以電鍍鋅方式製備Fe/Zn鍍層，再以大氣下溫度400 ℃、425 ℃，時間240秒、300秒條件下進行退火處理，藉由穿透式電子顯微鏡觀察所產生之介金屬化合物。結果顯示介金屬化合物皆以Γ1-Fe3Zn10、Γ2-Fe11Zn39、δ-FeZn10相存在。
以浸鍍鋅(460 ℃)浸鍍3秒獲得Fe/Zn鍍層，表面有明顯單斜柱狀ζ-FeZn13相，再以穿透式電子顯微鏡觀察得到ζ相與基材Fe無明顯的晶相關係。由於鐵極易氧化，即使在低露點處理，鐵表面仍有非常薄的氧化物約10-20奈米，隔絕了Fe與ζ相，因此無法觀察到Fe與ζ相之任何晶向關係。

The specimens were prepared by electro plating Zn on Fe and then annealed at 400 and 450 ℃ for 240 and 300 s in air. The microstructure were studied by transmission electron microscopy (TEM) to analyze the intermetallic compounds. The results showed that Γ1-Fe3Zn10, Γ2 -Fe11Zn39, and δ-FeZn10 have formed.
Another specimens was obtained by hot-dipping in Zn bath at 460 ℃for 3 s. Monoclinic ζ-FeZn13 phase was observed but there is no orientation relationship between ζ phase and Fe. Because iron is easily oxidized even at low-dew point, very thin (10-20 nm) iron oxide formed on the surface. The ζ phase was separated from the Fe substrate and therefore on orientation relationship was observed between them.

論文審定書………………...........................................…………….i
摘要………………………………………………………....…....………ii
Abstract………………….……………………...…………….…….…..iii
目錄………………………………………………………………….…...iv
第一章 前言………………………………………………………..……..1
第二章 文獻回顧…………………………………………………..……..2
2.1 電鍍鋅起源與原理……………………………………….…..…….2
2.2 鍍鋅退火處理………………………………………………...…….6
2.3 介金屬化合物與基材之間的關係………………………...……….7
第三章 實驗方法…………………………………………………..……..9
3.1 試片準備…….............................................................….....9
3.1.1鐵基材之處理……………................................................9
3.1.2電鍍鋅及熱處裡…………………………....…….…………...10
3.2實驗儀器……………………………………………....………….....12
3.2.1 光學顯微鏡............................................................…..12
3.2.2 退火爐........................................................................12
3.2.3 X光繞射分析儀............................................................12
3.2.4 穿透式電子顯微鏡…………………………………….…......13
第四章 結果與討論…………………………………………………......14
4.1 試片表面OM分析………………………….…………………......14
4.2 XRD分析組成…………………………………………………......14
4.3 TEM討論晶相關係……………………………………………......15
第五章 結論………………………………………………………….…..19
第六章 參考文獻………………………………………………….…..…20

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