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論文名稱 Title |
胺基膦化物鋅、鎳、鋁金屬錯合物之合成、結構及反應性之探討 Amido Phosphine Complexes of Zinc, Nickel, and Aluminum: Synthesis, Structure, and Reactivity |
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系所名稱 Department |
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畢業學年期 Year, semester |
語文別 Language |
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學位類別 Degree |
頁數 Number of pages |
99 |
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研究生 Author |
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指導教授 Advisor |
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召集委員 Convenor |
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口試委員 Advisory Committee |
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口試日期 Date of Exam |
2004-06-10 |
繳交日期 Date of Submission |
2004-07-22 |
關鍵字 Keywords |
鋁金屬錯合物、鎳、胺基膦化物、鋅 Aluminum, Nickel, Amido Phosphine Complexes, Zinc |
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統計 Statistics |
本論文已被瀏覽 5650 次,被下載 0 次 The thesis/dissertation has been browsed 5650 times, has been downloaded 0 times. |
中文摘要 |
我們發展出一個具有剛硬及堅固的苯環骨架的氮基膦化物配位基,我們並利用一個簡單合成策略來得到新的具有立體障礙的新配位基N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide, ([Me-NP]-)、N-(2-diphenylphosphinophenyl)-2,6-diisopropylanilide,([iPr-NP]-)、N-(2-dimethylaminoethyl)-2-diphenylphosphinoanilide, ([PNN]-),合成的方法在於利用簡單的Pd做cross-coupling先合成出配位基的前趨物F化合物,再利用親核基的膦化反應將F取代成PPh2,並利用此配位基與鋅、鎳、鋁等過渡金屬或主族元素形成金屬錯合物,目前已確定多類的金屬錯合物的組成與結構,並針對不同的催化反應測試,以知具有相當的活性。 |
Abstract |
none |
目次 Table of Contents |
目錄 iii 圖目錄 vii 表目錄 xviii 壹、緒論 1 貳、結果與討論 9 一、配位基的合成 9 二、鋰錯合物的合成 10 1. 合成[NP]Li錯合物 10 2. 合成[PNN]Li錯合物 11 三、鋅金屬錯合物的合成 12 1. 合成[NP]Zn錯合物 12 2. [NP]Zn錯合物的催化反應 17 3. 合成[PNN]Zn錯合物 19 四、鎳金屬錯合物的合成 19 1. 合成[NP]Ni( |
參考文獻 References |
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