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博碩士論文 etd-0723112-155659 詳細資訊
Title page for etd-0723112-155659
論文名稱
Title
鎳與錫界面反應之研究
A Study of the Interfacial reaction between Ni and Sn
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
79
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2012-06-27
繳交日期
Date of Submission
2012-07-23
關鍵字
Keywords
Ni3Sn4、Ni3Sn2、晶向關係、介金屬化合物、熱蒸鍍
Ni3Sn4, Ni3Sn2, orientation relationship, epitaxial
統計
Statistics
本論文已被瀏覽 5697 次,被下載 671
The thesis/dissertation has been browsed 5697 times, has been downloaded 671 times.
中文摘要
本研究以熱蒸鍍技術在NaCl(001)、(111)平面上製備出Ni/Sn雙層薄膜,經熱處理後觀察到介金屬化合物Ni3Sn4的生成。並藉穿透式電子顯微鏡(TEM)分析觀察所生成之介金屬化合物,配合X光繞射儀驗證,探討其與Ni的晶向關係。
由實驗結果可得Ni3Sn2高溫η相與Ni存在兩種晶向關係,第一組是界面為(2 0) η-Ni3Sn2/(001)Ni,(0002) η-Ni3Sn2//(220)Ni與(01 0) η-Ni3Sn2//(2 0)Ni,第二是界面為(2 0) η-Ni3Sn2 /(111)Ni,(0002) η-Ni3Sn2 //(2 0)Ni與(01 0) η-Ni3Sn2//(22 )Ni。而在本實驗中並未得到Ni3Sn4與Ni之晶向關係。
Abstract
The orientation relationship and interfaces of Ni3Sn4 and Ni3Sn2 with the Ni (001) and (111) surfaces have been studied with transmission electron microscopy. Ni was evaporated onto the NaCl (001) and (111) surfaces to form epitaxial Ni thin films and Sn was evaporated onto the Ni film and heat treated to form Ni3Sn4 and Ni3Sn2.
No orientation relationship between Ni3Sn4 and Ni was found. Two types of orientation relationships between η-Ni3Sn2 and Ni were found: (1) (0002) η-Ni3Sn2//(220)Ni and (01 0) η-Ni3Sn2//(2 0)Ni on the (2 0) η-Ni3Sn2/(001)Ni interface;and (2) (0002) η-Ni3Sn2 //(2 0)Ni and (01 0) η-Ni3Sn2//(22 )Ni on the (2 0) η-Ni3Sn2/(001)Ni interface.
目次 Table of Contents
論文審定書....................................................................................i
中文摘要........................................................................................ii
英文摘要.......................................................................................iii
目錄...............................................................................................iv
第一章、簡介 ............................................................................. 1
1.1前言 ........................................................................................ 1
1.2文獻回顧 ................................................................................ 3
1.2.1 Ni/Sn之界面反應 ............................................................. 3
1.2.2 Ni3Sn4/ Ni3Sn2之生成焓 .............................................. 8
第二章、實驗方法 ..................................................................... 9
2.1 熱蒸鍍簡介 ........................................................................... 9
2.2 蒸鍍系統 ............................................................................ 10
2.3 分析儀器 ............................................................................ 13
2.4 實驗目的 ............................................................................ 14
2.5 實驗步驟 ............................................................................ 15
第三章、實驗結果 ................................................................... 16
3.1 各介金屬之ring繞射圖 ..................................................... 16
3.2 在NaCl(001)面上之界面 ................................................. 17
3.3 在NaCl(111)面上之界面 .................................................. 18
3.4 XRD鑑定 ............................................................................ 18
第四章、實驗結果討論 ........................................................... 19
4.1 IMC的生成 ......................................................................... 19
4.2 晶向關係與界面 ................................................................ 19
4.3 Ni3Sn4與Ni3Sn2之析出順序 ......................................... 21
第五章、結論 ........................................................................... 22
參考文獻 ................................................................................... 23
參考文獻 References
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