本論文主要研究高分子磷光發光二極體（Polymer Phosphorescent light-emitting diodes, PPLEDs）之能量轉移現象。研究主要分為三部分：新型主體高分子摻雜磷光材料之元件、主體高分子PVK 摻雜磷光材料元件，以及新型磷光高分子發光元件。
首先我們研究新型主體高分子BP105（Polyfluorene-based material）摻雜磷光染料Ir(ppy)3 之能量轉移現象。接著使用PVK 做為主體高分子材料，摻雜磷光染料Ir(ppy)3、FIrpic，觀察其是否能有效改善能量轉移效率。最後研究新型主體高分子與磷光材料分別採用混和（Blend）與化學鍵結（Bonding）方式製作之元件，並針對元件效率與能量轉移效率作比較。
另外本論文藉由添加glycerol提升導電高分子PEDOT：PSS導電度，並將其應用在螢光高分子super yellow 元件中，針對其元件效率與製程變化作比較。實驗結果發現：使用改質過後PEDOT：PSS所製作之PLED元件，電流密度與發光效率皆大幅改善。

In this research, we studied the phenomenon of energy transfer of polymer phosphorescent light-emitting diodes, PPLEDs. This thesis was divided into three parts: devices constructed by new-type host polymer blended with phosphorescent material, devices constructed by host polymer PVK blended with phosphorescent materials, and devices constructed by new-type phosphorescent polymer materials.
The phenomenon of energy transfer between host polymer BP105 and phosphorescent dye Ir(ppy)3 was studied. Second, we chose PVK as a host polymer material, and Ir(ppy)3 as a phosphorescent guest material, to observe whether it can improve efficiency of devices by using energy transfer process. At last we manufactured devices constructed by new-type host polymer blended or bonded with new-type phosphorescent materials, and compared their emitting and energy transfer efficiency.
A glycerol-modified PEDOT:PSS layer that used as an anode buffer layer in PLED using super yellow as the emitter was also been studied. It was found the glycerol-modified device showed a larger current density and improved luminescent efficiency then that of the unmodified device.

誌謝 I
中文摘要 III
Abstract IV
目錄 V
圖目錄 VII
表目錄 XI
第一章 導論 1
1-1 有機光發二極體（OLED）簡介與原理 1
1-2 高分子發光二極體（PLED）簡介 4
1-3 有機發光二極體元件特性與原理 8
第二章 實驗原理 18
2-1 磷光發光元件基本原理 18
2-2 新型金屬錯合物磷光高分子 25
2-3 實驗動機 29
第三章 實驗製程步驟與分析儀器 31
3-1 實驗架構 31
3-2 實驗的流程 41
3-3 儀器介紹 48
第四章 結果討論與分析 55
4-1 材料性質分析 55
4-2 元件性質分析 65
第五章 總結 97
參考文獻 98

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