本論文研究HJJ系列材料的光物理特性及其於有機發光二極體的元件應用，此系列材料的合成理念是以兩苯環平行相對的二聚對二甲苯（[2,2]-paracyclophane）分子作為中心，在二聚對二甲苯的兩個苯環分別接上不同的基團作為電子供體與電子受體。
本論文藉由量測並分析各材料的光物理特性，選擇搭配適合的傳輸材料進行螢光及磷光元件的製作，探討材料與元件表現之間的關係。
在螢光元件的應用上，HJJ-2螢光元件在外部量子效率、電流效率與功率效率的表現上分別是1.8%、1.6 cd/A、1.4 lm/W； 以HJJ-5作為主體的螢光元件在外部量子效率、電流效率與功率效率的表現上分別為0.06%、0.1 cd/A、0.09 lm/W；HJJ-6螢光元件在外部量子效率、電流效率與功率效率的表現上分別為0.35%、0.3 cd/A、0.32 lm/W。以HJJ-5作為磷光主體的元件外部量子效率、電流效率與功率效率則為1.6%、4.2 cd/A、3.3 lm/W。

In this thesis, we studied the HJJ series of synthetic materials, and measured the photophysical properties and the applications on organic light-emitting devices. The synthetic concepts of these materials were centered on the paracyclophane molecule which its two benzene rings were parallel, and the two benzene rinds were connected to different groups as Donor and Acceptor..
In this paper, by measuring and analyzing the photophysical properties of each material, we chose the appropriate transporting materials to process fluorescent and phosphorescent devices, and explored the relationship between materials and devices performance.
After optimization, HJJ-2 fluorescence device showed 1.8%, 1.6 cd/A, and 1.4 lm/W in EQE, current efficiency, and power efficiency；fluorescence device which used HJJ-5 as host material showed 0.06%、0.1 cd/A、0.09 lm/W in EQE, current efficiency, and power efficiency；HJJ-6 fluorescence device showed 0.35%、0.3 cd/A、0.32 lm/W in EQE, current efficiency, and power efficiency；phosphorescence device which used HJJ-5 as host material showed 1.6%、4.2 cd/A、3.3 lm/W in EQE, current efficiency, and power efficiency.

中文審定書 i
致謝 ii
摘要 iii
Abstract iv
目錄 v
圖目錄 viii
表目錄 x
第一章 緒論 1
1-1 前言 1
1-2 有機發光二極體（OLED）的發展及文獻回顧 3
1-3 研究動機與目的 5
1-4 各章節提要 5
第二章 基礎理論 6
2-1 影響OLED發光效率的因子 6
2-2有機電激發光元件發光原理及機制 8
2-2-1 電激發光原理 8
2-2-2 螢光與磷光發光原理 9
2-2-3 主客體發光系統 11
2-3 有機發光二極體（OLED）材料的選擇 15
2-3-1 陽極材料 16
2-3-2 電洞注入材料及電洞傳輸材料 16
2-3-3 主客體發光材料 17
2-3-4 電子注入材料與電子傳輸材料 19
2-3-5 陰極材料 19
第三章 元件製程 20
3-1 實驗流程 20
3-1-1 材料純化 21
3-1-2 基板清潔 21
3-1-3 元件蒸鍍 23
3-2 元件特性量測 24
第四章 結果與討論 25
4-1 簡介 25
4-2 材料特性 25
4-2-1 HJJ-1 28
4-2-2 HJJ-2 29
4-2-3 HJJ-3 30
4-2-4 HJJ-5 31
4-2-5 HJJ-6 32
4-3 元件設計 34
4-4 HJJ-2與HJJ-6應用於螢光元件 35
4-5 HJJ-5作為主體應用於磷光及螢光元件 39
第五章 結論 44
參考文獻 45

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