(一)本部份以反式 (trans) 的鄰-甲氧基二苯乙烯及其衍生物47a-f進行熱解及光解研究，發現熱解部份除了得到預期產物2-芳香基苯駢[b]呋喃的產物52a,c-f之外，尚得到其異構物53a,c-d。其中化合物47b的熱解，由於呋喃環 (furan) 高溫下開環重排會形成主產物萘 (63) 的架構；另一部份光解結果發現，得到的產物均符合預期的結果。(二)本部份以N-(N-甲基-3-吲哚基)甲基苯甲醯胺 (45) 為起始物，在 瞬間真空熱解的反應條件下進行裂解反應，得到擴環產物3-甲基喹啉 (38)、4-甲基喹啉 (39) 和二次裂解的產物喹啉 (36)。
(二)本部份以N-(N-甲基-3-吲哚基)甲基苯甲醯胺 (45) 為起始物，在 瞬間真空熱解的反應條件下進行裂解反應，得到擴環產物3-甲基喹啉 (38)、4-甲基喹啉 (39) 和二次裂解的產物喹啉 (36)。

1.trans o-methoxystilbene and its derivatives 47a-f had been studied by means of pyrolysis and photolysis. Under pyrolytic conditions, compounds 47a-f gave not only the expected products 52a,c-f, but also their corresponding isomers 53a,c-f . Furthermore, compound 47b gave naphthalene (63) as the major product by opening the furan ring at higher temperature. Under photolytic conditions, compounds 47a-f gave the expected photocyclic products 2a-f and 109a-f.2.Pyrolytic chemistry of N-(N-Methyl-3-indolyl)methyl benzamide (45) hes been studied. Pyrolysis of 45 gave 3-methyl quinoline (38), 4-methyl quinoline (39) and secondary pyrolysis product quinoline (36).
2.Pyrolytic chemistry of N-(N-Methyl-3-indolyl)methyl benzamide (45) hes been studied. Pyrolysis of 45 gave 3-methyl quinoline (38), 4-methyl quinoline (39) and secondary pyrolysis product quinoline (36).

第一章 鄰位-甲氧基二苯乙烯及其衍生物之熱解與光解研究
壹、緒論 1
貳、結果與討論 23
參、結論 62
肆、實驗部份 64
伍、參考文獻 111

第二章 N-(N-甲基-3-吲哚基)甲基苯甲醯胺之熱解研究
壹、緒論 117
貳、結果與討論 130
參、結論 136
肆、實驗部份 138
伍、參考文獻 146

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