研究架構與流程 3-1
3.2 大氣中醛酮類化合物採樣地點及時段規劃 3-2
3.3 採樣方法與設備 3-4
3.3.1 空氣採樣器 3-4
3.3.2 吸附管 (Cartridge) 3-6
3.4 採樣程序 3-7
3.5 樣品分析 3-7
3.6 分析設備及程序 3-7
3.7 因子分析與受體模式之理論基礎 3-8
3.7.1 因子分析 3-8
3.8 Carbonyls分析之品質保證與品質控制 3-12
3.8.1 空白試驗 3-12
3.8.2 方法偵測極限 3-12
3.8.3 檢量線的配置 3-13
3.8.4 準確度 3-13
3.8.5 精密度 (RSD) 3-14

第四章 結果與討論 4-1
4.1 大氣中醛酮類化合物 (Carbonyl compounds)濃度 4-1
4.1.1 採樣時間之氣象資料 4-1
4.2 大氣中醛酮類化合物濃度 4-3
4.2.1 大氣中醛酮類化合物之特性 4-3
4.2.2 大氣中醛酮類化合物濃度之季節變化分布 4-9
4.2.3 大氣中醛酮類化合物濃度之日變化分布 4-14
4.3 大氣中醛酮類化合物貢獻來源分析 4-21
4.3.1 醛酮類化合物之夏季及冬季貢獻來源分析 4-22
4.3.2 醛酮類化合物之貢獻來源分析 4-27
4.4 醛酮類化合物濃度與臭氧濃度相關性分析 4-30

第五章 結論與建議 5-1
5.1 結論 5-1
5.2 建議 5-2

參考文獻 參-1

附錄A 空氣中氣態之醛類化合物檢驗方法 附A-1
附錄B 楠梓站及小港站四季採樣時程之各時段風花圖 附B-1
附錄C 楠梓站及小港站Carbonyls大氣採樣之各時段濃度表 附C-1
附錄D 個人簡歷 附D-1

表目錄
頁碼
表2.1-1 民國86 - 95年高雄市四空品測站臭氧 (O3)事件日每年之天數 2-2
表2.1-2 民國86 - 95年高雄市四空品測站懸浮微粒 (PM10)事件日每年之天數 2-2
表2.1-3 民國92年高雄市各污染源排放總表 2-10
表2.1-4 高雄地區近十年各月份平均氣象資料統計表 2-13
表2.2-1 揮發性有機物 (VOC)排放源 2-15
表2.2-2 高雄市地區固定與移動污染源排放量 2-16
表2.3-1 18種Carbonyls之分子量及物理特性 2-22
表2.3-2 各污染源之Carbonyls濃度特徵之比較 2-25
表3.2-1 本研究分析之18種Carbonyls物種 3-3
表3.2-2 高雄市區空氣品質監測網測站環境資料一覽表 3-4
表3.2-3 楠梓站及小港站之採樣日期 3-4
表3.8-1 Carbonyls標準品之成分及濃度 (Rescek) 3-15
表3.8-2 標準品檢量線 3-16
表3.8-3 18種Carbonyls之回收率 3-17
表4.1-1 楠梓站採樣時間氣象資料 4-2
表4.1-2 小港站採樣時間氣象資料 4-2
表4.2-1 楠梓站與小港站Carbonyls濃度 4-4
表4.2-2 楠梓站與小港站附近道路之車流量 4-5
表4.2-3 楠梓站與小港站各Carbonyls濃度之百分比 4-6
表4.2-4 本研究Carbonyls濃度與其他地區之相關文獻比較 4-8
表4.2-5 楠梓站Carbonyls之四季濃度分布 4-11
表4.2-6 小港站Carbonyls之四季濃度分布 4-12
表4.2-7 楠梓站Carbonyls各時段濃度 4-16
表4.2-8 小港站Carbonyls各時段濃度 4-17
表4.3-1 移動車輛尾氣Carbonyls平均排放指紋 4-21
表4.3-2 楠梓站夏季之Carbonyls平均濃度因子分析結果 4-23
表4.3-3 楠梓站冬季之Carbonyls平均濃度因子分析結果 4-24
表4.3-4 小港站夏季之Carbonyls平均濃度因子分析結果 4-25
表4.3-5 小港站冬季之Carbonyls平均濃度因子分析結果 4-26
表4.3-6 楠梓站之Carbonyls平均濃度因子分析結果 4-28
表4.3-7 小港站之Carbonyls平均濃度因子分析結果 4-29
表4.4-1 楠梓站及小港站各時段Total Carbonyls與O3相關性
分析 4-30

圖目錄
頁碼
圖2.1-1 高屏地區空氣品質現況 (86 - 95年) 2-1
圖2.1-2 高雄市各測站PM10逐月濃度變化趨勢 2-4
圖2.1-3 高雄市各測站SO2逐月濃度變化趨勢 2-5
圖2.1-4 高雄市各測站O3逐月濃度變化趨勢 2-6
圖2.1-5 高雄市各測站NOX逐月濃度變化趨勢 2-7
圖2.2-1 民國92年高雄市地區固定與移動源NMHC排放百分比 2-16
圖3.1-1 研究架構流程圖 3-1
圖3.2-1 高雄市地區Carbonyls採樣點周界環境示意圖 3-3
圖3.3-1 Airchek 2000空氣採樣器 3-5
圖3.3-2 LpDNPH-Cartridge吸附管示意圖 3-6
圖4.2-1 楠梓站及小港站之總Carbonyls四季濃度分布 4-9
圖4.2-2 (a)楠梓站與(b)小港站四季之各Carbonyls濃度分布 4-13
圖4.2-3 (a)楠梓站與(b)小港站四時段之各Carbonyls濃度分布 4-19
圖4.2-4 楠梓站及小港站四時段之總Carbonyls濃度 4-20


附表目錄
頁碼
附表C-1 楠梓站春季carbonyls大氣採樣之各時段濃度表 C-1
附表C-2 楠梓站夏季carbonyls大氣採樣之各時段濃度表 C-2
附表C-3 楠梓站秋季carbonyls大氣採樣之各時段濃度表 C-3
附表C-4 楠梓站冬季carbonyls大氣採樣之各時段濃度表 C-4
附表C-5 小港站春季carbonyls大氣採樣之各時段濃度表 C-5
附表C-6 小港站夏季carbonyls大氣採樣之各時段濃度表 C-6
附表C-7 小港站秋季carbonyls大氣採樣之各時段濃度表 C-7
附表C-8 小港站冬季carbonyls大氣採樣之各時段濃度表 C-8



附圖目錄
頁碼
附圖B-1 楠梓站春季採樣日期 (時段)之風花圖 B-1
附圖B-2 楠梓站夏季採樣日期 (時段)之風花圖 B-3
附圖B-3 楠梓站秋季採樣日期 (時段)之風花圖 B-5
附圖B-4 楠梓站冬季採樣日期 (時段)之風花圖 B-7
附圖B-5 小港站春季採樣日期 (時段)之風花圖 B-9
附圖B-6 小港站夏季採樣日期 (時段)之風花圖 B-11
附圖B-7 小港站秋季採樣日期 (時段)之風花圖 B-13
附圖B-8 小港站冬季採樣日期 (時段)之風花圖 B-15
參考文獻 References
Anilovich, I., Hakkert, A.S., 1996. Survey of vehicle emissions in israel
related to vehicle age and periodic inspection. The Science of Total
Environment 189/190, 197 − 203.
Atkinson, R., 1990. Gas-phase trospospheric chemistry of organic
chemistry: a review. Atmospheric Environment 24A, 1 − 41.
Atkinson, R., Tuazon, E. C. and Aschmann, S. M., 1995. Products of the
Gas-Phase Reactions of a Series of 1-Alkenes and
1-Methylcyclohexene with the OH Radical in the Presence of NO.
Environment Science and Technology 29, 1674 − 1680.
Baéz, P.A., Belmont, R., Padilla, H., 1995. Measurements of
formaldehyde and acetaldehyde in the atmosphere of Mexico City.
Environmental Pollution 89, 163 − 167.
Bailey, R. A., Clark, H. M., Krause, S., Strong, R. L., 1978. Atmospheric
Press, New York.
Baugh, J., Ray, W., Black, F., 1987. Motor vehicle emissions under
reduced ambient temperature idle operating conditions. Atmospheric
Environment 21, 2077 − 2082.
Borbon, A., Locoge, N., Veillerot, M., Galloo, J. C., Guillermo, R., 2002.
Characteristics of NMHCs in a French urban atmosphere:
overview of the main sources. The Science of the Total Environment
292, 177 − 191.
Carlier, P., Hannachi, H., Mouvier, G., 1986. The chemistry of carbonyl
compounds in the atmosphere- a review. Atmospheric Environment
20, 2079 − 2099.
Carter, W.P.L., 1994. Development of ozone reactivity scales for volatile
organic compounds. Journal of the Air & Waste Management
Association 44 , 881 − 899.
Carter, W.P.L., Pierce, J.A., Luo, D., and Malkina, I. L.,1995.
Environmental Chanmber Study of Maximum Incremental
Reactivities of Volatile Organic Compounds. Atmospheric
Environment 29, 2499 − 2511.
Cetin, E. Odabasi, M., Seyfioglu, R., 2003. Ambient volatile organic
compound (VOC) concentrations around a petrochemical complex
and a petroleum refinery. The Science of the Total Environment 312,
103 − 112.
Chang, M.E., Cardelino, C., 2000, Application of the Urban Airshed
Model to Forecasting Next-Day Peak Ozone Concemtrations in
Atlanta, Georgia. Journal of the Air & Waste Management
Association 50, 2010 − 2024.
Chen, K.S., Lin, C.F., Chou, Y.M., 2001. Determination of source
contributions to ambient PM2.5 in Kaohsiung, Taiwan, Using a
receptor model. Journal of Air and Waste Management Association
51, 489 − 498.
Chen, K.S., Lai, C.H., Ho, Y.T., 2003a. Source profiles and ozone
formation potentials of volatile organic compounds in three traffic
tunnels in Kaohsiung, Taiwan. Journal of Air and Waste
Management Association 53, 102 − 112.
Chen, K.S., Ho, Y.T., Lai, C.H., Chou, Y.M., 2003. Photochemical
modeling and analysis of meteorological parameters during ozone
episodes in Kaohsiung, Taiwan. Atmospheric Environment 37, 1811
− 1823. (NSC 90-2211-E-110-005)
Chen, K.S., Ho, Y.T., Lai, C.H., Tsai, Y.A., Chen, S.J., 2004. Trends in
Concentration of Ground-Level Ozone and Meteorological
Conditions during High Ozone Episodes in Kao-Ping Airshed,
Taiwan. Journal of the Air & Waste Management Association 54, 36
− 48.
Chiang, T. A., Wu, P. F., Wang, L.F., Lee, H., Lee, C.H., and Ko, Y.C.,
1997. Mutagenicity and polycyclic aromatic hydrocarbon content of
fumes from heatedcooking oils produced in Taiwan. Mutation
Research 381, 157 − 161.
Christensen, C.S., Skov, H.; Nielsen, T., Lohse, C., 2000. Temporal
Variation of Carbonyl Compound Concentrations at a Semi-Rural
Site in Denmark. Atmospheric Environment 34, 287 − 296.
Ciccioil, P., Brancaleoni, E., Frattoni, M., Cecinato, A., Brachetti, A.,
1993. Ubiquitous occurrence of semi-volatile carbonyl compounds
in tropospheric samples and their possible source. Atmospheric
Environment 27A, 1891 − 1901.
D′Alessandro, A., Lucarelli, F., Mandò, P.A., Marcazzan, G., Nava, S.,
Prati, P., Valli, G., Vecchi, R., Zucchiatti, A., 2003. Hourly elemental
composition and sources identification of fine and coarse PM10
particulate matter in four Italian towns. Journal of Aerosol Science
34, 243 − 259.
Derwent, R.G., Davies, T.J., Delaney, M., Dollard, G.J., Field, R.A.,
Dumitrean, P., Nason, P.D., Jones, B. M.R., Pepler, S.A., 2000.
Analysis and interpretation of the continuous hourly monitoring data
for 26 C2 - C8 hydrocarbons at 12 United Kingdom sites during
1996. Atmospheric Environment 34, 297 − 312.
Derwent, R.G., Middleton, D.R., Field, R.A., Goldstone, M.E., Lester,
J.N., Perry, R., 1995. Analysis and interpretation of air quality data
from an urban roadside location in central London over the period
from July 1991 to July 1992. Atmospheric Environment 29, 923 −
946.
Drewitt, G.B., Curren, K., Steyn, D.G., Gillespie, T.J., Niki, H., 1998.
Measurement of biogenic hydrocarbon emission from vegetation in
the lower fraser valley, British Columbia. Atmospheric Environment
32, 3457 − 3466.
Fang G.C., Wu, Y.S., Chang, C.N., Ho, T.T., 2006. A study of polycyclic
aromatic hydrocarbons concentrations and source identifications by
methods of diagnostic ratio and principal component analysis at
Taichung chemical Harbor near Taiwan Strait. Chemosphere, in
press.
Fehsenfeld, F. C., Coauthors, 1992. Emissions of volatile organic
compounds form vegetation and implications for atmospheric
chemistry. Global Biogeochemical Cycles 6, 389 − 430.
Feng, Y., Wen, S., Wang, X., Sheng, G., He, Q., Tang, J., Fu, J., 2004.
Indoor and outdoor carbonyl compounds in the hotel ballrooms in
Guangzhou, China. Atmospheric Environment 38, 103 − 112.
Feng, Y., Wen, S., Chen, Y., Wang, X., Lü, H.,Bi, X., Sheng G., Fu, J.,
2005. Ambient levels of carbonyl compounds and their sources in
Guangzhou, China. Atmospheric Environment 39, 1789 − 1800.
Ferrari, C. P., Kaluzny, P., Roche, A., Jacob, V., Foster, P., 1998. Aromatic
hydrocarbons and aldehydes in the atmosphere of Grenoble, France.
Chemosphere 37, 1587 − 1601.
Godoy, M.L.D.P., Godoy, J.M., Artaxo, P., 2005. Aerosol source
apportionment around a large coal fired power plant- Thermoelectric
Complex Jorge Lacerda, Santa Catarina, Brazil. Atmospheric
Environment 39, 5307 − 5324.
Greenberg, J. P., Guenther, A., Zimmerman, P., Baugh, W., Geron, C.,
Davis, K., Helmig, D., Klinger, L.F., 1999. Tethered balloon
measurements of biogenic VOCs in the atmospheric boundary layer.
Atmospheric Environment 33, 855 − 867.
Grosjean, D., 1982. Formaldehyde and other carbonyls in Los Angeles
ambient air. Environment Science and Technology 16, 254 − 262.
Grosjean, D., William II, E.L., Grosjean, E., 1993a. Atmospheric
chemistry of isoprene and of its carbonyl products. Environmental
Science and Technology 27, 830 − 840.
Grosjean, D., Williams II, E.L., Grosjean, E., 1993b. Peroxyacyl nitrates
at southern California mountain forest locations. Environmental
Science and Technology 27, 110 − 121.
Grosjean, D., Grojean, E., Seinfeld, J.H., 1996a. Atmospheric chemistry
of 1-octene, 1-decene, and cyclohexene: gas-phase carbonyl and
peroxyacyl nitrate products. Environmental Science and Technology
30, 1038 − 1047.
Grosjean, E., Grojean, D., Fraser, M.P., Cass, G.R., 1996b. Air quality
model evaluation data for organics. 2. C1 - C14 carbonyls in Los
Angeles air. Environmental Science and Technology 30, 2687 –
2703.
Grosjean, D., Grosjean, E., Moreira, L.F.R., 2002. Speciated ambient
carbonyls in Rio de Janeiro, Brazil. Environmental Science and
Technology 36, 1389 – 1395.
Guo, H., Lee, S.C., Ho, K.F., Wang, X.M., Zou, S.C., 2003.
Particle-associated polycyclic aromatic hydrocarbons in urban air of
Hong Kong. Atmospheric Environment 37, 5307 − 5317.
Guo, H., Wang, T., Blake, D.R., Simpson, I.J., Kwok, Y.H., Li, Y.S., 2006.
Regional and local contributions to ambient non-methane volatile
organic compounds at a polluted rural/coastal site in Pearl River
Delta, Chia. Atmospheric Environment 40, 2345 − 2359.
Guo, H., Wang, T., Louie, P.K.K., 2004a. Source apportionment of
ambient non-methane hydrocarbons in Hong Kong: Application of a
principal component analysis/absolute principal compound scores
(PCA/APCS) receptor model. Environmental Pollution 129, 489 −
498.
Guo, H., Wang, T., Simpson, I.J., Blake, D. R., Yu, X.M., Kwork, Y.H., Li,
Y.S., 2004b. Source contributions to ambient VOCs and CO at a
rural site in eastern China. Atmospheric Environment 38, 4551 −
4560.
Guyon, P., Graham, B., Robertsw, G.C., Mayol-Bracero, O.L., Maenhaut,
W., Artaxo, P., Andreae, M.O., 2004. Source of optically active
aerosol particles over the Amazon forest. Atmospheric Environment
38, 1039 − 1051.
Ho, K.F., Lee, S.C., Chiu, G.M.Y., 2002. Characterization of selected
volatile organic compounds, polycyclic aromatic hydrocarbons and
carbonyl compounds at a roadside monitoring station. Atmospheric
Environment 36, 57 − 65.
Ho, K.F., Lee, S.C., Louie, P.K.K., Zou, S.C., 2002. Seasonal variation of
carbonyls compoundconcentratio ns in urban area of Hong Kong.
Atmospheric Environment 36, 1259 − 1265.
Hodgson, A.T., Faulker, D., Sullivan, D. P., DiBartolomeo, D. L., Russell,
M. L., Fisk, W. J., 2003. Effect of outside air ventilation rate on
volatile organic compound concentrations in a call center.
Atmospheric Environment 37, 5517 − 5527.
Hung, I.F., Chung, H., Hung, C.K., Huang, K.C., Tsai, C.J., 1996.
Organic aerosols in a semiconductor manufacturing facility. Journal
of Aerosol Science 27, 657.
Hsu, J. H., 2000. The Relationship between Volatile Organic Profiles and
Emission Sources in Ozone Episode Regions. Ph. D. dissertation,
Department of Environmental Engineering, National Cheng Kung
University, Tainan, Taiwan.
Hurley, P., 2002a, The Air Pollurion Model (TAPM) Version 2. Part 1:
Technical Description. CSIRO Atmospheric Research, Private Bag 1,
Aspendale, Vic 3195, Australia.
Hurley, P., 2002b, The Air Pollurion Model (TAPM) Version 2. User
Manual. CSIRO Atmospheric Research Internal Paper NO.25.
Hurley, P., Manins, P., Lee, S., Boyle, R., Ng, Y. L., Dewundege, P., 2003,
Year-long, high-resolution, urban airshed modelling: verification of
TAPM predictions of smog and particles in Melbourne, Australia.
Atmospheric Environment 37, 1899 − 1910.
Ito, K., Xue, N., Thurston, G., 2004. Spatial variation of PM2.5 chemical
species and source-apportioned mass concentrations in New York
City. Atmospheric Environment 38, 5269 − 5282.
Kalaitzoglou, M., Terzi, E., Samara, C., 2004. Patterns and sources of
particle-phase aliphatic and polycylic aromatic hydrocarbons in
urban and rural sites of western Greece. Atmospheric Environment
38, 2545 − 2560.
Kalivoda, M.T., Feller, R., 1995. ATEMIS- A Tool for Calculating Air
Traffic Exhaust Emission and Its Application, The Science of Total
Environment 169, 241–247.
Kean, A. J., Grosjean, E., Grosjean, D., Harley, R.A., 2001. On-road
measurement of carbonyls in California light-duty vehicle emissions.
Environment Science and Technology 35, 4198 − 4204.
Kesselmeier, J., Bode, K., Hofmann, U., Müller, H., Schäfer, L., Wolf, A.,
Ciccioli, P., Brancaleoni, E., Cecinato, A., Frattoni, M., Foster, P.,
Ferrari, C., Jacob, V., Fugit, J.L., Dutaur, L., Simon, V., Torres, L.,
1997. Emission of short chained organic acids, aldehydes and
monoterpenes from Quercus ilex L. and Pinus pinea L. in relation to
physiologica activities, carbon budget and emission algorithms.
Atmospheric Environment 31, 119 − 133.
Kohno, H., Tamura, M., Honda, S., Shibuya, A., Yamamoto, T., Berezin,
A.A., Chang, J.S., 1997. Generation of aerosol particales in the
process of xylene and TCE decomposition from air stream by a
ferroelectric packed-bed barrier discharge reactor. Journal of Aerosol
Science 28, 413 − 414.
Konig, G., Brunda, M., Puxbaum, H., 1995. Relative Contribution of
Oxygenated Hydrocarbons to the Total Biogenic VOCs Emission of
Selected Mid-European Agricultural and Natural Plant Species.
Atmospheric Environment 29, 861 − 874.
Lai, C.H., Chen, K.S., Ho, Y.T., Chou, M.S., 2004. Characteristics of
C2-C5 hydrocarbons in the air of urban Kaohsiung, Taiwan.
Atmospheric Environment 38, 1997 − 2011.
Lai, C.H., Chen, K.S., Ho, Y.T., Peng, Y.P., Chou, Y.M., 2005. Receptor
modeling of source contributions to atmospheric hydrocarbons in
urban Kaohsiung, Taiwan. Atmospheric Environment 39, 4543 −
4559.
Lai, C.H., Chen, K.S., Tsai P.C., 2006. Health Risk Assessment and
Emission Source of Hazardous Air Pollutants in Kaohsiung City.
Journal of Central Taiwan University of Science and Technology, in
press.
Levy, H., 1971. Normal atmosphere: large radical and formaldehyde
concentration predicted. Science 173, 141 − 143.
Miller, S.L., Anderson, M.J., Daly, E.P., Milford, J.B., 2002. Source
apportionment of exposures to volatile organic compounds. I.
Evaluation of receptor models using simulated exposure data.
Atmospheric Environment 36, 3629–3641.
Montzakz, S.A,, Trainer, M, Goldan, P.D., Kuster, W.C., Fehsenfeld, F. C.,
1993. Journal of Geophysical Research. 98, 1101 − 1993.
Müller, K., 1997. Determination of aldehydes and ketones in the
atmosphere-a comparative long time study at an urban and a rural
site in eastern Germany. Chemosphere 35, 2093 − 2106.
Nelson, P.F., Quigley, S.M., 1982. Non-methane hydrocarbons in the
atmosphere of Sydney, Australia. Environmental Science and
Technology 16, 650 − 655.
Possanzini, M., Palo, V.D., Petricca, M., Fratarcangeli, R., Brocco, D.,
1996. Measurements of Lower Carbonyls in Rome Ambient Air.
Atmospheric Environment 30, 3757 − 3764.
Poulopoulos, S., Philippopoulos, C., 2000. Influence of MTBE addition
into gasoline on automotive exhaust emission. Atmospheric
Environment 34, 4781 – 4786.
Revitt, D.M., Muncaster, G.M., Hamilton, R.S., 1999. Trends in
hydrocarbon fleet emission at four UK highway sites. The Science
of Total Environment 235, 91 − 99.
Roumegoux, J.P., 1995. Calcul des emission unitaires de polluants des
vehicules utilitaires. The Science of Total Environment 169, 205 −
211.
Schulte, J.H., 1964. Sealed environment in relation to health and disease.
Archives of Environment Health 8, 438 − 452.
Schauer, J.J., Kleeman, M.J., Cass, G.R., Simoneit, B.R.T., 1999a.
Measurement of emissions from air pollution sources. 2. C1 though
C30 organic compounds from medium duty diesel trucks.
Environmental Science and Technology 33, 1578 − 1587.
Schauer, J.J., Kleeman, M.J., Cass, G.R., Simoneit, B.R.T., 2001.
Measurement of emissions from air pollution sources. 3. C1–C29
organic compounds from fireplace combustion of wood.
Environmental Science and Technology 35, 1716 − 1728.
Schauer, J.J.; Kleeman, M.J.; Cass, G.R.; Simoneit, B.R.T., 2002.
Measurement of Emissions from Air Pollution Sources. 4. C1 - C27
Organic Compounds from Cooking with Seed Oils. Environment
Science and Technology 36, 567 − 575.
Schneeweiss, H. and Mathes, H. 1995. Factor analysis and principal
compounds. Journal of Multivariate Analysis 55, 105 − 124.
Seinfeld, J.H., 1986. Atmospheric Chemistry and Physics of Air Pollution.
John Wiley, New York.
Senaratne, I., and Shooter, D., 2004. Elemental composition in source
identification of brown haze in Auckland, New Zealand.
Atmospheric Environment 38, 3049 − 3059.
Sexton, K., Westberg, H.H., 1983. Photochemical ozone formation from
petroleum refinery emission. Atmospheric Environment 17, 467 −
475.
Shepson, P.B., Hastie, D.R., Schiff, H. I., Polizzi, M., Bottenheim, J.W.,
Anlauf, K., Mackay, G.I., Karecki, D.R., 1991. Atmospheric
concentrations and temporal variations of C1 - C3
carbonyl-compounds at 2 rural sites in Central Ontario. Atmospheric
Environment Part A-General Topics 25, 2001 − 2015.
Shimoda, M., Nakada, N., Nakashima, M., Osajima, Y., 1997.
Quantitative comparison of volatile flavor compounds in
deep-roasted sesame seedoil. Journal of Agriculture and Food
Chemistry 45, 3193 − 3196.
Siegl, W.O., Hammerle, R.H., Herrmann, H.M., Wenclawiak, B.W.,
Luers-Jongen, B., 1999. Organic emission profile for a light-duty
diesel vehicle. Atmospheric Environment 33, 797 − 805.
Simoneit, B.R.T., 1999a. Measurement of emissions from air pollution
sources. 2. C1 thought C30 organic compounds from medium duty
diesel trucks. Environment Science and Technology 33, 1578 −
1587.
Singh, H.B., Ohara, D., Herlth, D., Sachse, W., Blake, D.R., Bradshaw,
J.D., Kanakidou, M. and Crutzen, P.J., 1994. Acetone in the
Atmosphere-Distribution, Sources, and Sinks. J. of Geophy.
Res.-Atmos.99, 1805 − 1819.
Sitting, M., 1974. Aldehydes. Pollution Detection and Monitoring
Handbook, Noyes Data Corp., Park Ridge, New Jersey.
SPECIATE 3.1. U.S. Environmental Protection Agency, released in
October 1999.
(http://www.epa.gov/un/chief/software/speciate/index.html).
Suschka, J., Mrowiec, B., Kuszmider, G., 1996. Volatile organic
compounds (VOC) at some sewage treatment plants in Poland.
Water Science and Technology 33, 273 − 276.
Tanner, R.L., Miguel, A.H., de Andrade, J.B., et al., 1988. Atmospheric
chemistry of aldehydes: enhanced peroxyacetyl nitrate formation
from ethanol-fueled vehicular emissions. Environment Science and
Technology 22, 1026 − 1034.
TEDS5.1,2003,Taiwan Emission Data System (TEDS)5.1,中鼎工程
公司。
Toll, I., Baldasano, J.M., 2000. Modelling of photochemical air pollution
in the Barcelona area with highly disaggregated anthropogenic and
biogenic emission. Atmospheric Environment 34, 3069 − 3084.
Vallius, M., Lanki, T., Tiittanen, P., Koistinen, K., Ruuskanen, J.,
Pekkanen, J., 2003. Source apportionment of urban ambient PM2.5
in two successive measurement campaigns in Helsinki, Finland.
Atmospheric Environment 37, 615 − 623.
Villanueva, I., Popp, C.J., Martin, R.S., 2004. Biogenic emissions and
ambient concentrations of hydrocarbons, carbonyl compounds and
organic acids from ponderosa pine and cottonwood trees at rural and
forested sites in Central New Mexico. Atmospheric Environment 38,
249 − 260.
Viskari, E.L., Matti Vartiainen and Pertti Pasanen, 2000. Seasonal and
diurnal variation in formaldehyde and acetaldehyde concentrations
along a highway in eastern finland. Atmospheric Environment 34,
917 − 923.
Wang, J.L., Ding, W.H., Chen, T.Y., 2000. Source determination of light
non-methane hydrocarbons by simultaneous multi-site sampling in a
metropolitan Area. Chemosphere-Global Change Science 2, 11 − 22.
Wiedinmyer, C., Strange, I.W., Estes, M., Yarwood, G., Allen, D.T., 2000.
Biogenic hydrocarbon emission estimates for North Central Texas.
Atmospheric Environment 34, 3419 − 3435.
Wildt, J., Kobel, K., Schuh, G., Heiden, A.C., 2003. Emissions of
oxygenated volatile organic compounds from plants Part II:
emissions of saturated aldehydes. Journal of Atmospheric Chemistry
45, 173 − 196.
Williams, I.D., Revitt, D.M., Hamilton, R.S., 1996. A comparison of
carbonyl compound concentrations at urban roadside and indoor
sites. The Science of the Total Environment 189/190, 475 − 483.
Zhang, J., Smith, K.R., 1999. Emissions of carbonyl compounds from
various cook stoves in China. Environmental Science and
Technology 33, 2311 − 2320.
王俊凱,1999,台灣地區大氣氣膠特性之研究-高雄、台北都會區氣
膠特性與污染來源推估,碩士論文,國立中央大學/環境工程研
究所。
吳立言,2002,「高雄地區固定源揮發性有機物指紋及光化反應潛勢
之探討」,碩士論文,國立中山大學環境工程研究所。
吳易儒,2003,「民俗活動對於空氣品質之影響」,碩士論文,國立成
功大學環境工程學系。
吳義林、林清和,2002,「台南縣臭氧防治策略規劃-敏感性物種之調
查研究」,台南縣環境保護局。
周明顯、樓基中、袁中新、賴嘉祥、何宜達、蔡詠安、吳立言,2001,
「高雄市臭氧生成前驅物控制及減量策略研擬」,高雄市政府環
境保護局。
林巧云,1998,「醛酮類對血管收縮素功能影響的先驅研究」,碩士論
參-13
文,國立台灣大學環境衛生研究所。
張能復、余泰毅、梁佳修,1998,「以主成分分析法分類南高屏地區
臭氧污染事件日」,第15 屆空氣污染控制技術研討會,國立中央
大學環境工程系。
莊桓齊、鄭福田,2001,「台灣地區臭氧敏感性光化指標方法之建立
與探討」,碩士論文,國立台灣大學環境工程研究所。
陳康興、何宜達、蔡詠安、賴嘉祥,2002,「氣象條件與臭氧事件日
相關性之探討」,第十九屆空氣污染防制技術研討會論文集,國
立台灣大學。
陳康興、何宜達、賴嘉祥、蔡詠安,2001,「光化學臭樣模式 (CAMx)
之發展與應用」,2001 年空氣品質模式技術研討會論文集,2001
年11 月23 − 24 日,高雄市。
陳康興、周明顯、何宜達、賴嘉祥、蔡詠安,2001,「高雄地區臭氧
事件日之模式模擬及分析」,第十八屆空氣污染防制技術研討會
論文集,p. 2 − 36,民國90 年12 月14 − 15 日, 國立高雄第一科
技大學。
陳康興、陳瑞仁、林銳敏、黃國林,2005,「高屏地區大氣細微粒 (PM2.5)
特徵及來源分析研究高屏地區大氣細微粒 (PM2.5)化學組成特
性時空變化調查分析、來源模擬及成因探討研究」,行政院國家
科學委員會期中報告。
陳康興、彭彥彬、呂佩真、賴嘉祥、何宜達,2004,「高屏地區臭氧
敏感物種與光化指標之調查研究」,中華民國環境工程學會第十
六屆年會及研討會論文摘要集(第廿一屆空氣污染控制技術研討
會),p. 2 − 64,民國93 年11 月26–27 日,國立成功大學。
陳康興、彭彥彬、倪國敦,2004,「高高屏地區臭氧趨勢分析與氣象
因子相關性之探討」,中華民國環境工程學會第十六屆年會及研
討會論文摘要集(第廿一屆空氣污染控制技術研討會),p. 2 −
65,民國93 年11 月26 − 27 日,國立成功大學。
陳康興、彭彥彬、廖琇怡、王文正、王信凱,2005,「高雄市臭氧特
性與氣象因子之相關性探討」,中華民國環境工程學會第十七屆
年會及研討會論文摘要集(第廿二屆空氣污染控制技術研討
會),p. 276,民國94 年11 月18 − 19 日,國立中央大學。
陳康興、謝連德、賴嘉祥、何宜達、彭彥彬,2003,「屏東地區揮發
性有機物空氣污染調查檢測計畫」,屏東縣環境保護局。
陳順予,2000,「多變量分析」二版,華泰書局。
陳瑞仁、陳康興、袁中新、林傑、賴嘉祥、何宜達、彭彥彬,2002,
「屏東地區空氣品質劣化原因探究及改善策略研擬」,屏東縣環
境保護局。
楊明益,2000,「高屏地區大氣醛酮化合物與臭氧污染事件關聯性」,
碩士論文,國立成功大學環境工程學系。
劉育穎,2001,「機車排放醛酮類化合物特徵與光化反應性研究」,碩
士論文,國立成功大學環境工程學系。
賴嘉祥,2002,「高雄市大氣中C2-C15 揮發性有機物特徵之時空分布
及其受體模式之分析」,碩士論文,國立中山大學環境工程研究
所。
謝祝欽、王麗婷、洪世皇、黃仍鈺,1998,「南台灣地區國有林地異
戊二烯與單帖類排放量推估「與最大臭氧生成潛勢之研究」,第
15 屆空氣污染控制技術研討會,國立中央大學環境工程系。
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