Responsive image
博碩士論文 etd-0806116-152409 詳細資訊
Title page for etd-0806116-152409
論文名稱
Title
添加交聯劑於全像儲存材料之製備技術與光學性質測量
Manufacturing Technique and Optical Property of Holographic Storage Materials with cross-linking agent
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
80
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2016-06-29
繳交日期
Date of Submission
2016-09-06
關鍵字
Keywords
交聯劑、丙烯醯胺、溶膠凝膠法、全像儲存材料
Holographic Storage Materials, Acrylamide, Sol-gel, Cross-linking agent
統計
Statistics
本論文已被瀏覽 5703 次,被下載 261
The thesis/dissertation has been browsed 5703 times, has been downloaded 261 times.
中文摘要
本實驗選用二氧化矽及聚乙烯醇,分別作為無機與有機基材。其中二氧化矽基材是利用溶膠-凝膠法製備,以四乙氧基矽烷(Tetraethyl orthosilicate, TEOS) 及矽烷偶合劑(3-Glycidoxypropyltrimethoxy silane, γ-GPTMS)作為前驅物,經溶膠凝膠反應形成二氧化矽網狀結構。
於不同基材中加入固定量單體丙烯醯胺(Acrylamide, AA) 及光起始劑(Irgacure 784) ,並添加不同比例交聯劑(N,N'-Methylenebisacrylamide, BMA)製備全像儲存材料。由光學測量證明,添加交聯劑,能減緩繞射效率衰退,使繞射效率提升。於Silica系列加入交聯劑BMA,其最大繞射效率由9.06 ± 3.42 %經加至76.74±5.34 %;PVA系列加入交聯劑BMA,並無提高繞射效率,但能改善衰退和
散射問題。
Abstract
In this study, the inorganic SiO2 and the organic PVA are selected to be different matrix systems. The inorganic SiO2 matrix is successful to be porous structure prepared by a sol-gel synthesis using Tetraethyl orthosilicate (TEOS) and 3-
Glycidoxypropyltrimethoxysilane (γ-GPMS) as precursors.
The porous SiO2 inorganic matrix and the PVA organic matrix also add a fixed amount of Acrylamide (AA) and Irgacure 784 with different amounts of N, N'-Methylenebisacrylamide (BMA), which prepared to be holographic storage materials.
According to the optical measurements, the decay of diffraction efficiency decreased which can increase the diffraction efficiency with adding the BMA. The diffraction efficiency of material based SiO2 inorganic matrix with adding the BMA increase from 9.06±3.42% to 76.74±5.34%. However, the diffraction efficiency of material based PVA
organic matrix can not obviously increase with adding the BMA. But, the problem of decay and scattering can improve in the PVA organic matrix with adding the BMA.
目次 Table of Contents
論文審定書 .................................................................................................................... i
論文公開授權書 ........................................................................................................... ii
誌謝 .............................................................................................................................. iii
摘要 .............................................................................................................................. iv
Abstract .......................................................................................................................... v
目錄 .............................................................................................................................. vi
圖目錄 .......................................................................................................................... xi
表目錄 ........................................................................................................................ xiii
第一章 緒論 ................................................................................................................. 1
1.1 前言 ............................................................................................................... 1
1.2 研究動機與目的 ........................................................................................... 2
第二章 理論基礎與文獻回顧 ..................................................................................... 3
2.1 全像儲存材料 ............................................................................................... 3
2.1.1 鹵化銀感光劑 ................................................................................. 3
2.1.2 光致變色材料 ................................................................................. 3
2.1.3 光折變材料 ..................................................................................... 3
vii
2.1.4 重鉻酸鹽明膠 ................................................................................ 4
2.1.5 感光高分子 ..................................................................................... 4
2.2 光聚合系統 ................................................................................................... 4
2.2.1 單體 ................................................................................................... 4
2.2.2 光交聯劑 ........................................................................................... 4
2.2.3 光起始劑 ........................................................................................... 5
2.3 光聚合原理 ................................................................................................... 8
2.3.1 光柵形成原理 ................................................................................... 8
2.3.2 體積全像光柵 ................................................................................... 9
2.4 溶膠-凝膠法 ............................................................................................... 9
2.4.1 溶膠-凝膠法介紹 ................................................................................... 9
2.4.2 溶膠凝膠法影響因素......................................................................... 10
2.5 全像術簡介................................................................................................... 14
第三章 實驗 ............................................................................................................... 15
3.1 實驗藥品 ..................................................................................................... 15
3.2 實驗流程 ..................................................................................................... 16
3.2.1 AA/Si薄膜 ....................................................................................... 16
3.2.2 AA/PVA薄膜 .................................................................................. 18
3.3 光學系統裝置 ............................................................................................. 20
viii
3.4 試片檢測流程 ............................................................................................. 21
3.5 實驗儀器 ..................................................................................................... 22
3.5.1 光學顯微鏡 ......................................................................................... 22
3.5.2 掃描式電子顯微鏡 ............................................................................. 22
3.5.3 原子力顯微鏡 ..................................................................................... 22
3.5.4 傅立葉轉換紅外線光譜儀 ................................................................. 23
3.5.5 薄膜特性分析儀................................................................................. 23
3.5.6 奈米壓痕系統..................................................................................... 23
3.6 試片代碼 ..................................................................................................... 24
3.6.1 Silica系列 ........................................................................................ 24
3.6.2 PVA系列 ......................................................................................... 24
第四章 結果與討論 ..................................................................................................... 25
4.1 基材對光學性質之影響 ............................................................................. 25
4.2 交聯劑(MBA)對光學性質影響 ................................................................. 27
4.3 高階繞射對繞射效率之影響 ..................................................................... 30
4.4 傅立葉轉換紅外線光譜儀(FTIR)分析 ...................................................... 35
ix
4.5 光學顯微鏡(OM)分析 ................................................................................ 42
4.6 原子力顯微鏡(AFM)分析 .......................................................................... 49
4.7 掃描式電子顯微鏡(SEM)分析 .................................................................. 52
4.8 薄膜特性分析 ............................................................................................. 56
4.8.1 Δn值理倫計算 ............................................................................... 56
4.8.2 薄膜特性分析儀之分析 ................................................................. 57
第五章 結論 ................................................................................................................. 58
5.1 Silica系列 .................................................................................................... 58
5.2 PVA系列 ..................................................................................................... 58
5.3 Silica系列與PVA系列比較 ........................................................................ 58
第六章 建議未來工作 ................................................................................................... 59
6.1 試片厚度探討 ............................................................................................. 59
6.2 PVA基材繞射效率衰退及繞射點散射探討 ............................................. 59
x
參考文獻 ..................................................................................................................... 60
附錄 ............................................................................................................................. 63
A. 奈米壓痕系統(Nano-indenter)分析 ........................................................... 63
A.1 比較基材機械性質 ............................................................................. 63
A.2 交聯劑添加量對機械性質之影響 ..................................................... 63
A.3 照光前後對機械性質之影響 ............................................................. 64
參考文獻 References
[1] C. J. Brinker and G. W. Scherer, "Sol-gel science: the physics and chemistry of
sol-gel processing: Academic press", 2013.
[2] E. Völkl, L. F. Allard, and D. C. Joy, "Introduction to electron holography:
Springer Science & Business Media", 2013.
[3] C. P. Chen, Y. Su, and C. G. Jhun, "Recent advances in holographic recording
media for dynamic holographic display," Journal of Optics and Photonics, vol. 1,
p. 1-8, 2014.
[4] M. W. Daniels, J. Sefcik, L. F. Francis, and A. V. McCormick, "Reactions of a
trifunctional silane coupling agent in the presence of colloidal silica sets in polar
media," Journal of Colloid and Interface Science, vol. 219, p. 351-356, 1999.
[5] L. Carretero, A. Murciano, S. Blaya, M. Ulibarrena, and A. Fimia, "Acrylamide-
N,N '-methylenebisacrylamide silica glass holographic recording material,"
Optics Express, vol. 12, p. 1780-1787, 2004.
[6] R. A. Lessard and G. Manivannan, "Holographic recording materials: an
overview," p. 2-23, 1995.
[7] W. R. Graver, J. W. Gladden, and J. W. Eastes, "Phase Holograms Formed by
Silver-Halide (Sensitized) Gelatin Processing," Applied Optics, vol. 19, p. 1529-
1536, 1980.
[8] Y. Hirshberg, "Reversible formation and eradication of colors by irradiation at
low temperatures. A photochemical memory model," Journal of the American
Chemical Society, vol. 78, p. 2304-2312, 1956.
[9] M. Serwadczak and S. Kucharski, "Photochromic gratings in sol-gel hybrid
materials containing cyanoazobenzene chromophores," Journal of Sol-Gel
Science and Technology, vol. 37, p. 57-62, 2006.
[10] A. Ashkin, G. D. Boyd, J. M. Dziedzic, R. G. Smith, A. A. Ballman, Levinste.Jj,
et al., "Optically-Induced Refractive Index Inhomogeneities in Linbo3 and Litao3
- (Ferroelectric Materials - Nonlinear Optics - E)," Applied Physics Letters, vol.
9, p. 72, 1966.
[11] T. A. Shankoff, "Phase holograms in dichromated gelatin," Appl Opt, vol. 7, p.
2101-5, 1968.
[12] R. Changkakoti and S. V. Pappu, "Study of the pH dependence of diffraction
61
efficiency of phase holograms in dye sensitized dichromated gelatin," Appl Opt,
vol. 25, p. 798, 1986.
[13] D. H. Close, A. D. Jacobson, J. D. Margerum, R. G. Brault, and F. J. Mcclung,
"Hologram Recording on Photopolymer Materials," Applied Physics Letters, vol.
14, p. 159, 1969.
[14] A. Fimia, P. Acebal, S. Blaya, L. Carretero, A. Murciano, and R. Madrigal, "A
comparative review of silver halide photopolymerizable system and sol-gel
holographic materials," in SPIE Europe Optics+ Optoelectronics, p. 735802-
735802-15, 2009.
[15] J. Guo, M. R. Gleeson, and J. T. Sheridan, "A review of the optimisation of
photopolymer materials for holographic data storage," Physics Research
International, vol. 2012, 2012.
[16] P. Mu and D. T. Plummer, Introduction to practical biochemistry: Tata McGraw-
Hill Education, 1988.
[17] M. Infusino, A. Ferraro, A. De Luca, R. Caputo, and C. Umeton, "POLYCRYPS
visible curing for spatial light modulator based holography," JOSA B, vol. 29, p.
3170-3176, 2012.
[18] M. Ortuño , S. Gallego , C. García , C. Neipp , A. Beléndez, and I. Pascual
"Optimization of a 1 mm thick PVA/acrylamide recording material to obtain
holographic memories: method of preparation and holographic properties,"
Applied Physics B, vol. 76, p. 851-857, 2003.
[19] R. Fuentes, E. Fernández, C. García, A. Beléndez, and I. Pascual, "Study of
reflection gratings recorded in polyvinyl alcohol/acrylamide-based
photopolymer," Applied optics, vol. 48, p. 6553-6557, 2009.
[20] A. Murciano, S. Blaya, L. Carretero, R. Madrigal, and A. Fimia, "Holographic
reflection gratings in photopolymerizable solgel materials," Optics letters, vol. 31,
p. 2317-2319, 2006.
[21] K. Osabe and H. Saito, "Stability of holographic gratings recorded on
photopolymer films using acrylamide as monomer and N, N'-
methylenebisacrylamide," in SPIE OPTO, p. 93860Q-93860Q-7, 2015.
[22] M. R. Gleeson and J. T. Sheridan, "A review of the modelling of free-radical
photopolymerization in the formation of holographic gratings," Journal of optics
A: pure and applied optics, vol. 11, p. 024008, 2009.
[23] P. Cheben and M. L. Calvo, "A photopolymerizable glass with diffraction
62
efficiency near 100% for holographic storage," Applied Physics Letters, vol. 78,
p. 1490-1492, 2001.
[24] J. Ebelman, "Mémoire sur de nouvelles combinaisons de l’acide borique avec les
éthers, et sur l'éther sulfureux," in Annales de chimie et de physique, p. 331, 1846.
[25] H. Schroeder, "Oxide layers deposited from organic solutions," Physics of thin
films, vol. 5, p. 87-141, 1969.
[26] R. K. Iler, "The chemistry of silica," ed: Wiley, New York, 1979.
[27] D. Gabor, "A new microscopic principle," Nature, vol. 161, p. 777, 1948.
[28] P. J. Vanheerden, "A New Optical Method of Storing and Retrieving
Information," Applied Optics, vol. 2, p. 387-392, 1963.
[29] E. N. Leith and Upatniek.J, "Wavefront Reconstruction with Diffused
Illumination + 3-Dimensional Objects," Journal of the Optical Society of America,
vol. 54, p. 1295, 1964.
[30] N. J. Phillips and D. Porter, "Advance in Processing of Holograms," Journal of
Physics E-Scientific Instruments, vol. 9, p. 631-634, 1976.
[31] W. Klein, "Theoretical efficiency of Bragg devices," Proceedings of the IEEE, vol.
54, p. 803-804, 1966.
[32] J. W. Goodman and S. C. Gustafson, "Introduction to fourier optics," Optical
Engineering, vol. 35, p. 1513-1513, 1996.
[33] J. Hanson, "Characteristic IR absorption frequencies of organic functional
groups," ed, 2013.
[34] H. Kogelnik, "Coupled wave theory for thick hologram gratings," Bell System
Technical Journal, vol. 48, p. 2909-2947, 1969.
[35] C. Wang, Y. Zhang, Y. Lu, and Y. Wei, "A novel bulk sol-gel process to prepare
monolithic silica materials," Journal of materials research, vol. 14, p. 4098-4102,
1999.
[36] Y. Uchiyama and H. Suzuki, "Anti-foaming agent," ed: Google Patents, 1992.
[37] R. Reichenbach-Klinke, P. Lange, C. Spindler, and G. Keilhofer, "Method of use
of a polyvinyl alcohol-based composition," ed: Google Patents, 2007.
電子全文 Fulltext
本電子全文僅授權使用者為學術研究之目的,進行個人非營利性質之檢索、閱讀、列印。請遵守中華民國著作權法之相關規定,切勿任意重製、散佈、改作、轉貼、播送,以免觸法。
論文使用權限 Thesis access permission:自定論文開放時間 user define
開放時間 Available:
校內 Campus: 已公開 available
校外 Off-campus: 已公開 available


紙本論文 Printed copies
紙本論文的公開資訊在102學年度以後相對較為完整。如果需要查詢101學年度以前的紙本論文公開資訊,請聯繫圖資處紙本論文服務櫃台。如有不便之處敬請見諒。
開放時間 available 已公開 available

QR Code