本研究中使用Poly(3-hexylthiophene)(P3HT)為電荷施體 (Donor)及[6,6]-phenyl-C61- butyric acid methyl ester(PCBM)為電荷受體(Acceptor)材料，以攙混 (Blend)的方式溶於二甲苯 (xylene)，將其應用於有機高分子太陽能電池，其元件結構如下：ITO/PEDOT/P3HT：PCBM/Al 在AM1.5G 100 mW/cm2 的模擬太陽光源下量測。在穩定製程中基礎元件回火後功率轉換效率可達2.3%。
為了增加電洞傳輸能力，將高導電率之高分子奈米導電管PANi，塗佈於電洞傳輸層及有機主動層之間作為陽極介面層，其元件結構為：ITO/PEDOT/PANi/P3HT：PCBM/Al，功率轉換效率可自2.3%提升至2.6%。
在不同轉速之下所製作的PANi 層對元件效率有不同的提升，當轉速為4000rpm 時，PANi 厚度約為100Å，元件效率可向上提升60%。因此可得知PANi 可當作良好的有機高分子太陽能電池陽極介面層的材料。

In our works , we used P3HT and PCBM blended in xylene as donor and acceptor materials for polymer solar cells . For the standard devices with the configuration of ITO/PEDOT/P3HT：PCBM/Al , the power conversion efficiency of 2.3% is achieved under AM1.5 100 mW/cm2 illumination .
In order to enhance the hole transportation , we used PANi nanotube , which has high conductivity , as an anode interlayer between the PEDOT：PSS layer and the organic active layer . The device structure was
ITO/PEDOT/PANi/P3HT:PCBM/Al , and the power conversion efficiency increased from 2.3% to 2.6% .
The efficiency of polymer solar cell was also increased with different rpm by using spin-coating process . For devices , at the process
parameters under 4000rpm and 100Å thickness of PANi , the power conversion efficiency was 60% higher than that of standard device .
We suggested that PANi can act as a good anode interlayer material for polymer solar cells .

誌 謝.................................................... I
中文摘要............................................... III
Abstract ................................................ IV
目錄..................................................... V
圖目錄................................................. VII
表目錄................................................... X
第一章 緒論.............................................. 1
1-1 新能源的需求.......................................1
1-2 有機太陽能電池簡介.................................5
1-3 有機太陽能電池結構演進.............................7
1-4 有機太陽能電池材料簡介............................14
1-5 高分子導電聚苯胺管Polyanilines(PANi)簡介..........16
1-6 研究動機..........................................18
附錄 奈米導電聚苯胺管(PANi)製備.......................21
第二章 基本理論......................................... 23
2-1 轉移機制..........................................23
2-2 光電轉換原理......................................25
2-3 太陽光模擬........................................30
2-4 太陽電池等效電路..................................36
2-5 光電特性參數......................................38
第三章 實驗流程......................................... 43
3-1 實驗架構..........................................43
3-2 實驗藥品..........................................45
3-3 製程儀器..........................................48
3-4 量測分析儀器......................................50
3-5 實驗步驟..........................................63
第四章 結果與討論....................................... 74
4-1 材料分析結果與討論................................74
4-2 元件製程結果與討論................................90
4-3 綜合分析與討論...................................102
第五章 總結............................................ 104
參考文獻............................................... 105

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