使用不同方式沈積鈦薄膜在ITO玻璃基板上，並使用陽極氧化法，在固定電解液濃度，改變氧化時間、外加偏壓的條件下，製作二氧化鈦薄膜，我們可以製作出孔洞尺寸最小為18nm，厚度為4500

We use different methods to deposit Ti thin film on the ITO glass substrate. Under the circumstances of using fixed concentration of electrolyte, changing anodic time, and applying voltage, we are able to use anodic method to make ordered nano TiO2 thin film,of which the smallest pore size is 18nm and the thickness is 4500

目錄
誌謝 I
中文摘要 II
Abstract III
目錄 V
圖目錄 VIII
表目錄 XII
第一章 序論 1
1-1 前言 1
1-2 太陽能電池 3
1-2-1 太陽能電池簡介 3
1-2-2 太陽能電池種類 4
1-2-3 太陽能電池的效率 5
1-2-4 太陽能電池的研發現況 6
1-3 陽極處理簡介 9
1-4 研究動機與目的 10
第二章 文獻回顧與基礎理論 12
2-1 二氧化鈦 12
2-1-1 二氧化鈦介紹 12
2-1-2 二氧化鈦薄膜的光學特性及特徵 14
2-1-3 多孔性奈米二氧化鈦薄膜介紹 16
2-2 染料敏化太陽能電池 17
2-2-1染料敏化太陽能電池發展史 17
2-2-2 染料敏化太陽能電池原理 19
2-3太陽能電池的主要輸出參數 22
第三章 實驗方法 24
3-1 藥品器材 24
3-2實驗設備 25
3-3 儀器原理與應用 26
3-3-1 製程儀器 26
3-4 實驗流程圖 36
3-4-1 光電極製作流程 36
3-4-2 染料敏化太陽電池製作流程圖 37
3-4-3 材料特性分析流程圖 38
3-5 實驗方法 39
3-5-1 鈦薄膜的製作 39
3-5-2 規則多孔性二氧化鈦薄膜製作 42
3-5-3 二氧化鈦薄膜電極的特性量測 44
3-5-4 白金對極的制作 45
3-5-5 染料敏化太陽能電池元件製作 46
第四章 結果與討論 51
4-1 鈦薄膜的特性分析 51
4-2 陽極氧化電流對時間的曲線分析 54
4-3 二氧化鈦薄膜特性分析 56
4-3-1 二氧化鈦薄膜SEM分析 57
4-3-2 二氧化鈦薄膜XRD分析 65
4-3-3 二氧化鈦薄膜Raman分析 68
4-3-4 二氧化鈦薄膜UV-Vis分析 70
4-4 染料敏化太陽能電池電壓-電流的輸出特性分析 73
4-4-1 經由TiCl4之影響 73
4-4-2 應用不同種二氧化鈦薄膜電極及其不同種對極所製作染料敏化太陽能電池輸出特性分析 75
第五章 總結 84
參考文獻 87

[1]工研院能資所 2002年資料
[2]M. Grätzel, “Photoelectrochemical cells” Nature 2001(414) 338-344
[3] M. Grätzel, “Powering the planet” Nature 2000(403) 363
[4]H. W. Vogel, “Uber die lightempfindlichkeit der Bromsilbers for die
sogenannten chemisch unwirksamen Farben,” Chemische Berichte,
vol. 6, p. 1302, 1873.
[5] B. O’Regan, M. Gratzel, “A low, high-efficiency solar cell based on
dye-sensiized colloidal TiO2 films.” Nature, Vol. 353, Oct 24 1991.
[6] B. O’Regan, M. Grätzel, “A low-cost, high-efficiency solar cell based
on dye-sensitized colloidal TiO2 films” Nature 1991(353) 737-740
[7]H.Yamashita, H.Nishiguchi, N.Kamada, M.Anpo, Research on
Chemical Intermediates, vol.20 (8) 815-823(1994)
[8]M.R. Hoffmann, S. T. Martin, W. Choi, D.W. Bahnemann, Chem Rev.
Vol.95 69-96 (1995)
[9]W.Choi, A. Termin, Hoffmann, Journal of Physical Chemistry vol.
98,13669-13679(1994)
[10]G.Zhao, H.Kozuka, H.Lin, T.Yoko, Thin Solid Films Vol.339123-128(1999)
[11]R.Asahi, T.Morikawa, T.Ohwaki, K.Aoki, Y.Taga, Science, Vol.293
269-271(2001)
[12]H.Yanashita, Y.Fuji, Y.Ichihshi, S.G.Zhang, K.Ikeue, D.R.Park,
K.Kayano, T.Tatsumi, M.Anpo, Catalysis Today Vol.45
221-227(1998)
[13] Masuda H, Yamada H, Satoh M, Asoh H, Nakao M and
Tamamura T 1997 Appl. Phys. Lett. 71 2770
[14] Shingubara S 2003 J. Nanopart. Res. 5 17
[15] Asoh H, Nishio K, Nakao M, Yokoo A, Tamamura T and
Masuda H 2001 J. Vac. Sci. Technol. B 19 569
[16] Masuda H, Ohya M, Nishio K, Asoh H, Nakao M,
Nohtomi M, Yokoo A and Tamamura T 2000 Japan. J.
Appl. Phys. 39 L1039
[17] Jessensky O, M¨uller F and G¨osele U 1998 Appl. Phys. Lett.
72 1173
[18] Asoh H, Nishio K, Nakao M, Tamamura T and
Masuda H 2001 J. Electrochem. Soc. 148 B152
[19] Masuda H, Hasegawa F and Ono S 1997 J. Electrochem. Soc144 L127
[20] Rehn L E, Kestel B J, Baldo P M, Hiller J,
McCormick A W and Birtcher R C 2003 Nucl. Instrum.
Methods Phys. Res. B 206 490
[21] Li J, Papadopoulos C and Xu J M 1999 Appl. Phys. Lett.
75 367
[22] Ji C X and Searson P C 2002 Appl. Phys. Lett. 81 4437
[23] Crouse D, Lo Y H, Miller E and Crouse M 2000 Appl. Phys.
Lett. 76 49
[24] Tian M L, Xu S Y, Wang J G, Kumar N, Wertz E, Li Q,
Campbell P M, Chan H W and Mallouk T E 2005 Nano
Lett. 5 697
[25] Shingubara S, Okino O, Murakami Y, Sakaue H and
Takahagi T 2001 J. Vac. Sci. Technol. B 19 1901
[26] Chu S Z, Wada K, Inoue S and Todoroki S 2002 J.
Electrochem. Soc. 149 B321
[27] Rabin O, Herz P R, Lin Y M, Akinwande A I, Cronin S B and
DresselhausM S 2003 Adv. Funct. Mater. 13 631
[28] Shiraki H, Kimura Y, Ishii H, Ono S, Itaya K and
Niwano M 2004 Appl. Surf. Sci. 237 369
[29] Lei Y, Zhang L D and Meng G W 2001 Appl. Phys. Lett.
78 1125
[30] Liu S M, Gan L M, Liu L H, Zhang W D and Zeng H C 2002
Chem. Mater. 14 1391
[31] Hoyer P 1996 Langmuir 12 1411
[32] Imai H, Takei Y, Shimizu K, MatsudaM and
Hirashima H 1999 J. Mater. Chem. 9 2971
[33] Yuan Z Y and Su B L 2004 Colloids Surf. A 241 173
[34] Lee S, Jeon C and Park Y 2004 Chem. Mater. 16 4292
[35] Yang B, Uchida M, Kim H M, Zhang X D and Kokubo T 2004
Biomaterials 25 1003
[36] Hoyer P 1996 Langmuir 12 1411
[37] Imai H, Takei Y, Shimizu K, MatsudaM and
Hirashima H 1999 J. Mater. Chem. 9 2971
[38] Hoyer P 1996 Adv. Mater. 8 857
[39] Miao Z, Xu D S, Ouyang J H, Guo G L, Zhao X S and
Tang Y Q 2002 Nano Lett. 2 717
[40] Gong D W, Grimes C A, Varghese O K, Hu W C, Singh R S,
Chen Z and Dickey E C 2001 J. Mater. Res. 16 3331
[41] Mor G K, Varghese O K, Paulose M, Mukherjee N and
Grimes C A 2003 J. Mater. Res. 18 2588
[42] Zhao J L, Wang X H, Chen R Z and Li L T 2005 Solid State
Commun. 134 705
[43] Beranek R, Hildebrand H and Schmuki P 2003 Electrochem.
Solid State 6 B12
[44] Macak J M, Sirotna K and Schmuki P 2005 Electrochim. Acta
50 3679
[45] Zwilling V, Darque-Ceretti E, Boutry-Forveille A, David D,
Perrin M Y and AucouturierM 1999 Surf. Interface Anal.
27 629
[46] Zwilling V, AucouturierM and Darque-Ceretti E 1999
Electrochim. Acta. 45 921
[47] Tsuchiya H, Macak J M, Taveira L, Balaur E, Ghicov A,
Sirotna K and Schmuki P 2005 Electrochem. Commun.
7 576
[48]萬海保,曹立新,王麗穎,曾廣賦,席時權, “染料敏化的TiO2納米晶多
孔膜的性質及其光電轉換” 化學通報 1999(6)
[49] A. Hagfeldt, M. Grätzel, “Light-Induced Redox Reactions in
Nanocrystalline Systems” Chem. Rev. 1995(95) 49-68
[50] M. Grätzel, “Mesoporous oxide junctions and nanostructured solar
cells” Current Opinion in Colloid & Interface Science 1999(4) 314-321
[51] K. Kalyanasundaram and M. Grätzel, “Applications of
functionalized transition metal complexes in photonic and optoelectronic
devices” Coord. Chem. Rev. 1998(77) 347-414
[52] A. Fujishima et al., “Slow interfacial charge recombination in
solid-state dye-sensitized solar cell using Al2O3-coated nanoporous TiO2
films” Sol. Energy Mater. Sol. Cells 2004(81) 197-203
[53] Cahen et al., “Nature of Photovoltaic Action in Dye-Sensitized Solar
Cells” J. Phys. Chem. B 2000(104) 2053-2059
[54]Xiaofeng Yu , Yongxiang Li et al. Nannotechnology 17 (2006)
808-814
［55］N.-G. Park﹔G. Schlichtho1rl﹔J. van de Lagemaat﹔H. M.
Cheong﹔A. Mascarenhas and A. J. Frank﹐J. Phys. Chem. B
1999﹐103﹐3308.
［56］B. D. Yao﹔Y. F. Chan﹔X. Y. Zhang﹔W. F. Zhang﹔Z. Y.
Yang, and N. Wang﹐Appl. Phys. Lett. 1998﹐82﹐281.
［57］L. Kavan﹔M. Kalba﹔M. Zukalova﹔I. Exnar﹔V. Lorenzen﹔
R. Nesper and M. Gratzel﹐Chem.Mater. 2004﹐16﹐477.
［58］D. Bersani﹔P. P. Lottic and Xing-Zhao Ding﹐Appl. Phys.
Lett.1998﹐72﹐1.
［59］N. G. Park﹔G. Schlichthorl﹔J. van de Lagemaat﹔H. M.
Cheong﹔A. Mascarenhas﹔A. J. Frank﹐J. Phys. Chem. B 1999﹐
103﹐3308–3314.