摘要
由兩階段酯化反應合成兩種未飽和聚酯預聚合物，就硬段而言，先加入間苯二甲酸與1,2-丙二醇進行酯化，第二階再加入馬林酸酐進行酯化反應，所合成共聚酯之玻璃轉移溫度約13

Abstract
Two kinds of unsaturated polyesters’ prepolymers were synthesized via two steps. For the hard segment, isophthalic acid was reacted with 1,2-propanediol first, then maleic anhydride was added to yield a copolyester with Tg around 13

目錄
目錄 I
Scheme contents III
表目錄 IV
圖目錄 V
摘要 VI
前言 1
研究目的 6
一、文獻探討 7
1.1聚酯熟化 9
1.2熟化後的測試 10
1.3聚合物阻燃機制及演化 11
1.4阻燃性的測試方法發展 14
1.5阻燃層發展現況 15
1.6阻燃層分類及功能上要求 15
1.7阻燃層抑制劑上硝化甘油滲移影響與概念 16
二、研究方法 18
2.1葯品及材料 18
2.2酯化合成 19
2.2.1第一階段聚酯化步驟 20
2.2.2第二階段聚酯化步驟(P-1與P-2) 20
2.2.3未飽和預聚合物(UP-1與UP-2)之製備步驟 21
2.3計算與模型 21
2.3.1氫氧化鉀濃度(Ns)計算 21
2.3.2酸價計算 21
2.3.3氫氧價及數目平均分子量的計算 22
2.3.4反應模型 22
2.4試樣測試 22
2.4.1化學鑑定 25
2.4.2物性測試 26
2.5實驗流程 29
2.5.1實驗流程圖 31
三、結果與討論 32
3.1預聚合物之定性與定量 32
3.1.1預聚合物(P-1與P-2)之FTIR圖譜 32
3.1.2 1H-NMR圖譜 32
3.1.2.1模擬1H-NMR圖譜位置(P-1與P-2) 34
3.1.2.2預聚合物(P-1與P-2)的1H-NMR圖譜 34
3.1.3預聚合物(P-1與P-2)分子量及滴定末端官能基測值 37
3.1.4預聚合物(P-1與P-2)之熱性質 37
3.2正熟化未飽和預聚合物(UP-1、UP-2與兩者各50％混摻)之凝膠時間探討 37
3.3混摻聚酯熟化(CP0-CP10)後之熱穩定性及機械性質 43
3.4混摻聚酯添加填料熟化(CPn-Xn-NPn)後之熱穩定性及機械特性質 44
3.5阻燃層(CP6-M30-NP2與LM-E-NP2)之NG吸收及燒蝕率 44
3.6阻燃層(CP6-M30-NP2與LM-E-NP2)之凝膠時間與放熱峰溫度 54
四、結論 56
附錄 57
附錄 1編碼索引 57
附錄 2標準氫氧化鉀溶液試劑配製法 58
附錄 3酸價之測定法 59
附錄 4氫氧價之測定法 60
附錄 5預聚合物P-1之GPC圖譜 61
附錄 6預聚合物P-2之GPC圖譜 62
附錄 7旋轉黏度計( Brookfield Viscometer )操作步驟 63
附錄 8拉力試驗機( Zwick tensile tester )操作步驟 64
參考文獻 65

參考文獻

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