本研究主要分析高屏峽谷岩心沉積物中多環芳香烴濃度隨時間分佈的情形，藉以回溯多環芳香烴污染史、污染來源及傳輸途徑。並於高屏峽谷內施放沉積物收集器，以瞭解沉積物及多環芳香烴之傳輸機制與通量。
研究結果顯示高屏峽谷各岩心中的總多環芳香烴平均濃度呈現相近之程度，為310 ng/g dry wt.（264∼364 ng/g），但各岩心之濃度趨勢並不相同，其原因可能為各岩心之沉積速率或多環芳香烴來源不同所造成。在多環芳香烴來源方面，各岩心表層皆傾向石油來源，隨深度的增加漸傾向燃燒來源或石油、燃燒混合來源，其中最外海之岩心C980、S1在底層有較明顯之生物來源。而各岩心中總多環芳香烴濃度與可能致癌及致突變性的benzo[a]pyrene 濃度皆遠低於各項生物影響指標，表示對底棲生物無明顯危害。若與國外文獻比較，高屏峽谷屬低多環芳香烴污染區。
就高屏峽谷之多環芳香烴污染史而言，在1893-1935年間，總多環芳香烴濃度呈現逐年減少的趨勢，可能與台灣地區之能源使用結構由燃燒煤炭逐漸轉換為石油有關。於1935-1949年間有較高的總多環芳香烴濃度，其可能為二次大戰時大鵬灣遭美軍大肆轟炸（1944年），導致火災、沉船及洩油事件產生高含量多環芳香烴。於1949-2004年間濃度呈現逐年增加的趨勢，可能為高屏地區重工業發展所造成。
佈署於高屏峽谷之沉積物收集器，上、下串列總多環芳香烴平均通量分別為66及108 μg/m2/d，結果顯示高屏峽谷之總多環芳香烴通量遠高於國外海域測值。而沉降顆粒之多環芳香烴來源以石油來源為主，其結果與高屏峽谷各岩心表層傾向石油來源相吻合，表示近幾十年來高屏峽谷中之多環芳香烴主要為石油來源。

Cores and sediment traps collected from Kao-ping Canyon were used to reconstruct historical record of PAHs contamination and find out the possible sources, distributions, trends and flux of PAHs. The sedimentary record of PAHs shows that the average concentration of total PAHs was 310 ng/g dry wt. (264∼364 ng/g) which was lower than coasts of the other countries. According to diagnostic ratios and statistical analysis, we identify sources of PAHs and suggest that all up-cores were dominated by petrogenic sources, but all down-cores except for C980 and S1 were tended to pyrogenic or mixed sources. In contrast, both C980 and S1 were showed higher perylene/ΣPAHs (%), which suggests that biogenic sources dominate in C980 and S1. In comparison with sediment quality guidelines (SQGs), the PAHs concentrations of all sediment cores weren’t exceeded the criteria, which suggests that no evident adverse biological effects exist caused by PAHs in Kao-ping Canyon.
It shows that the transition from coal to petroleum fuel use corresponding to the total concentrations of PAHs decrease recorded during 1893-1935 period in the sediment core. A PAHs concentration peak also recorded during the World War Ⅱ, 1893-1935. Because of increase of importing fossil fuel and the growth of heavy industrials in Kao-Ping area, the total concentrations of PAHs were shown evidence of increase again since 1950s in the core from Kao-ping Canyon.
The average PAHs flux in the upper and lower mooring deployed in Kao-ping Canyon were 66 and 108 μg/m2/d, respectively, which were higher than coasts of the other countries. The PAHs sources of sinking particles were dominated by petrogenic sources which were as similar sources as all up-cores.

摘要
目錄 Ⅰ
表目錄 Ⅲ
圖目錄 Ⅳ
第一章 前言 1
1-1 研究動機 1
1-2 研究目的 2
第二章 文獻回顧 3
2-1 多環芳香烴（PAHs） 3
2-1-1 多環芳香烴之來源 3
2-1-2 多環芳香烴之物理與化學特性 4
2-1-3 多環芳香烴之危害 5
2-1-4 多環芳香烴之化學指紋分析 5
2-2 研究區域－高屏峽谷 6
2-2-1 海底峽谷 6
2-2-2 高屏峽谷之地形特徵 7
2-2-3 高屏峽谷之形成原因 8
2-2-4 高屏峽谷之流場 8
2-3 岩心之應用 9
第三章 研究方法 11
3-1 材料與儀器 11
3-1-1 材料 11
3-1-2 儀器設備 11
3-2 試藥及器具前處理 12
3-3 樣品之採樣與保存 12
3-4 樣品前處理 13
3-5 分析方法 13
3-5-1 顆徑分析 13
3-5-2 總有機碳（TOC）分析 13
3-5-3 多環芳香烴分析 14
3-6 品保及品管（QA�QC） 15
3-6-1 方法回收率 15
3-6-2 重複分析 16
3-6-3 標準查核樣品分析 16
3-6-4 方法偵測極限 16
3-7 群集分析（Hierarchical Cluster Analysis, HCA） 16
第四章 結果與討論 18
4-1 總多環芳香烴之濃度趨勢 18
4-2 總多環芳香烴濃度與岩心位置之關係 20
4-3 總多環芳香烴濃度、總有機碳及粒徑之相關性分析 22
4-4 多環芳香烴之來源 23
4-5 近代之多環芳香烴來源 25
4-6 多環芳香烴污染史探討 26
4-7 Perylene之來源探討 27
4-8 沉積物品質指標（Sediment Quality Guidelines, SQG） 29
4-9 國外文獻比較 30
4-10 高屏峽谷總多環芳香烴之通量（fluxes） 30
第五章 結論與建議 33
參考文獻 95
附錄 104

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