本實驗設計之微型平板質子交換膜燃料電池組是黃光製程技術製作SU 8流道板與單極板之微流道，並且利用微電鑄製程技術製作金屬流道板與單極板。本實驗之燃料電池組採用新型設計，將燃料之通道加工於壓力板（PMMA）內，使燃料供給的通道更方便且簡單，並針對不同方式的入口結合微型平板質子交換膜燃料電池組進行性能測量。實驗結果以VI曲線、PI曲線來表示。當完成性能曲線圖（VI、PI曲線）後，發現不同方式的入口對發電功率與電流密度有很大影響，因此利用由本實驗所量測出來的數據探討在不同方式入口燃料電池組之性能。

Planar μPEM Fuel Cell Stacks are designed and fabricated in-house through a deep UV lithography technique, with SU 8 photoresist used as the microstructure mold for the fuel cell flow channel or bipolar plates when micro electroforming. The fuel cell stacks use a new design which means installing the fuel channel into PMMA, by which the fuel supply channel becomes convenient and simplified. The performance of the stack is measured in different inlets, and the effect of the hydrogen inlets is explained. The experimental results are presented in the form of polarization VI curves and PI curves for the different types of inlet. Furthermore, the influence of the inlets is presented and discussed.

目錄 i
表目錄 iii
圖目錄 iv
符號說明 v
中文摘要 vii
Abstract viii
第一章 序論 1
1-1 前言 1
1-2 燃料電池發展之歷史與簡介 3
1-3 文獻回顧 4
1-4 研究目的 10
第二章 微型質子交換膜燃料電池組元件設計與製作 14
2-1 質子交換膜燃料電池組成元件 14
2-2 燃料電池組設計要點 19
2-3 微型質子交換膜燃料電池組元件設計與製作 21
2-3-1 黃光微影製程 21
2-3-2 微電鑄製程 24
2-3-3 母模結構移除 25
2-4 氫氣與氧化劑供給的設計 25
2-5 燃料電池的組裝 26
第三章 燃料電池性能分析 36
3-1 極化曲線原理 36
3-2 參考電極 37
3-3 極化現象 38
第四章 實驗設備與材料 43
4-1 實驗設備 43
4-2 實驗材料 47
第五章 誤差分析 52
第六章 實驗結果與討論 56
6-1 燃料與氧化劑通道不同對性能之影響 56
6-2 燃料電池的最佳流率探討 58
6-3 燃料與氧化劑供應對性能的影響現象探討 59
6-4 10-Cell平板燃料電池組與模組化 61
6-5 燃料電池組串聯之平均功率 62
第七章 結論與未來展望 71
7-1 結論 71
7-2 建議與未來展望 72
參考文獻 74
附錄 A 82

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