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博碩士論文 etd-0720104-224114 詳細資訊
Title page for etd-0720104-224114
論文名稱
Title
二價鎳與二價鉑的雙(2-二苯基膦苯)醯胺錯合物
Bis(2-diphenylphosphinophenyl)amide Complexes of Ni(II) and Pt(II)
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
89
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2004-06-10
繳交日期
Date of Submission
2004-07-20
關鍵字
Keywords
鉑、鎳、膦、醯胺、錯合物
amide, platinum, nickel, complex, phosphine
統計
Statistics
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中文摘要
一系列二價鎳與二價鉑的雙(2-二苯基膦苯)醯胺錯合物已被合成,在對二價鎳一系列錯合物的研究中有以下發現。首先,含鹵基的錯合物 (包括氯化物、溴化物、碘化物) 可以在空氣中穩定存放。在含碳氫配位基的錯合物方面,我們也成功的合成出含烷基(alkyl)與芬基(aryl)配位基的錯合物。其中尤其以含有
Abstract
A series of nickel(II) and Pt(II) complexes supported by the bis(2-diphenylphosphinophenyl)amide ligand, [PNP]─ have been prepared.
In Nickel(II) chemistry, the halide complexes are both air and water stable. The nickel(II) alkyl and aryl derivatives were presented including those in which the alkyl contains
目次 Table of Contents
List of figures / VI
List of tables / VII
I. Introduction / 1
II. Experimental section / 4
i. Chemicals / 4
ii. Instrumentation / 7
iii. Synthesis / 9
1 Synthesis of [PNP]Li(THF)2 / 9
2 Synthesis of [PNP]NiCl / 10
3 Synthesis of [PNP]NiBr / 14
4 Synthesis of [PNP]NiI / 16
5 Synthesis of [PNP]NiMe / 18
6 Synthesis of [PNP]NiCH2Si(CH3)3 / 19
7 Synthesis of [PNP]NiPh / 20
8 Synthesis of [PNP]NiEt / 21
9 Synthesis of [PNP]NiiBu / 23
10 Synthesis of [PNP]NinBu / 24
11 Synthesis of [PNP]NiOtBu / 25
12 Synthesis of NaOPh / 26
13 Synthesis of [PNP]NiOPh / 27
14 Synthesis of NaSPh / 28
15 Synthesis of [PNP]NiSPh / 28
16 Synthesis of [PNP]NiNHPh / 30
17 Synthesis of [PNP]NiNHtBu / 31
18 Synthesis of [PNP]Ni(O2CPh) / 32
19 Synthesis of [PNP]NiOTf / 33
20 Synthesis of [(PNP)NiPy]OTf / 35
21 Synthesis of PtCl2(SMe2)2 / 36
22 Synthesis of [PNP]PtCl / 37
23 Synthesis of [PNP]PtMe / 38
24 Synthesis of [PNP]PtPh / 40
25 Synthesis of [PNP]PtOTf / 43
26 Synthesis of [(PNP)Pt(NCMe)]OTf / 44
27 Synthesis of [(PNP)PtPy]OTf / 45
28 Synthesis of [(PNP)Pt(dabco)]OTf / 46


III. Results and discussion / 47
i. Synthesis of lithium amide complex / 47
ii. Synthesis of [PNP]NiX complexes / 50
iii. Synthesis of [PNP]NiR complexes / 54
iv. Synthesis of amido, alkoxo, thiolate complexes / 57
v. Reactivity of [PNP]NiMe and [PNP]NiOTf / 59
vi. C-X bond activation / 61
vii. Synthesis of Pt(II) complexes / 65
IV. Conclusions / 69
V. References / 70
VI. Appendix / 74
i. Synthesis of [PNP]NiCCH / 74
ii. Synthesis of [PNP]PtnBU / 75
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