卡唑配位基與氯化銅合成出來的銅金屬錯化合物能夠利用逆向原子轉移自由基聚合的技術將甲基丙烯酸甲酯進行聚合反應。

1,8-bis(phenylimino)-3,6-ditertbutyl-carbazole is synthesized and characterized, which can be complexed with copper(II) halide by deprotonation and transmetallation. The resulting copper complexes enable to polymerize MMA through RATRP process.

目錄
章節 頁次
第一章 緒論
1-1.前言.....................................................1
1-2.活性/控制自由基聚合........................3
1-3.原子轉移自由基聚合........................10
1-4.結論....................................................15

第二章 合成1,8-雙取代基卡唑配位基

2-1. 研究動機............................................16
2-2. 實驗步驟與探討................................17

第三章.1,8-雙亞胺基卡唑金屬錯化合物的合成與反應

3-1. 含雙亞胺基卡唑之錯化合物合成 ..................................................................36
3-2. 1,8-雙亞胺基卡唑在鹼性條件之錯化合物合....................................................................37
3-3. 8-雙亞胺基卡唑金屬錯化合物之合成....................................................................39
3-3-1. [1,8-bis(phenylimino)-3,6-ditertbutyl-carbazole]-
ZrCl3之合成........................................40
3-3-2. [1,8-bis(phenylimino)-3,6-ditertbutyl-carbazole]-
NiX(X=Cl,Br)之合成.................................41
3-3-3. [1,8-bis(phenylimino)-3,6-ditertbutyl-carbazole]-
CuX之合成................................................47

3-4.銅金屬錯化合物的應用......................... ..53
3-5.1,8-bis(imidazolyl) -3,6-ditertbutyl- carbazole
之合成......................................................62
3-6. 結論..........................................................66

第四章 實驗部分

4-1.一般實驗....................................................67
4-2.物理性質的測量........................................67
4-3.實驗步驟....................................................68

參考資料..............................................................86

※附錄一 藥品

※附錄二 X-ray data

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