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博碩士論文 etd-0705105-164008 詳細資訊
Title page for etd-0705105-164008
論文名稱
Title
CuInSe2奈米粉體之合成及混成太陽能電池研製
The Synthesis of CuInSe2 Nano Powders and Fabrication of Hybrid Solar Cells
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
84
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2005-06-27
繳交日期
Date of Submission
2005-07-05
關鍵字
Keywords
銅銦鹽類、閃鋅礦材料、混成太陽能電池
CuInSe2, Chalcopyrite, Hybrid solar cells
統計
Statistics
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中文摘要
本實驗中我們採用Y. Qian等人在Advanced Materials雜誌中發表的CuInSe2粉末製備方式合成不同形貌的CuInSe2粉末。藉由控制合成溫度、反應時間與洗劑(Washing agent)種類,我們成功製備出奈米級(<20nm)的CuInSe2球狀粉末與CuInSe2奈米線,由於藉由控制奈米線的長度能影響CuInSe2材料能階的分布情形,因此將其奈米線
Abstract
We had demonstrated that, by controlling and changing the temperature, reaction time and washing agents, the morphology and powder size of CuInSe2 can be altered considerably. CuInSe2 was synthesized by a solvothermal route as described by Y. Qian et al. By synthesizing nanorods, we can control the distance which the electrons are transported in hybrid solar cell with conjugated polymers. With the tuning of the band gap by controlling the nanorod length, we can increase the opportunity of orbits overlap between the CuInSe2 material and the PBO polymer matrix..
The synthetic temperature 1800C and reaction time 48 hrs are the best condition in our experiment. By using D.I water and ethanol as washing agents, we can find different morphology of spherical and nanowire. However, we fabricate hybrid solar cell by using these CuInSe2 powders in PBO conjugated polymers. By preparing hybrid solution in different concentration and controlling spin coating rate, we fabricate solar cells device successfully. From the I-V characteristics, we can get noticeable characteristics of diode. Then, we calculate the fill factor (F.F.) with the open-circuit voltage(Voc)and short-circuit current(Isc)
目次 Table of Contents
中文摘要……………………………………………..………………..……Ⅰ
英文摘要……………………………………………………..……….….…Ⅱ
總目錄 ………………………………………………………………….….Ⅲ
表目錄 …………………………………………………………………..…Ⅴ
圖目錄 ……………………………………………………………………..Ⅵ
第一章、緒論……………………………………………………………..…1
1.1 前言……………………………………..…………………………...1
1.2 半導體簡介……………………………..………………………..….2
1.3 Ⅰ-Ⅲ-Ⅵ族薄膜太陽能電池之現況與發展…………….…….…….6
1.4 有機混成薄膜太陽能電池之發展與應用………………………….7
1.5 本研究之目的及內容……………………………………………….8
第二章、實驗原理…………………………………………………………...10
2.1 CuInSe2奈米微粉之合成……………...……………………………10
2.2 CuInSe2奈米微粉之生成動力學…………...………………………10
2.3 CuInSe2奈米微粉之粒徑計算……...………………………………14
2.4 CuInSe2奈米微粉之能隙計算……...………………………………14
2.5 CuInSe2奈米微粉之量子效應...…..…………………………….….15
第三章、實驗步驟與分析方法………………………………...…………..18
3.1 CuInSe2奈米微粉之合成步驟……………………………………...18
3.2 CuInSe2奈米微粉
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