論文使用權限 Thesis access permission：自定論文開放時間 user define
開放時間 Available：
校內 Campus： 已公開 available
校外 Off-campus： 已公開 available
博碩士論文 etd-0810112-150811 詳細資訊
Title page for etd-0810112-150811
論文名稱 Title |
熱處理對Fe-10Mn-3Al-0.6C合金之拉伸性質與組織之影響 The effect of heat treatment on the tensile property and microstructure of Fe-10Mn-3Al-0.6C alloy. |
||
系所名稱 Department |
|||
畢業學年期 Year, semester |
語文別 Language |
||
學位類別 Degree |
頁數 Number of pages |
166 |
|
研究生 Author |
|||
指導教授 Advisor |
|||
召集委員 Convenor |
|||
口試委員 Advisory Committee |
|||
口試日期 Date of Exam |
2012-07-30 |
繳交日期 Date of Submission |
2012-08-10 |
關鍵字 Keywords |
沃斯田鐵、碳化物、退火、第三代高強度汽車鋼板、變形雙晶、肥粒鐵 ferrite, carbide, annealing, TWIP, austenite |
||
統計 Statistics |
本論文已被瀏覽 5698 次，被下載 366 次 The thesis/dissertation has been browsed 5698 times, has been downloaded 366 times. |
中文摘要 |
高錳鋼在變形過程中產生大量的變形雙晶，因此具有很高的強度及良好的延展性。錳含量的改變會影響材料的stacking fault energy (SFE)的大小，因此影響變形雙晶的形成與發展。本實驗透過退火溫度和時間的改變，欲改變材料的微觀結構，期望達到達第三代高強度汽車鋼板(3rd AHSS)之目標性能。 本實驗發現Fe-10Mn-3Al-0.6C冷軋板材在675℃退火處理，可以得到奧斯田鐵相及少量的肥粒鐵相。退火後的試片以沃斯田鐵相為主，其中肥粒鐵相隨著退火時間的增加其體積分率及晶粒大小並無明顯的改變，且兩相成份也未隨退火時間的增加而改變。軋延的變形組織和晶界上生成的碳化物會隨著退火時間的增加而減少，使得材料的拉伸強度及延伸率隨著退火時間的增加而增加。試片經拉伸後，奧斯田鐵相中有變形雙晶的產生，因此使得材料具有高的加工硬化率、拉伸強度及延伸率。因沃斯田鐵相的成分並未隨著退火時間的增加而有所變化，故其疊差能未發生改變，因此變形雙晶效應在不同退火時間對本鋼材的影響並不大。在最佳熱處理條件下，Fe-10Mn-3Al-0.6C鋼材的拉伸強度可達900MPa，延伸率可達40%，此性質已達三代高強度汽車鋼板之目標性能。 |
Abstract |
Twin induced plasticity (TWIP) steel is a new type of structural steel, which is characterized by both high strength and superior ductility. The key to twin formation lies in the control of the stacking fault energy (SFE) of the alloy. In this thesis, the effect of heat treatment on the tensile property and microstructure of a Fe-10Mn-3Al-0.6C alloy was studied. After annealing at 675℃ for different times, It was found that both austenite and ferrite phases existed. The volume fraction and composition of these two phases did not change significantly by the heat treatment conditions used. When annealed at 675℃, increasing annealing time caused the carbides formed at grain boundaries gradually dissolved, and led to the higher ultimate tensile stress, 900MPa, and elongation, 40%. Deformation twins were formed in the austenite phase after tensile test in the annealed specimens, indicating that TWIP behavior occurred. The best tensile property of Fe-10Mn-3Al-0.6C alloy obtained by annealing at 675℃ is within the target property of the 3rd AHSS. |
目次 Table of Contents |
目錄 目錄-------------------------------------------------------------------------------------------------- i 表目錄----------------------------------------------------------------------------------------------iii圖目錄--------------------------------------------------------------------------------------------i 前言-----------------------------------------------------------------------------------------1 文獻回顧-----------------------------------------------------------------------------------2 2-1 高錳鋼--------------------------------------------------------------------------------2 2-2高錳鋼的熱力學性質---------------------------------------------------------------4 2-2-1 TWIP鋼中的變形組織與加工硬化---------------------------------------4 2-2-2 TWIP鋼中影響加工硬化的因子--------------------------------------16 2-2-3 TWIP鋼的加工硬化率和雙晶初始結構的關係----------------------19 研究目的---------------------------------------------------------------------------------22 實驗方法---------------------------------------------------------------------------------23 4-1實驗材料-----------------------------------------------------------------------------23 4-2拉伸測試-----------------------------------------------------------------------------23 4-3 XRD繞射分析----------------------------------------------------------------------24 4-4 EBSD分析與其試片製作--------------------------------------------------------24 4-5光學顯微鏡與掃描式電子顯微鏡-----------------------------------------------24 4-6 X光成份分析系統(EDS)分析---------------------------------------------------25 4-7熱膨脹儀-----------------------------------------------------------------------------25 實驗結果---------------------------------------------------------------------------------26 5-1熱膨脹儀-----------------------------------------------------------------------------26 5-2應力應變曲線-----------------------------------------------------------------------26 5-3光學顯微鏡--------------------------------------------------------------------------27 5-4 XRD----------------------------------------------------------------------------------29 5-5 SEM----------------------------------------------------------------------------------30 5-6 EBSD---------------------------------------------------------------------------------31 5-7 EDS-----------------------------------------------------------------------------------31 討論---------------------------------------------------------------------------------------33 結論---------------------------------------------------------------------------------------38 參考文獻---------------------------------------------------------------------------------39 表-------------------------------------------------------------------------------------------------43 圖-------------------------------------------------------------------------------------------------62 |
參考文獻 References |
[1] O Grassel, L Kruger, G Frommeyer, LW. Meyer ,Int J Plast ,(2000),16,1391. [2] Y Lu, B Hutchinson, DA Molodov, G Gottstein. Acta Mater,( 2010),58,3079. [3] JE Jin,YK Lee., Mater Sci Eng A,(2009),527,157. [4] JK Kim, L Chen, HS Kim, SK Kim, Y Estrin, BCD Cooman, Metall Mater Trans A ,(2009),40,3147. [5] S Curtze, VT Kuokkala, Acta Mater ,(2010),58,5129. [6] I Gutierrez-Urrutia, S Zaefferer, D Raabe, Mater Sci Eng A ,(2010),527,3552. [7] H Idrissi, K Renard, D Schryvers, PJ Jacques,Scripta Mater ,(2010),63,961. [8] Y Lu, DA Molodov, G Gottstein, Acta Mater ,(2011),59,3229. [9] JD Yoo, KT Park , Mater Sci Eng A ,(2008),496,417. [10] JD Yoo, SW Hwang, KT Park, Metall Mater Trans A ,(2009),40,1520. [11] GB Olson, M Cohen.,Metall Trans A ,(1976),7,1897. [12] GB Olson, M Cohen, Metall Trans A ,(1976),7,1905. [13] B.W. Oh, S. J. Cho, Y. G. Kim, Y. P. Kim, W. S. Kim , S. H.Hong, Mater. Sci. Eng. A ,(1995), A197,147. [14] S. Allain, J. P. Chateau, O. Bouaziz, S. Migot , N. Guelton:,Mater. Sci. Eng. A ,(2004),387–389,306. [15] X. Tian, H. Li and Y. Zhang: J. ,Mater. Sci.,( 2008),43,6214. [16] X. Tian and Y. Zhang, Mater. Sci. Eng. A,( 2009),516,73. [17] J. Kim, S.-J. Lee and B. C. de Cooman: Scr. Mater,( 2011),65,363. [18] J. Kim, B. C. de Cooman:Metall., Mater. Trans. A ,(2011),42,932. [19] A. Yakubtsov, A. Ariapour , D. D. Perovic, Acta Mater( 1999),47,1271 [20] G. Frommeyer, U. Brux and P.Neumann,ISIJ Int.,(2003),43,438. [21] S. Alain, J.-P. Chateau, O. Bouaziz, S. Migot , N. Guelton,Mater. Sci. Eng. A, (2004),387–389,158 [22] A. Dumay, J.-P. Chateau, S. Allain, S. Migot ,O. Bouaziz, Mater. Sci. Eng. A ,(2008),483–484,184. [23] J.-E. Jin and Y.-K. Lee, Mater. Sci. Eng. A ,(2009), 527,157. [24] B. X. Huang, X. D. Wang, L. Wang , Y. H. Rong, Metall. Mater. Trans. A ,(2008),39,717. [25] X. Tian, H. Li and Y. Zhang, J. Mater. Sci.,(2008), 43,6214. [26] X. D. Wang, B. X. Huang,Y. H. Rong, Philos. Mag. Lett.,(2008), 88,845. [27] H. Idrissi, L. Ryelt, M. Veron, D. Schryvers an, P. J. Jacques,Scr. Mater,(2009),60, 941. [28] A. Saaed-Akbari, J. Imlau, U. Prahl , W. Bleck, Metall. Mater.Trans. A ,(2009),40,3076. [29] V. T. Witusiewicz, F. Sommer , E. J. Mittemeijer, J. Phase Equilib. Diff. ,(2004),25,346. [30] J. K. Jung, O. Y. Lee, Y. K. Park, D. E. Kim, K. G. Jin, S. K. Kim , K. H. Song, J. Kor., Inst. Met. Mater,(2008),46:627. [31] B. C. De Cooman, O. Kwon , K.-G. Chin, Materials Science and Technology ,(2012),38,513. [32] G. Dini, R. Ueji, A. Najafizadeh , S. M. Monir-Vaghefi, Mater.Sci. Eng. A ,(2010),527,2759. [33] J.G. Sevillano, Scripta Mater.,( 2009), 60,336. [34] Gutierrez-Urrutia, D. Raabe ,Acta Materialia,( 2011), 59 ,6449. [35] Jae-Eun Jin, Young-Kook Lee, Mater. Sci. Eng. A. ,(2009),527,157. [36] D. Barbier, N. Gey, S. Allain, N. Bozzolo, M. Humbert, Mater. Sci. Eng. A ,(2009),500,196. [37] K. Renard, P.J. Jacques ,Mater Sci Eng A,(2012),542,8. [38] H. Idrissi, K. Renard, L. Ryelandt, D. Schryvers, P.J. Jacques, Acta Mater ,(2010),58,2464. [39] D. Barbier, N. Gey, S. Allain, N. Bozzolo, M. Humbert, Mater. Sci. Eng. A ,(2009),500,196. [40] I. Gutierrez-Urrutia, D. Raabe, Acta Mater.,( 2011),59,6449. [41] I. Gutierrez-Urrutia, S. Zaefferer, D. Raabe, Mater. Sci. Eng. A ,(2010),527, 3552. [42] S. Dancette, M.A. Melchior, K. Renard, L. Delannay, P.J. Jacques, Acta Mater.,(2012),60,2135. [43] O. Bouaziz, H. Zurob, B. Chebab, J. D. Embury, S. Allain , M. Huang, Mater. Sci. Technol,(2011),27,707. [44] F. Barlat, unpublished results, Graduate Institute of Ferrous Technology, POSTECH, Pohan, Korea, (2010). [45] O. Bouaziz , N. Geulton, Mater. Sci. Eng. A ,(2001), 319–321, 246. [46] S. Allain, J.-P. Chateau and O. Bouaziz: Mater. Sci. Eng. A 2004;A387–389:143. [47] S. Allain, J.-P. Chateau, D. Dahmoun, O. Bouaziz, Mater. Sci. Eng. A,( 2004),387–389,272. [48] U. F. Kocks , H. Mecking, Acta Metall.,(1981), 32,1865. [49] J.-E. Jin and Y.-K. Lee, Mater. Sci. Eng. A, (2009),527,157. [50] M. N. Shiekhelsouk, V. Favier, K. Inal , M. Cherkaoui, Int. J. Plast. , (2009), 25 , 105. [51] A. Saeed-Akbari,Mosecker,A.Schwedt,W.Bleck,( 2011),34,1668. [52] A. Saeed-Akbari, J. Imlau, U. Prahl, W. Bleck, Metall. Mater.Trans. A ,(2009),40,3076. [53] A. Saeed-Akbari, Mechanism Maps, Mechanical Properties, andFlow Behavior in High-Manganese TRIP/TWIP and TWIP Steels,Shaker Verlag, Aachen, (2011). [54] R. Ueji, N. Tsushida, D. Terada, N. Tsuji, Y. Tanaka, A.Takemura, K. Kunishige, Scripta Mater,(2008),59,963. [55] H. Idrissi, K. Renard, D. Schryvers , P.J. Jacques. Scripta Materialia, (2010),63,961. |
電子全文 Fulltext |
本電子全文僅授權使用者為學術研究之目的，進行個人非營利性質之檢索、閱讀、列印。請遵守中華民國著作權法之相關規定，切勿任意重製、散佈、改作、轉貼、播送，以免觸法。 |
紙本論文 Printed copies |
紙本論文的公開資訊在102學年度以後相對較為完整。如果需要查詢101學年度以前的紙本論文公開資訊，請聯繫圖資處紙本論文服務櫃台。如有不便之處敬請見諒。 開放時間 available 已公開 available |
QR Code |
國立中山大學 圖書與資訊處 │ 諮詢服務：2452 論文審查小組 │ 服務信箱 │ 系統開發維運：圖資處知識創新組
Office of Library and Information Services, National Sun Yat-sen University │ Contact Us : 2452 Thesis Format Review Team , Mail │ Development and operations : Knowledge Innovation Division, LIS