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博碩士論文 etd-0722104-170752 詳細資訊
Title page for etd-0722104-170752
論文名稱
Title
胺基膦化物鋅、鎳、鋁金屬錯合物之合成、結構及反應性之探討
Amido Phosphine Complexes of Zinc, Nickel, and Aluminum: Synthesis, Structure, and Reactivity
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
99
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2004-06-10
繳交日期
Date of Submission
2004-07-22
關鍵字
Keywords
鋁金屬錯合物、鎳、胺基膦化物、鋅
Aluminum, Nickel, Amido Phosphine Complexes, Zinc
統計
Statistics
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中文摘要
我們發展出一個具有剛硬及堅固的苯環骨架的氮基膦化物配位基,我們並利用一個簡單合成策略來得到新的具有立體障礙的新配位基N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide, ([Me-NP]-)、N-(2-diphenylphosphinophenyl)-2,6-diisopropylanilide,([iPr-NP]-)、N-(2-dimethylaminoethyl)-2-diphenylphosphinoanilide, ([PNN]-),合成的方法在於利用簡單的Pd做cross-coupling先合成出配位基的前趨物F化合物,再利用親核基的膦化反應將F取代成PPh2,並利用此配位基與鋅、鎳、鋁等過渡金屬或主族元素形成金屬錯合物,目前已確定多類的金屬錯合物的組成與結構,並針對不同的催化反應測試,以知具有相當的活性。
Abstract
none
目次 Table of Contents
目錄 iii
圖目錄 vii
表目錄 xviii
壹、緒論 1
貳、結果與討論 9
一、配位基的合成 9
二、鋰錯合物的合成 10
1. 合成[NP]Li錯合物 10
2. 合成[PNN]Li錯合物 11
三、鋅金屬錯合物的合成 12
1. 合成[NP]Zn錯合物 12
2. [NP]Zn錯合物的催化反應 17
3. 合成[PNN]Zn錯合物 19
四、鎳金屬錯合物的合成 19
1. 合成[NP]Ni(
參考文獻 References
陸、參考文獻:
1. Levowitz, I. L. in Modern Plastics Encyclopedia ‘99(McGraw-Hill, New York, 1999), vol. 75, PP. B3-B6.
2. Ita, P. World Polyethylene 1138 (Freedonia Group, Cleveland, OH, 1999).
3. Boor, J. Ziegler-Natta Catalysts and Polymerizations (Academic Press, New York, 1979).
4. Fischer, E. O. Angew. Chem. 1952, 22, 620.
5. Wilkinson, G. and Birmingham, I. M. J. Am. Chem. Soc. 1954, 76, 4281.
6. Togni, A. and Halterman, R. L. Metallocenes (Wiley- VCH, Weinheim, Germany, 1998).
7. Kaminsky, W.; Sinn., H.; Vollmer, H. J.; Woldt, R. Angew. Chem. Int. Ed. Engl. 1980, 19, 390.
8. Sinn., H. and Kaminsky W., Adv. Organomet. Chem. 1980, 18, 99.
9. Wild, F. R. W. P.; Zsolnai, L.; Huttner, G.; Brintzinger, H. H. J. Organomet. Chem. 1982, 232, 233.
10. Coates, G. W. and Waymouth, R. M. Science 1995, 267, 217.
11. Kaminsky, W.; Külper, K.; Brintzinger, H. H. Wild F. R. W. P., Angew. Chem. Int. Ed. Engl. 1985, 24, 507.
12. Ewen J. A., J. Am. Chem. Soc. 1984, 106, 6355.
13. Guram, A. S. and Jordan, R. F., in Comprehensive Organometallic Chemistry, M. F. Lappert, Ed. (Pergamon, Oxford, 1996), pp. 589-625.
14. Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem. Int. Ed. Engl. 1999, 38, 428 and references therein.
15. Ittel, S. D.; Johnson, L. K.; Brookhart, M. Chem. Rev. 2000, 100, 1169.
16. Gates, D. P.; Svejda, S. A.; Onate, E.; Killian, C. M.; Johnson, L. K.; White, P. S.; Brookhart, M. Macromolecules 2000, 33, 2320.
17. Leatherman, M. D.; Brookhart, M. Macromolecules 2001, 34, 2748.
18. Mecking, S.; Held, A.; Bauers, F. M. Angew, Chem. Int. Ed. 2002, 41, 545.
19. Bauers, F. M.; Mecking, S. Macromolecules 2001, 34, 1165.
20. Soula, R.; Saillard, B.; Spitz, R.; Claveria, J.; Llaurro, M. F.; Monnet, C. Macromolecules 2002, 35, 1513.
21. Solua, R.; J. P.; Llauro, M. F.; Tomov, A.; Spitz, R.; Claverie, J.; Drujon, X.; Malinge, J.; Saudermont, T. Macromolecules 2001, 34, 2438.
22. Johnson, L. K.; Mecking, S.; Brookhart, M. J. Am. Chem. Soc. 1996, 118, 267.
23. Mecking, S.; Johnson, L. K.; Wang, L.; Brookhart, M. J. Am. Chem. Soc. 1996, 118, 267.
24. Ostoya Starzewski, K. A.; Witte, J. Angew. Chem. Int. Ed. Engl. 1985, 24, 599.
25. Johnson, L.; Bennett, A.; Dobbs, K.; Hauptman, E.; Ionkin, A.; Ittel, S.; McCord, E.; McLain, S.; Radzewich, C.; Yin, Z.; Wang, L.; Wang, Y.; Brookhart, M. Polym. Mater. Sci. Eng. 2002, 86, 319.
26. Keim, W.; Kowalt, F. H.; Goddard, R. Krüger, C. Angew. Chem. Int. Ed. Engl. 1978, 17, 466.
27. Wang, C. et al. Organometallics 1998, 17, 3149.
28. Neutral complexes with salicylaldimine ligands have been reportes as catalysts for polymerization, These systems require cocatalyst activation, and only demonstrate moderate activity [L. K. Johnson et al., Chem. Abstr. 1998, 129, 149362j.
29. Klabunde, U. and lttel, S. D. J. Mol. Catal. 1987, 41, 123.
30. Klabunde, U. et al. J. Polym. Sci. Part A : Polym. Chem. 1987, 25, 1989.
31. Klabunde, U.; Tulip, T. H.; Roe, D. C.; Ittel, S. D. J. Organomet. Chem. 1987, 334, 141.
32. In the presence of alkylating agnets such as MAO, this complexe producted trace amounts of PE.
33. Komon, Z. J. A.; Bu, X.; Bazan, G. C. J. Am. Chem. Soc. 2000, 122, 1830-1831.
34. Komon, Z. J. A.; Bu, X.; Bazan, G. C.; Fang, C. Inorg. Chim. Acta 2003, 345, 95-102.
35. Kalamarides, H. A.; iyer, S. ; Lipian, J. ; Rhodes, L. F. Organometallics 2000, 19, 3983-3990.
36. Younkin, T. R.; Conner, E. F.; Henderson, J. I.; Friedrich, S. K.; Brubbs, R. H.; Bansleben, D. A.; Science 2000, 287, 460-462.
37. Wang, C.; Friedrich, S.; Younkin, T. R.; Li, R. T.; Grubbs, R. H.; Bansleben, D. A.; Day, M. W. Organometallics 1998, 17, 3149-3151.
38. Domhover, B.; Klaui, W.; Kermer-Aach, A.; Bell, R.; Mootz, D. Angew, Chem. Int. Ed. 1998, 37, 3050-3052.
39. Wiencko, H. L.; Kogut, E.; Warren, T. H. Inorg. Chim. Acta 2003, 345, 199-208.
40. Liang, L.-C.; Lee, W.-Y.; Hung, C.-H. Inorg. Chem. 2003, 42, 5471-5473.
41. Liang, L.-C.; Lee, W.-Y.; Yin, C.-C. Organometallics 2004, 23, accepted.
42. Tamao K., Kiso Y., Sumitani K., Kumada M., J. Am. Chem. Soc. 1972, 94, 9268.
43. Kiso Y., Tamao K., Kumada M., J. Organomet. Chem. 1973, 50, C12.
44. Liang, L.-C.; Huang, M.-H. ; Hung, C.- H. Inorg. Chem. 2004, 43, 2166-2174.
45. Hitchcock, P. B.; Lappert, M. F.; Leung, W.-P.; Yin, P. J. Chem. Soc. Dalton Trans. 1995, 3925-3932.
46. Prust, J.; Stasch, A.; Zheng, W.; Roesky, H. W.; Alexopoulos, E.; Usón, I.; Böhler, D.; Schuchardt, T. Organometallics 2001, 20, 3825-3828.
47. Darensbourg, D. J.; Zimmer, M. S.; Rainey, P.; Larkins, D. L.; Inorg. Chem. 1998, 37, 2852-2853.
48. Ellis, D.; Farrugia, L. J.; Hickman, D. T.; Lovatt, P. A.; Peacock, R. D. Chem. Commun. 1996, 1817-1818.
49. Klein, H.-F.; Beck, R.; Hetche, O. Eur. J. Inorg. Chem. 2003, 232-239.
50. Anderson, T. J.; Vicic, D. A. Organometallics 2004, 23, 623-625.
51. Carmona, E.; Paneque, M.; Poveda, M. Polyhedron 1989, 8 ,285-291.
52. Burch, R. R.; Nuetterties, E. L.; Day, V. W. Organometallics 1982, 1, 188- 197.
53. Komon, Z. J. A.; Bu, X.; Bazan, G. C. J. Am. Chem. Soc. 2000, 122, 12379-12380.
54. Lee, B. Y.; Bazan, G. C.; Vela, J.; Komon, Z. J. A.; Bu, X. J. Am. Chem. Soc. 2001, 123, 5342-5353.
55. Liang, L.-C.; Lin, J.-M. ; Hung, C.-H. Organometallics 2003, 22, 3007-3009.
56. 之所以沒有苯環上的訊號,乃由於次要產物本身的比例就低,所以訊號較弱,故無法辨別。
57. Masotti, H.; Wallet, J. C.; Peiffer, G. J. Organometal Chem. 1986, 308, 241-252.
58. Tenorio, M. J.; Puerta, M. C.; I. S. And P. V.; J. Chem. Daltion Trans. 2001, 653-657.
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