本論文採用溶膠凝膠法，合成出具單一分散性的二氧化矽奈米粒子。首先經由調整反應物四乙氧基矽烷(TEOS)的使用量，來改變合成出的奈米粒子之粒徑大小，並研究經由添加螢光染料或是鐵電性晶種來賦予二氧化矽奈米粒子特殊的功能性。另一方面利用重力沉降法使奈米粒子堆積成三維光子晶體，透過對系統的加熱，加速奈米粒子堆積的速度，在短時間內堆積出大面積的光子晶體結構，實驗中將探討溫度對於堆積效果的影響。最後利用製作出來的結構，做為模板以製作出反蛋白石結構，提高光子晶體內部空隙的空間佔有率，未來將可應用於反射式顯示器或是光子晶體雷射的製作。

In this study, the sol-gel method is used to synthesis mono-dispersed silica particles. The size of particles can be controlled by the usage of the tetraethyl orthosilicate (TEOS) in the chemical reaction, and the multifunctional silica particles can be formed with fluorescence dye or ferroelectric seeds. Moreover, the formation of photonic crystal structure with large area is accumulated through gravity sedimentation. The influence of temperatures on the effect of gravity sedimentation will be studied. Finally, the opal structures will be used as template to produce inverse-opal structures, which increase the proportion of void inside the photonic crystals and can be applied on the production of the reflective displays and the photonic crystal lasers.

論文審定書 i
致謝 ii
中文摘要 iii
Abstract iv
目錄 v
圖次 vii
表次 x
第一章　緒論 1
第二章 簡介 3
2.1 光子晶體簡介 3
2.2 奈米粒子簡介 10
第三章 相關理論 15
3.1光子能隙計算 15
3.2奈米粒子的成核理論 17
第四章 實驗方法 19
4.1溶膠凝膠法合成二氧化矽奈米粒子 19
4.2玻璃表面的親水性處理 21
4.3樣品的量測 21
4.4奈米粒子的堆疊 22
4.5反蛋白石結構的製作 23
4.6具功能性的奈米粒子合成 24
4.7二氧化矽膠晶自發放大輻射 25
第五章 結果與討論 27
5.1 二氧化矽奈米粒子的合成 27
5.2反蛋白石結構 39
5.3二氧化矽膠晶放大自發輻射 42
第六章 總結與未來展望 44
6.1 總結 44
6.2未來展望 45
參考文獻 46

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