本研究主要研究以中研院化學所林建村老師實驗室所開發之CC-MP系列開發螢磷混合白色有機發光二極體，首先根據材料的光物理特性，選出光激發光量子效率較高的三者CC-MP2 (PLQY=0.60)、CC-MP4 (PLQY=0.64)、CC-MP5 (PLQY=0.66)製作成單色光元件，探討其元件光色是否可以與紅色磷光客體材料混合成白光，進而確認使用CC-MP2作為藍色螢光發光層及紅色磷光發光層之主體材料開發白光元件。
CC-MP2經元件優化後，成功製得暖白光(warm-white) 及冷白光(cool-white)元件，其元件特性如下述：暖白光元件之最大外部量子效率可達9.89%，最大功率效率為13.7 lm/W，最大電流效率為14.8 cd/A，CRI值為71，色溫為2269K；冷白光元件之最大外部量子效率5.8%，最大功率效率為8.5 lm/W，最大電流效率為8.59 cd/A，CRI值為69，色溫為3686K。

In this thesis, CC-MP series compounds were utilized to develop fluorescent-phosphorescent hybrid white-emissive organic light-emitting diodes. According to the photophysical properties of the materials, CC-MP2 (PLQY=0.60)、CC-MP4 (PLQY=0.64)、CC-MP5 (PLQY=0.66), the materials with higher photoluminescence quantum yield, were selected to fabricate fluorescent OLEDs. Due to the emissive color was complementary to red phosphor, CC-MP2 was chosen as the blue fluorescent emissive layer in the hybrid devices.
Two hybrid devices with warm-white and cool-white emissive color were realized with CC-MP2 and Ir(pq)2(acac). The warm-white OLEDs exhibits maximum external quantum efficiency of 9.89%, maximum power efficiency of 13.7 lm/W, maximum current efficiency of 14.8 cd/A, color rendering index of 71, and correlated color temperature of 2269K. The cool-white OLEDs exhibits maximum external quantum efficiency of 5.8 %, maximum power efficiency of 8.5 lm/W, maximum current efficiency of 8.59 cd/A, color rendering index of 69, and correlated color temperature of 3686 K.

目錄
中文論文審定書 i
英文論文審定書 ii
摘要……….. iii
Abstract iv
目錄…. v
圖目錄 viii
表目錄 xii
第一章 緒論 1
1-1前言 1
1-2有機發光二極體(OLED)的發展及文獻回顧 2
1-3白色有機發光二極體(WOLED)的發展及文獻回顧 4
1-4研究動機與目的 5
1-5各章節提要 6
第二章 基礎理論 7
2-1 影響OLED發光效率的因子 7
2-2 有機電激發光(Organic Electroluminescence，OEL) 8
2-2-1有機電激發光原理 8
2-2-2 螢光和磷光的發光原理 10
2-2-3 主客體發光系統 13
2-3 有機發光二極體(OLED)材料的選擇 16
2-3-1陰極 16
2-3-2陽極 16
2-3-3電子注入(EIL)/傳輸(ETL)材料 17
2-3-4電洞注入(HIL)/傳輸(HTL)材料 18
2-3-5主客體發光材料 19
2-4白色有機發光二極體不同元件設計 21
2-5 CIE標準色彩空間 23
第三章 實驗設備與元件製程 26
3-1 實驗流程 26
3-2實驗設備介紹 27
3-2-1純化系統-管式高溫爐(Tube Furnace) 27
3-2-2超音波震盪機(Ultrasonic Cleaner) 28
3-2-3橢圓偏光儀(Ellipsometer) 28
3-2-4紫外光/可見光光譜(UV/Vis Spectrophotometer) 28
3-2-5螢光光譜儀(Fluorimeter)與光激發量子效率量測系統(Photoluminescence Quantum Yield measurement system) 29
3-2-6紫外光臭氧清洗機(UV-Ozone) 29
3-2-7真空熱蒸鍍系統(Vacuum Evaporation Deposition System) 30
3-2-8低水氧手套箱(Glove box) 31
3-2-9 OLED光電特性量測系統 31
3-3元件製程與量測 32
3-3-1基板清潔 32
3-3-2基板表面處理 33
3-3-3元件蒸鍍 33
3-3-4元件量測 34
第四章 結果與討論 34
4-1簡介 34
4-2吩噻嗪衍生物材料的光物理特性 34
4-3單色元件的特性分析 39
4-3-1 CC-MP2單色元件 40
4-3-2 CC-MP4單色元件 43
4-3-3 CC-MP5單色元件 45
4-3-4 CC-MP2、CC-MP4、CC-MP5元件特性比較 46
4-4 螢磷混合白光元件的特性分析 48
4-4-1暖白色光元件優化及特性探討 49
4-4-2冷白色光元件優化及特性探討 58
4-5暖白光及冷白光最佳化元件之比較 71
第五章 結論 73
參考文獻 74

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