利用我們合成出的三牙雙苯酚膦化物[OPO]2-及雙牙苯胺膦亞胺化物[NN-iPr]-與伍價鉭、參價鋁金屬起始物反應，可合成相關的金屬錯合物。
首先、合成出具有鹵素的三牙雙苯酚膦化物的金屬錯合物後，可藉由加入不同的反應試劑來取代鹵素。利用加入水可以形成含有氫氧根的取代；改變成與格林納試劑反應後，可以置換成甲基或是乙基的取代。藉由含乙機取代的鉭金屬錯合物在高溫下會進行β氫原子消去反應得到取代基為氫的鉭金屬錯合物。
利用雙牙苯胺膦亞胺化物與正丁基鋰反應後，可以藉由去氫化反應得到含有鋰金屬的錯合物。同樣利用雙牙苯胺膦亞胺化物與三烷基鋁金屬反應後可以成功合成出鋁金屬錯合物。而我們對於這一系列所合成出的金屬錯合物進行結構鑑定與探討。

The preparation and structural characterization of a series of Tantalum complexes supported by 2,2’-phenylphosphinobis(4,6-di-tert-butyl- phenolate) ([OPO]2-) are described. The reaction of Li2[OPO] with TaCl5 produced yellow crystals of [OPO]2TaCl, regardless of the stoichiometry of the starting materials employed. Alkylation of [OPO]2TaCl with a variety of Grignard reagents generated [OPO]2TaR (R = Me, Et). Formation of [OPO]2TaH arise from [OPO]2TaEt undergo β-Hydrogen elimination at 120 oC or reaction of [OPO]2TaCl with LiHBEt3. The solid-state structures of [OPO]2TaCl, [OPO]2TaOH and [OPO]2TaH and the solution of these Tantalum complexes were characterized by X-ray crystallography and multinuclear NMR spectroscopy.

A new chelating N, N ligand family incorporation an anilido- phosphinimine donor set has been designed. The ligand 1-(NHAr)-2-(PPh2=NAr)C6H4 ([NN-iPr]; Ar = 2,6-diisopropylphenyl) was prepared by Staudinger reaction with 2,6-diisopropyl- phenylazide and N-(2-diphenylphosphinopheyl)-2,6-diisopropyl-anilide. Deprotonation of H[NN-iPr] with n-BuLi in THF at -35 oC generated [NN-iPr]Li(THF). The reactions of trialkylaluminum with H[NN-iPr] produced the corresponding dialkyl complexes [NN-iPr]AlMe2 and [NN-iPr]AlEt2. The aluminum complexes were all characterized by 1H, 13C{1H}, 31P{1H}, and 27Al{1H} NMR spectroscopy. The solid-state structures of H[NN-iPr] and [NN-iPr]AlMe2 were determined by X-ray crystallography.

雙苯酚膦化物鉭錯合物
壹、緒論
貳、結果與討論
參、結論
肆、未來展望
伍、實驗部分
陸、參考文獻

苯胺膦亞胺化物鋁錯合物
壹、緒論
貳、結果與討論
參、結論
肆、未來展望
伍、實驗部分
陸、參考文獻

附錄

雙苯酚膦化物鉭錯合物
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