本研究採用黃光微影SU-8製程及濕蝕刻技術，製作多洞型紅銅雙極板(孔徑為750 μm、厚度為50 μm)；而產氫部分，以重量百分比方式調配不同的低濃度(1-10 wt. %)之氫氧化鈉溶液(NaOH solution)與鋁箔紙(Al paper)作為化學產氫。此外，改變雙極板之開孔率來改善燃料電池功率密度，並將針對量測燃料電池系統之性能探討，實驗結果以VI曲線與PI曲線表示。實驗結果可得，藉由化學產氫反應所伴隨自發性加熱、加濕過程、氫氣內部循環及累積壓力機制，將可增強整體燃料電池系統之效能。最後燃料電池系統結合直流升壓轉換器，將燃料電池之輸出電壓升壓至4.99 V作為手機蓄電池充電使用。

In the study, micro-PEM fuel cells are designed and fabricated in-house through a deep UV lithography SU-8 process and a wet etching technique for perforated holes plates (diameter is 750 μm) of 50 μm thickness of pure copper. Measurements of cell performance are performed using the low percentage of the weight concentration (1-10 wt. %) of NaOH solution, Al paper as the source material for hydrogen production, and different open ratios of the perforated plates to determine which best improves cell power density. Experimental results are presented in the form of polarization VI and PI curves under the above operating conditions. The experimental results show cell performance is enhanced by the self-heating, humidifying of hydrogen production, hydrogen internal circulation and accumulated pressure. Finally, the micro-PEM fuel cell system with DC/DC boost converter can generate 4.99 V for use in cellular phone accumulators charging.

目 錄 i
表 目 錄 iii
圖 目 錄 iv
符號說明 viii
中文摘要 x
英文摘要 xi
第一章 序論 1
1-1 前言 1
1-2 燃料電池發展之歷史與簡介 3
1-3 文獻回顧 5
1-4 研究目的 16
第二章 微型質子交換膜燃料電池元件設計與製作 20
2-1 質子交換膜燃料電池組成元件 20
2-2 燃料電池組設計要點 25
2-3 產氫結合微型質子交換膜燃料電池系統設計製作 27
第三章 實驗相關設備與元件材料 43
3-1 實驗設備 43
3-2 實驗元件材料 48
第四章 燃料電池之性能 54
4-1 前言 54
4-2 電極熱力學 54
4-3 極化現象 60
第五章 誤差分析 63
第六章 實驗結果與討論 67
6-1 氫氧化鈉濃度對於化學當量及總產氫量之影響 69
6-2 氫氧化鈉濃度對化學產氫溫度之影響 78
6-3 定孔徑下改變開孔率(開孔數)對燃料電池之性能影響 80
6-4 陰極多洞型35％對於陽極單一開孔25-55％之影響 82
6-5 陽極多洞型35％對於陰極單一開孔25-55％之影響 83
6-6 固定微型燃料電池之電流密度下，升壓轉換器效能影響 85
第七章 結論與未來展望 107
7-1 結論 107
7-2 建議 109
參考文獻 111
附錄 A 120

參考文獻
1. R. Jiang and D. Chu, "Stack Design and Performance of Polymer Electrolyte Membrane Fuel Cell," Journal of Power Sources, Vol.93, 2001, pp.25-31.
2. S. Slade, S. A. Campbell, T. R. Ralph, and F. C. Walsh, "Ionic Conductivity of an Extruded Nafion 117 EW Series of Membranes," Journal of The Electrochemical Society, Vol.149, 2002, pp.1556-1564.
3. H. Chang, J. R. Kim, J. H. Cho, H. K. Kim, and K. H. Choi, "Materials and Process for Small Fuel Cells," Solid State Ionics, Vol.148, 2002, pp.601-606.
4. D. Natarajan, and T. V. Nguyen, "Three-Dimensional Effects of Liquid Water Flooding in the Cathode of a PEM Fuel Cell," Journal of Power Sources, Vol.115, 2003, pp.66-80.
5. G. Bender, M. S. Wilson, and T. A. Zawodzinski, "Further Refinements in the Segmented Cell Approach to Diagnosing Performance in Polymer Electrolyte Fuel Cell," Journal of Power Sources, Vol.123, 2003, pp.163-171.
6. M. Ciureanu, S. D. Mikhailenko, and S. Kaliaguine, "PEM Fuel Cells as Membrane Reactors: Kinetic Analysis by Impedance Spectroscopy," Catalysis Today, Vol.82, 2003, pp.195-206.
7. R. O. Hayre, D. Braithwaite, W. Hermann, S. J. Lee, T. Fabian, S. W. Cha, Y. Saito, and F. B. Prinz, "Development of Portable Fuel Cell Arrays with Print-circuit Technology," Journal of Power Sources, Vol.124, 2003, pp.459-472.
8. S. S. Hsieh, J. K. Kuo, C. F. Hwang, and H. H. Tsai, "A Novel Design and Microfabrication for a Micro PEMFC," Microsystem Technologies, Vol.10, 2004, pp.121-126.
9. Y. Yamazaki, "Application of MEMS Technology to Micro Fuel Cells," Electrochimica Acta, Vol.50, 2004, pp.663-666.
10. B. H. Liu, Z. P. Li, K. Arai, and S. Suda, "Performance Improvement of a Micro Borohydride Fuel Cell Operating at Ambient Conditions," Electrochimica Acta, Vol.50, 2005, pp.3719-3725.
11. D. Gruber, N. Ponath, and J. Muller, "Microfabricated Polymer Electrolyte Membrane Fuel Cells with Low Catalyst Loadings," Electrochimica Acta, Vol.51, 2005, pp.701-705.
12. D. Gruber, N. Ponath, J. Muller, and F. Lindstaedt, "Sputter-deposited Ultra-low Catalyst Loadings for PEM Fuel Cells," Journal of Power Sources, Vol.150, 2005, pp.67-72.
13. G. Q. Lu and C. Y. Wang, "Development of Micro Direct Methanol Fuel Cells for High Power Applications," Journal of Power Sources, Vol.144, 2005, pp.141-145.
14. R. S. Jayashree, J. S. Spendelow, J. Yeom, C. Rastogi, M. A. Shannon, and P. J. A. Kenis, "Characterization and Application of Electrodeposited Pt, Pt/Pd, and Pd Catalyst Structures for Direct Formic Acid Micro Fuel Cells," Electrochimica Acta, Vol.50, 2005, pp.4674-4682.
15. S. S. Hsieh, C. F. Huang, J. K. Kuo, H. H. Tsai, and S. H. Yang, "SU-8 Flow Field Plates for a Micro PEMFC," Journal of Solid State Electrochem, Vol.9, 2005, pp.121-131.
16. M. Agarwal, R. A. Gunasekaran, P. Coane, and K. Varahramyan, "Scum-free Patterning of SU-8 Resist for Electroforming Applications," Journal of Micromechanics and Microengineering, Vol.15, 2005, pp.130-135.
17. Y. G. Yoon, W. Y. Lee, G. G. Park, T. H. Yang, and C. S. Kim, "Effects of Channel and Rib Widths of Flow Field Plates on the Performance of a PEMFC," International Journal of Hydrogen Energy, Vol.30, 2005, pp.1363-1366.
18. S. U. Jeong, R. K. Kim, E. A. Cho, H. J. Kim, S. W. Nam, I. H. Oh, S. A. Hong, S. H. Kim, "A Study on Hydrogen Generation from NaBH4 Solution Using the High-Performance Co-B Catalyst," Journal of Power Sources, Vol.144, 2005, pp.129-134.
19. G. Karimi1, X. Li, "Electroosmotic Flow Through Polymer Electrolyte Membranes in PEM Fuel Cells," Journal of Power Sources, Vol.140, 2005, pp.1-11.
20. X. Yu, S. T. Tu, Z. Wang, Y. Qi, "On-Board Production of Hydrogen for Fuel Cells Over Cu/ZnO/Al2O3 Catalyst Coating in a Micro-Channel Reactor," Journal of Power Sources, Vol.150, 2005, pp.57-66.
21. S. S. Hsieh, S. H. Yang, J. K. Kuo, C. F. Huang, and H. H. Tsai, "Study of Operational Parameters on the Performance of Micro PEMFCs with Different Flow Fields," Energy Conversion and Management, Vol.47, 2006, pp. 1868-187.
22. S. S. Hsieh, C. L. Feng, and C. F. Huang, "Development and Performance Analysis of a H2/Air Micro PEM Fuel Cell Stack," Journal of Power Sources, Vol.163, 2006, pp.440-449.
23. S. Shimpalee, S. Greenway, and J. W. Van Zee, "The Impact of Channel Path Length on PEMFC Flow-field Design," Journal of Power Sources, Vol.160, 2006, pp.398-406.
24. H. Tawfik, Y. Hung, and D. Mahajan, "Metal Bipolar Plates for PEM Fuel Cell-A Review," Journal of Power Sources, Vol.163, 2007, 755-767.
25. J. Park, M. Matsubara, and X. Li, "Application of Lattice Boltzmann Method to a Micro-Scale Flow Simulation in the Porous Electrode of a PEM Fuel Cell," Journal of Power Sources, Vol.173, 2007, 404-414.
26. S. S. Hsieh, and K. M. Chu, "Channel and Rib Geometric Scale Effects of Flowfield Plates on the Performance and Transient Thermal Behavior of a Micro PEM Fuel Cell," Journal of Power Sources, Vol.173, 2007, 222-232.
27. X. Zhu, P. C. Sui, and N. Djilali, "Dynamic Behaviour of Liquid Water Emerging from a GDL Pore into a PEMFC Gas Flow Channel," Journal of Power Sources, Vol.172, 2007, 287-295.
28. D. Spernjak, A. K. Prasad, and S. G. Advani, "Experimental Investigation of Liquid Water Formation and Transport in a Transparent Single-serpentine PEM Fuel Cell," Journal of Power Sources, Vol.170, 2007, pp.334-344.
29. G. Strickland, S. Litster, and J. G. Santiago, "Current Distribution in Polymer Electrolyte Membrane Fuel Cell with Active Water Management," Journal of Power Sources, Vol.174, 2007, pp.272-281.
30. H. K. Atiyeh, K. Karan, B. Peppley, A. Phoenix, E. Halliop, and J. Pharoah, "Experimental Investigation of the Role of a Microporous Layer on the Water Transport and Performance of a PEM Fuel Cell," Journal of Power Sources, Vol.170, 2007, pp.111-121.
31. J. P. Owejan, T. A. Trabold, J. J. Gagliardo, D. L. Jacobsion, R. N. Carter, D. S. Hussey, and M. Arif, "Voltage Instability in a Simulated Fuel Cell Stack Correlated to Cathode Water Accumulation," Journal of Power Sources, Vol.171, 2007, pp.626-633.
32. X. Li, I. Sabir, and J. Park, "A Flow Channel Design Procedure for PEM Fuel Cells with Effective Water Removal," Journal of Power Sources, Vol.163, 2007, pp.933-942.
33. P. V. Leal, F. R. Palomo, F. Barragan, C. Garcia, and J. J. Brey, "Design of Control Systems for Portable PEM Fuel Cell," Journal of Power Sources, Vol.169, 2007, pp.194-197.
34. H. Woo and J. B. Benziger, "PEM Fuel Cell Current Regulation by Fuel Feed Control," Chemical Engineering Science, Vol.62, 2007, pp.957-968.
35. Kundu, J. H. Gil, C. R. Jung, H. R. Lee, S. H. Kim, B. Ku, and Y. S. Oh, "Micro Fuel Cells-Current Development and Applications," Journal of Power Sources, Vol.170, 2007, pp.67-78.
36. H. Nakajima, T. Konomi, and T. Kitahara, "Direct Water Balance Analysis on a Polymer Electrolyte Fuel Cell (PEFC): Effects of Hydrophobic Treatment and Micro-porous Layer addition to the Gas Diffusion Layer of a PEFC on its Performance during a Simulated Start-up Operation," Journal of Power Sources, Vol.171, 2007, pp.457-463.
37. Y. Fan, H. Hu, and H. Liu, "Enhanced Coulombic Efficiency and Power Density of Air-Cathode Microbial Fuel Cells with an Improved Cell Configuration," Journal of Power Sources, Vol.171, 2007, pp.348-354.
38. S. S. Martinez, L. A. Sanchez, A. A. Gallegos, P. J. Sebastian, "Coupling a PEM Fuel Cell and the Hydrogen Generation from Aluminum Waste Cans," Journal of Hydrogen Energy, Vol.32, 2007, pp.3159-3162.
39. L. Soler, J. Macan’as, M. Mu’noz, J. Casado, "Aluminum and Aluminum Alloys as Sources of Hydrogen for Fuel Cell Applications," Journal of Power Sources, Vol.169, 2007, pp.144-149.
40. X. Zhang, D. Zheng, T. Wang, C. Chen, J. Cao, J. Yan ,W. Wang, J. Liu, H. Liu, J. Tian, X. Li, H. Yang, B. Xia, "A Preliminary Study of A Miniature Planar 6-Cell PEMFC Stack," Journal of Power Sources, Vol.166, 2007, pp.441-444.
41. C. R. Jung, A. Kundu, B. Ku, J. H. Gil, H. R. Lee, J. H. Jang, "Hydrogen from Aluminum in a Flow Reactor for Fuel Cell Applications," Journal of Power Sources, Vol.175, 2008, pp.490-494.
42. E. D. Wang, P. F. Shi, C. Y. Du, X. R. Wang, "A Mini-Type Hydrogen Generator from Aluminum for Proton Exchange Membrane Fuel Cells," Journal of Power Sources, Vol.181, 2008, pp.144-148.
43. K. Akiyam, S. Matsumoto, A. Miyasak, T. Shodai, "An Air-Breathing Single Cell Small Proton Exchange Membrane Fuel Cell System with AB5-Type Metal Hydride and an Ultra-Low Voltage Input Boost Converter," Journal of Power Sources, Vol.186, 2009, pp.37-44.
44. S. H. Kim, H. Y. Cha, C. M. Miesse, J. H. Jang, Y. S. Oh, S. W. Cha, "Air-Breathing Miniature Planar Stack Using the Flexible Printed Circuit Board as A Current Collector," Journal of Hydrogen Energy, Vol.34460, 2009, pp.459-466.
45. H. Z. Wang, D. Y. C. Leung, M. K. H. Leung, M. Ni, "A Review on Hydrogen Production Using Aluminum and Aluminum Alloys," Renewable and Sustainable Energy Reviews, Vol.34, 2009, pp.845-853.
46. B. Alinejad, K. Mahmoodi, "A Novel Method for Generating Hydrogen by Hydrolysis of Highly Activated Aluminum Nano Particles in Pure Water," International Journal of Hydrogen Energy, Vol.34, 2009, pp.7934-7938.
47. J. He’lary, N. Salandre, J. Saillard, D. Poullain, A. Beaucamp, D. Autissier, "A Physico-Chemical Study of An NH3BH3-Based Reactive Composition for Hydrogen Generation," International Journal of Hydrogen Energy, Vol.34, 2009, pp.169-173.
48. L. Zhu, V. Swaminathan, B. Gurau, R. I. Masel, M. A. Shannon, "An Onboard Hydrogen Generation Method Based on Hydrides and Water Recovery for Micro-Fuel Cells," Journal of Power Sources, Vol.192, 2009, pp.556-561.
49. L. Soler, A. M. Candela, J. Macana’s, M. Mun’oz, J. Casado, "Hydrogen Generation by Aluminum Corrosion in Seawater Promoted by Suspensions of Aluminum Hydroxide," International Journal of Hydrogen Energy, Vol.34, 2009, pp.8511-8518.
50. W. David, P. Wolfgang, S. I. Eberhard, A. B. Tarek, M. Steffen, "Comments on Solid State Hydrogen Storage Systems Design for Fuel Cell Vehicles," International Journal of Hydrogen Energy, Vol.34, 2009, pp.6265-6270.
51. M. Fan, L. Sun, F. Xu, "Experiment Assessment of Hydrogen Production from Activated Aluminum Alloys in Portable Generator for Fuel Cell Applications," Energy, Vol.35, 2010, pp.1-5.
52. A. Kundu, J. H. Jang, J. H. Gil, C. R. Jung, H. R. Lee, S. H. Kim, and Y. S. Oh, "Micro Fuel Cells Current Development and Applications," Journal of Power Sources, Vol.170, 2007, pp.67-78.
53. S. T. Kline, and F.A. Mcclintock, "Describing Uncertainties in Single-Sample Experiments," Mechanical Engineering, Vol.75, 1953, pp.3-8.
54. R. J. Moffat, "Contributions to the Theory of Single-Sample Uncertainty Analysis," Journal of Fluids Engineering, Vol.104, 1982, pp.250-260.
55. Philip R. Bevington, "Data Reduction and Error Analysis for the Physical Sciences," Case Western Reserve University, 1969, pp.58-64.
56. Vern Lindberg, "Part I of Fundamental Measurements: Uncertainties and Error Propagation," 2000, pp.37-44.
57. www.powercam.cc/home/read_attach.php?id=166, 2010, pp.3-5.
58. 黃福坤, "實驗數據的處理與分析," http://www.phy.ntnu.edu.tw/demolab/html.php?html=Notes/dataProcess, 2010.
59. Z. Qi, A. Kaufman, "Activation of Low Temperature PEM Fuel Cells," Journal of Power Sources, Vol.111, 2002, pp.181-184.
60. C. Y. Wen, G. W. Huang, "Application of a Thermally Conductive Pyrolytic Graphite Sheet to Thermal Management of A PEM Fuel Cell," Journal of Power Sources, Vol.178, 2008, pp.132-140.
61. R. F. Mann, J. C. Amphlett, B. A. Peppley, C. P. Thurgood, "Application of Butler-Volmer Equations in the Modelling of Activation Polarization for PEM Fuel Cells," Journal of Power Sources, Vol.161, 2006, pp.775-781.
62. Q. Li, N. J. Bjerrum, "Aluminum as Anode for Energy Storage and Conversion: a Review," Journal of Power Sources, Vol.110, 2002, pp.1-10.
63. B. David, "Reaction of Aluminum with Sodium Hydroxide Solution as a Source of Hydrogen," Journal of The Electrochemical Society, Vol.117, 1970, pp.1097-1099.
64. 張文宗,"鋁渣資源化剩餘物之再利用探討," 成功大學資源工程學研究所碩士論文, 2003, pp.6-7.
65. F. Habashi, "A Short History of Hydrometallurgy," Hydrometallurgy, Vol.79, 2005, pp.15-22.