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論文名稱 Title |
鐵鉬碳鈦銲覆合金化塗層之抗高溫磨耗性質研究 Tungsten Inert Gas Arc Welding Fe-Mo-Ti-C Alloying Coatings Composites for High Temperature Applications |
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系所名稱 Department |
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畢業學年期 Year, semester |
語文別 Language |
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學位類別 Degree |
頁數 Number of pages |
88 |
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研究生 Author |
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指導教授 Advisor |
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召集委員 Convenor |
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口試委員 Advisory Committee |
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口試日期 Date of Exam |
2002-07-04 |
繳交日期 Date of Submission |
2002-07-09 |
關鍵字 Keywords |
硬面處理、固態潤滑、高溫磨耗、鎢極惰氣遮護電弧銲覆 self-lubricating coatings, wear, tribological, welding, reinforced, hardfacing |
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統計 Statistics |
本論文已被瀏覽 5706 次,被下載 6554 次 The thesis/dissertation has been browsed 5706 times, has been downloaded 6554 times. |
中文摘要 |
本文是以鎢極惰氣遮護電弧銲覆方式,將預混摻之鐵及鉬金屬粉末,碳粉末、碳化鈦陶瓷粉末,銲覆於S45C中碳鋼基材上。藉由金相組織分析、硬度測量、X光繞射等分析銲覆層組織,並進行環對盤乾摩擦磨耗試驗,評估銲覆層的常溫及高溫之抗磨耗性能,再利用掃描式電子顯微鏡觀察磨耗表面。實驗結果顯示:經鎢極惰氣遮護電弧銲覆銲覆後之銲覆層,合金化塗層中主要為樹枝狀碳化物之凝固組織,主要為M2C及M6C。當預佈塗含碳量提高,C/M莫爾比38.9時,時會有MC相產生。高溫450℃下進行磨耗測試,其環對盤滑動摩擦係數約0.3,每百萬牛頓-米之耗損量為 0.67毫克。實驗中並發現,當有MC相產生會使抗磨耗性質變差,且加入碳化鈦粉末之銲覆層,對耐磨耗性質並未改善。 |
Abstract |
none |
目次 Table of Contents |
目錄 壹、緒論 1-1前言………………………………………………1 1-2文獻回顧…………………………………………3 1-2-1硬面處理方式………………………………………3 1-2-2 磨耗機構……………………………………………5 1-2-3銲覆層合金 ………………………………………7 1-2-4高溫環境下的潤滑機制……………………………9 1-3研究動機與目的……………………………………12 貳、實驗方法與步驟………………………………………14 2-1實驗材料準備………………………………………14 2-2氬銲銲覆處理………………………………………14 2-3 掃瞄式電子顯微鏡(SEM)觀察……………………15 2-4磨耗測試……………………………………………15 2-5硬度試驗……………………………………………16 2-6 X光繞射實驗(XRD)……………………………16 參、結果與討論……………………………………………17 3-1銲覆後試片外觀觀察………………………………17 3-2金相組織觀察………………………………………18 3-3平面硬度量測………………………………………21 3-4 X光繞射分析………………………………………22 3-5 乾摩擦滑動磨耗損失比較………………………23 3-6 潤滑特性比較………………………………………25 3-7磨耗面SEM觀察………………………………………27 3-8 晶體結構分析………………………………………28 肆、結論結論與未來研究方向……………………………30 伍、參考文獻…………………………………………………32 陸、表………………………………………………………36 柒、圖…………………………………………………………41 |
參考文獻 References |
伍、參考文獻 1. E.A馬你欽柯著,何世禹譯, “金屬表面摩擦破壞實質”,國防工業出版社,1990年8月. 2. E. Pagounis,M. Talvite & V.K.Lindroos, “INFLUENCE OF THE METAL/CERAMIC INTERFACE ON THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF HIPed IRON-BASED COMPOSITES”, Composites Science and Technology 56 ,(1996) ,1329-1337. 3. 石淼森,“固體潤滑技術”,中國文化出版社, 1998年3月. 4. Zhao Xingzhong,Liu Jiajun,Zhu Baoliang,Ouyang Jinlin &Xue Qunji, “ Tribological Properties of Tic-Based Ceramic/High speed Steel Pair at High Temperature ”,Ceramic International 24,(1998),13-18. 5. Rabinowicz E. “Friction and Wear of Matrials.New-York”, John Willey and sons, Inc. 1965“ 6. D.F.Moore “Principles and Application of Tribology”,科技圖書股份有限公司,1986. 7. J.F.Archard, J.Appl.Phys, vol.24, 1953,pp.981. 8. D.W.Hoffman and G.H.Meier, “J.Vac Sic Technol”,1982,pp355-358 9. 高一之,卲慧昌,許澤東,“熱作工具鋼之應用及破損案例介紹”, 1997模具技術成果暨論文集. 10. J. Kozlowski, J. Markoski, A. Prajzner, J. Zdanowski “Properties of carbides, nitrides and carbonitride based on Ti and Mo multicomponent layers” Surface Coating Technology 98,(1998),1440-1443. 11. Lalitha R. Katioelli, Arvind Agarwal, Narendra B. Dahotre “Laser surface engineered Tic coating in6061 Al alloy” Applied Surface Science 153 (2000) 65-78 12. Andrew W. barchelor, Loh Nee Lam, Margam Chandrasekaran “Lubrication of stellite at ambient and elevated temperature by transfer film form a graphite slider” Wear 198 (1996) 208-215 13. Y.S .Jin, C.H. Zhou “The effective of high temperature lubrication by in situ formation of graphite/MoS2 films 14. P.J. Blau, B. Dumont, D.N. Braski, T. Jenkins, E.S Zanoria ,M.C. Long “Reciprocationg frication and wear behavior of a ceramic-matrix graphite composite for possible use in diesel engine valve guides” Wear 225-229 (1999) 1338-1349r 198 (1996) 208-215 15. Present progress in the development of low friction coating J.-P Hirvonen ,J. Koskinen ,J.R Jervis ,M NastasiSurface and Coating Technology 80,(1996),139-150 16. Jianjun Wei, Xushou Zhang, Qunji Xue “The tribological properties of ceramic coatings modified by molybdenum film under oil-condition” Thin Solid Film 266,(1995),48-51. 17. V. Randle, “Microtexture Determination and Its applications”, London, Institute of Materials, (1992), 39-91. 18. 林俊仁,國立中山大學材料科學研究所博士論文,中華民國八十五年七月 表面張力校應對高銲深電子束銲接熔池行為之影響 P.7-P.9. 19. J.F.LANCASTER, “METALLURGY OF WELDING” FIFTH EDITION 1993 P.148 20. 張桓,吳春森,林明仁,呂明賢“閥門用耐熱鋼高溫特性研究”2001材料科學年會. 21. 中山大學材料研究所教授 何扭今 “銲接冶金上課講義” 22 Toshimitsu Okane Takateru Umeda “Interface temperature measurement of Mo2C and M6C eutectic carbides in the Fe-Mo-C system“ Science and Technology of advanced Materials2 (2001) 247-251 23 Todd P. St. Clair ,1, S. Ted Oyama , David F. Cox , Shigeki Otani ,Yoshio Ishizawa , Rong-Li Lo , Ken-ichi Fukui , Yasuhiro Iwasawa “Surface characterization of α-Mo2C (0001) ” Surface Science 426 (1999) 187–198 24 Håkan W. Hugosson Department of Physics Uppsala University “Theoretical studies of phase stabilities and electronic structure in molybdenum carbide” 25 林偉邦,盧偉華,曾榮貴,吳林源“以鎢極惰氣遮護電弧銲覆鐵鉬矽碳合金化塗層之研究”2001陸軍官校研討會論文集. |
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