論文使用權限 Thesis access permission:校內校外均不公開 not available
開放時間 Available:
校內 Campus:永不公開 not available
校外 Off-campus:永不公開 not available
論文名稱 Title |
二價鎳與二價鉑的雙(2-二苯基膦苯)醯胺錯合物 Bis(2-diphenylphosphinophenyl)amide Complexes of Ni(II) and Pt(II) |
||
系所名稱 Department |
|||
畢業學年期 Year, semester |
語文別 Language |
||
學位類別 Degree |
頁數 Number of pages |
89 |
|
研究生 Author |
|||
指導教授 Advisor |
|||
召集委員 Convenor |
|||
口試委員 Advisory Committee |
|||
口試日期 Date of Exam |
2004-06-10 |
繳交日期 Date of Submission |
2004-07-20 |
關鍵字 Keywords |
鉑、鎳、膦、醯胺、錯合物 amide, platinum, nickel, complex, phosphine |
||
統計 Statistics |
本論文已被瀏覽 5692 次,被下載 0 次 The thesis/dissertation has been browsed 5692 times, has been downloaded 0 times. |
中文摘要 |
一系列二價鎳與二價鉑的雙(2-二苯基膦苯)醯胺錯合物已被合成,在對二價鎳一系列錯合物的研究中有以下發現。首先,含鹵基的錯合物 (包括氯化物、溴化物、碘化物) 可以在空氣中穩定存放。在含碳氫配位基的錯合物方面,我們也成功的合成出含烷基(alkyl)與芬基(aryl)配位基的錯合物。其中尤其以含有 |
Abstract |
A series of nickel(II) and Pt(II) complexes supported by the bis(2-diphenylphosphinophenyl)amide ligand, [PNP]─ have been prepared. In Nickel(II) chemistry, the halide complexes are both air and water stable. The nickel(II) alkyl and aryl derivatives were presented including those in which the alkyl contains |
目次 Table of Contents |
List of figures / VI List of tables / VII I. Introduction / 1 II. Experimental section / 4 i. Chemicals / 4 ii. Instrumentation / 7 iii. Synthesis / 9 1 Synthesis of [PNP]Li(THF)2 / 9 2 Synthesis of [PNP]NiCl / 10 3 Synthesis of [PNP]NiBr / 14 4 Synthesis of [PNP]NiI / 16 5 Synthesis of [PNP]NiMe / 18 6 Synthesis of [PNP]NiCH2Si(CH3)3 / 19 7 Synthesis of [PNP]NiPh / 20 8 Synthesis of [PNP]NiEt / 21 9 Synthesis of [PNP]NiiBu / 23 10 Synthesis of [PNP]NinBu / 24 11 Synthesis of [PNP]NiOtBu / 25 12 Synthesis of NaOPh / 26 13 Synthesis of [PNP]NiOPh / 27 14 Synthesis of NaSPh / 28 15 Synthesis of [PNP]NiSPh / 28 16 Synthesis of [PNP]NiNHPh / 30 17 Synthesis of [PNP]NiNHtBu / 31 18 Synthesis of [PNP]Ni(O2CPh) / 32 19 Synthesis of [PNP]NiOTf / 33 20 Synthesis of [(PNP)NiPy]OTf / 35 21 Synthesis of PtCl2(SMe2)2 / 36 22 Synthesis of [PNP]PtCl / 37 23 Synthesis of [PNP]PtMe / 38 24 Synthesis of [PNP]PtPh / 40 25 Synthesis of [PNP]PtOTf / 43 26 Synthesis of [(PNP)Pt(NCMe)]OTf / 44 27 Synthesis of [(PNP)PtPy]OTf / 45 28 Synthesis of [(PNP)Pt(dabco)]OTf / 46 III. Results and discussion / 47 i. Synthesis of lithium amide complex / 47 ii. Synthesis of [PNP]NiX complexes / 50 iii. Synthesis of [PNP]NiR complexes / 54 iv. Synthesis of amido, alkoxo, thiolate complexes / 57 v. Reactivity of [PNP]NiMe and [PNP]NiOTf / 59 vi. C-X bond activation / 61 vii. Synthesis of Pt(II) complexes / 65 IV. Conclusions / 69 V. References / 70 VI. Appendix / 74 i. Synthesis of [PNP]NiCCH / 74 ii. Synthesis of [PNP]PtnBU / 75 |
參考文獻 References |
1. van der Boom, M. E.; Milstein, D. Chem. Rev. 2003, 103, 1759-1792. 2. Gupta, M.; Hagen, C.; Kaska, W. C.; Flesher, R.; Jensen, C. M. J. Chem. Soc., Chem. Commun. 1996, 2083. 3. Gupta, M.; Hagen, C.; Kaska, W. C.; Cramer, R. E.; Jensen, C. M. J. Am. Chem. Soc. 1997, 119, 840. 4. Jensen, C. M. Chem. Commun. 1999, 2443. 5. Lee, D. W.; Kaska, W. C.; Jensen, C. M. Organometallics 1998, 17, 1. 6. Liu, F.; Pak, E. B.; Singh, B.; Jensen, C. M.; Goldman, A. S. J. Am. Chem. Soc. 1999, 121, 4086. 7. Morales-Morales, D.; Lee, D. W.; Wang, Z.; Jensen, C. M. Organometallics 2001, 20, 1144. 8. Xu, W. W.; Rosini, G. P.; Gupta, M.; Jensen, C. M.; Kaska, W. C.; Krogh-Jespersen, K.; Goldman, A. S. Chem. Commun. 1997, 2273. 9. Haenel, M. W.; Oevers, S.; Angermund, K.; Kaska, W. C.; Fan, H.-J.; Hall, M. B. Angew. Chem., Int. Ed. 2001, 40, 3596. 10. Haenel, M. W.; Oevers, S.; Angermund, K.; Kaska, W. C.; Fan, H.-J.; Hall, M. B. Angew. Chem., Int. Ed. 2001, 40, 3596. 11. Kiewel, K.; Liu, Y. S.; Bergbreiter, D. E.; Sulikowski, G. A. Tetrahedron Lett. 1999, 40, 8945. 12. Morales-Morales, D.; Grause, C.; Kasaoka, K.; Redo´n, R.; Cramer, R. E.; Jensen, C. M. Inorg. Chim. Acta 2000, 300-302, 958. 13. Morales-Morales, D.; Redo´n, R.; Yung, C.; Jensen, C. M. Chem. Commun. 2000, 1619. 14. Ohff, M.; Ohff, A.; van der Boom, M. E.; Milstein, D. J. Am. Chem. Soc. 1997, 119, 11687. 15. Beletskaya, I. P.; Chuchurjukin, A. V.; Dijkstra, H. P.; van Klink, G. P. M.; van Koten, G. Tetrahedron Lett. 2000, 41, 1075 16. Miyazaki, F.; Yamaguchi, K.; Shibasaki, M. Tetrahedron Lett. 1999, 40, 7379. 17. Heck, R. F. Palladium Reagents in Organic Synthesis; Benchtop Edition; Academic Press: London, 1990. 18. Beletskaya, I. P.; Cheprakov, A. V. Chem. Rev. 2000, 100, 3009. 19. Crisp, G. T. Chem. Soc. Rev. 1998, 27, 427. 20. Fryzuk, M. D. Can. J. Chem. 1992, 70, 2839-2845. 21. Fryzuk, M. D.; Haddad, T. S.; Rettig, S. J. Organometallics 1992, 11, 2967-2969. 22. Fryzuk, M. D.; Leznoff, D. B.; Rettig, S. J.; Thompson, R. C. Inorg. Chem. 1994, 33, 5528-5534. 23. Fryzuk, M. D.; Mylvaganam, M.; Zaworotko, M. J.; MacGillivray, L. R. Organometallics 1996, 15, 1134-1138. 24. Fryzuk, M. D.; Giesbrecht, G.; Rettig, S. J. Organometallics 1996, 15, 3329-3336. 25. Fryzuk, M. D.; Giesbrecht, G. R.; Olovsson, G.; Rettig, S. J. Organometallics 1996, 15, 4832-4841. 26. Fryzuk, M. D.; Giesbrecht, G. R.; Rettig, S. J. Organometallics 1997, 16, 725-736. 27. Fryzuk, M. D.; Leznoff, D. B.; Ma, E. S. F.; Rettig, S. J.; Young, V. G. Organometallics 1998, 17, 2313-2323. 28. Fryzuk, M. D.; Leznoff, D. B.; Thompson, R. C.; Rettig, S. J. J. Am. Chem. Soc. 1998, 120, 10126-10135 29. Fryzuk, M. D.; Carter, A.; Rettig, S. J. Organometallics 1992, 11, 469-472. 30. Ozerov, O. V.; Ferard, H. F.; Watson, L. A.; Huffman, J. C.; Caulton, K. G. Inorg. Chem. 2002, 41, 5615-5625. 31. Fryzuk, M. D.; Haddad, T. S.; Rettig, S. J. Organometallics 1991, 10, 2026-2036. 32. Liang, L.-C.; Lin, J.-M.; Hung, C.-H. Organometallics 2003, 22, 3007-3009. 33. Periana, R. A.; Taube, D. J.; Gamble, S.; Taube, H.; Satoh, T.; Fujii, H. Science 1998, 280, 560-564. 34. Periana, R. A.; Taube, D. J.; Evitt, E. R.; Loffler, D. G.; Wentrcek, P. R.; Voss, G.; Masuda, T. Science 1993, 259, 340-343. 35. Gol’dshleger, N. F.; Es’kova, V. V.; Shilov, A. E.; Shteinman, A. A. Zh. Fiz. Khim. 1972, 46, 1353-1354 (English translation 1972, 46, 785-786). 36. Shilov, A. E.; Shul’pin, G. B. ActiVation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes; Kluwer Academic Publishers: Dordrecht, 2000. 37. Labinger, J. A.; Herring, A. M.; Lyon, D. K.; Luinstra, G. A.; Bercaw, J. E.; Horvath, I. T.; Eller, K. Organometallics 1993, 12, 895-905. 38. Hill, G. S.; Irwin, M. J.; Levy, C. J.; Redina, L. M.; Puddephat, R. J.; Inorg. Synth., 1998, 32, 149-153. 39. Fryzuk, M. D.; Macneil, P. A.; Rettig, S. J.; Secco, A. S.; Trotter, J. Organometallics 1982, 1, 918-930. 40. Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 3rd ed.; Wiley-Interscience: New York, 2001; pp 260-262. |
電子全文 Fulltext |
本電子全文僅授權使用者為學術研究之目的,進行個人非營利性質之檢索、閱讀、列印。請遵守中華民國著作權法之相關規定,切勿任意重製、散佈、改作、轉貼、播送,以免觸法。 論文使用權限 Thesis access permission:校內校外均不公開 not available 開放時間 Available: 校內 Campus:永不公開 not available 校外 Off-campus:永不公開 not available 您的 IP(校外) 位址是 54.225.56.41 論文開放下載的時間是 校外不公開 Your IP address is 54.225.56.41 This thesis will be available to you on Indicate off-campus access is not available. |
紙本論文 Printed copies |
紙本論文的公開資訊在102學年度以後相對較為完整。如果需要查詢101學年度以前的紙本論文公開資訊,請聯繫圖資處紙本論文服務櫃台。如有不便之處敬請見諒。 開放時間 available 已公開 available |
QR Code |