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博碩士論文 etd-0811117-145844 詳細資訊
Title page for etd-0811117-145844
論文名稱
Title
利用時變兆赫波研究含金谷胱甘肽奈米粒子發光溶液之光學特性
Study of optical properties of Au/Glutathione nanoparticles solution using Terahertz time domain spectroscopy
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
62
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2017-07-24
繳交日期
Date of Submission
2017-09-11
關鍵字
Keywords
介電常數、折射率、金奈米粒子、谷胱甘肽、兆赫波時域
dielectric constant, refractive index, gold nanoparticles, THz-TDS, GSH
統計
Statistics
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中文摘要
在本論文中我們主要利用時變兆赫波研究含金奈米粒子發光溶液在兆赫波波段之光學性質,不同液體溶液樣品所對應到的折射率及介電常數的數值分析,當在GSH+Au之離子水溶液加上鑭系金屬離子形成發光強度更加突出的溶液之後,我們發現其在介於0.3~2.0 THz區間內的折射率與介電常數會隨著頻率增加而有下降的趨勢,且對應數值大小會較GSH+Au離子之水溶液還小。
Abstract
In this thesis we mainly do research about optical properties of luminous solution that has gold nanoparticles in Terahertz spectral region using terahertz time-domain spectroscopy and data analysis of different solution samples corresponding to refractive index and dielectric constant. After adding rare earth elements to the ionic solution of GSH+Au to form a solution that has a higher light intensity, we found that the refractive index and dielectric constant in the region between 0.3~2.0 THz will decrease as the frequency increases. In addition, the corresponding values will be less than the ionic solution of GSH+Au.
目次 Table of Contents
論文審定書......i
致謝......ii
摘要......iii
Abstract......iv
目錄......v
圖次......vi
表次......ix
第一章 緒論......1
1-1前言......1
1-2兆赫波簡介......2
1-3兆赫波發展史......3
1-4聚集誘導發光效應簡介......4
1-5產生兆赫波簡介......5
1-6文獻探討......6
第二章 實驗系統架設與介紹......10
2-1光路架設......10
2-2 Mai Tai Laser介紹......12
2-3 PC-Antenna介紹......13
2-4鎖相放大器(Lock-in,SR850)介紹......13
2-5 Balance Detector介紹......15
第三章 實驗原理介紹......16
3-1光電導偶極天線產生及偵測兆赫波原理......16
3-2光電導偶極天線產生及偵測兆赫波原理推導......16
3-3自由空間電光取樣偵測......19
3-4數據分析原理......21
第四章 介紹樣品與實驗結果......24
4-1樣品介紹......24
4-2實驗結果......28
第五章 結論......49
參考資料......50
參考文獻 References
1. Y. Hong, J. W. Y. Lam and B. Z. Tang, “Aggregation-induced emission”, Chem. Soc. Rev. 40,5361 (2011).
2. Y. Yu,C. Feng,Y. Hong , J. Liu , S. Chen , K. M. Ng ,K. Q. Luo , and B. Z. Tang ‘‘Cytophilic Fluorescent Bioprobes for Long-Term Cell Tracking’’, Adv. Mater. 23 (2011).
3. Y. Hong, J. W. Y. Lam and B. Z. Tang, ‘‘Aggregation-induced emission : phenomenon, mechanism and applications’’, Chem.Commun. 4332 (2009).
4. M. Tonouchi, “Cutting-edge terahertz technology”, Nat. Photonics. 1, 97 (2007).
5. X.C. Zhang, “Introduction to THz Wave Photonics”,Springer (2010).
6. B. Zhu , Y. Chen , K. Deng , W. Hu , and Z. S. Yao, “Terahertz Science and Technology and Applications”, PIERS Proceedings, Beijing, China, March 23–27 (2009).
7. E. Pickwell and V.P.Wallace “Biomedical applications of terahertz technology”,
J. Phys. D: Appl. Phys. 39,301 (2006).
8. G. P. Williams ,“Filling the THz gap—high power sources and applications”, IOP Publishing Ltd, Rep. Prog. Phys. 69,301 (2006).
9. G. Mourou, C. V. Stancampiano, A. Antonetti, and A. Orszag, “Picosecond
microwave pulses generated with a subpicosecond laser‐driven semiconductor
switch”, Appl. Phys. Lett. 39, 295 (1981).
10. D. H. Auston, K. P. Cheung, and P. R. Smith, “Picosecond photoconducting
Hertzian dipoles”, Appl. Phys. Lett. 45, 284 (1984).
11. C.h. Fattinger and D. Grischkowsky, “ Point source terahertz optics”, Appl. Phys.
 Lett. 53, 1480 (1988).
12. J. T. Darrow, X. C. Zhang, D. H. Auston, and J. D. Morse , “Saturation properties  
 of large-aperture photoconducting antennas”, IEEE Journal of Quantum Electron.
vol. 28.(1992).
13. Q. Wu, M. Litz, and X. C. Zhang, “Broadband detection capability of ZnTe
electro-optic field detectors”, Appl. Phys. Lett. 68, 2924 (1996).
14. Q. Wu and X. C. Zhang, “Design and Characterization of Traveling-Wave
Electrooptic Terahertz Sensors”,IEEE J. Sel. Top. Quantum Electron. 2, 693 (1996).
15. K. Liu, A. Krotkus, K. Bertulis, J. Xu, and X. C. Zhang, “Terahertz radiation from
n-type GaAs with Be-doped low-temperature-grown GaAs surface layers”, J. Appl.
Phys, 94, 3651 (2003).
16. J. N. Heyman, N. Coates, A. Reinhardt, and G. Strasser, “Diffusion and drift in
terahertz emission at GaAs surfaces”, Appl. Phys. Lett.83, 5476 (2003).
17. S. Rihani, R. Faulks, H. E. Beere, I. Farrer, M. Evans, D. A. Ritchie, and M.
Pepper, “Enhanced terahertz emission from a multilayered low temperature grown
GaAs structure”, Appl. Phys. Lett. 96, 091101 (2010).
18. M. Currie, F. Quaranta, A. Cola, E. M. Gallo, and B. Nabet , “Low-temperature
grown GaAs heterojunction metal-semiconductor-metal photodetectors improve
speed and efficiency” , Appl. Phys. Lett. 99, 203502 (2011).
19. Y. Hong, J. W. Y. Lam and B. Z. Tang ‘‘Aggregation-induced emission’’ Chem. Soc. Rev. 40,5361 (2011).
20. H. Wang , E. Zhao , J. W. Y. Lam,and B. Z. Tang. ‘‘AIE luminogens: emission brightened by aggregation’’, Materials Today. Vol. 00, No.00 (2015).
21.X. C. Zhang, “Introduction to THz Wave Photonics”,Springer, New York, (2010).
22.W. Weining, Y. Haitao, Y. Weiwei , Z. Guozhong , Z. Cunlin, L. Haibo,Z.
Xicheng“THz spectrum of reduced glutathione”, Science in China Ser. G Physics. Vol.48,No.5,585 (2005).
23. J. Xu,Kevin W, Plaxco,S. J. Allen, ‘‘Absorption spectra of liquid water and aqueous buffers between 0.3 and 3.72 THz’’, THE JOURNAL OF CHEMICAL PHYSICS,124, 036101 (2006).
24.Masaya Nagai, Hiroyuki Yada, Takashi Arikawa, and Koichiro Tanaka, ‘‘Terahertz time-domain attenuated total reflection spectroscopy in water and biological solution’’, Int. J. Infrared Milli. Waves 27 (2006).
25.L. Duvillaret, F. Garet, and J. L. Coutaz, ‘‘A Reliable Method for Extraction of Material Parameters in Terahertz Time-Domian Spectroscopy’’, IEEE, 2, 739 (1996).
26.B. Harbecke, “Application of Fourier's Allied Integrals to the Kramers-Kronig Transformation of Reflectance Data”, Appl. Phys.A40 (1986).
27.J. A. Bardwell and M. J. Dignam, “Extensions of the Kramers-Kronig transformation
that cover a wide range of practical spectroscopic applications”, The Journal of Chemical Physics, 83, 5468 (1985).
28. H. Tuononen, E. Gornov, J. A. Zeitler, J. Aaltonen, and K. E. Peiponen, “Using modified Kramers–Kronig relations to test transmission spectra of porous media in THz-TDS”, OPTICS LETTERS, Vol. 35, No. 5,631 (2010).
29.X. Zou, M. He, D. Springer, D. Lee, S. K. Nair, “Effect of annealing on the temperature-dependent dielectric properties of LaAlO3 at terahertz frequencies”, AIP Advances. 2, 012120 (2012).
30.K. Yamamoto,M. H. Kabir,K. Tominaga“The importance of glutathione in human
disease”, J. Opt. Soc. Am.B, Vol.22, No.11,145 (2005).
31.J. Sun and Y. Jin, “Fluorescent Au nanoclusters: recent progress and sensing applications”, J. Mater. Chem. C. 2 (2014).
32.J. F. Rusling, G. Sotzing , F. Papadimitrakopoulosa, “Designing nanomaterial-
enhanced electrochemical immunosensors for cancer biomarker proteins”, Bioelectrochemistry. 76 (2009).
33.X. T. Wu, C. X. Li, S. H. Liao, L. Li, T. T. Wang, Z. M. Su,C. G. Wang, J. H. Zhao, C. P. Sui, and J. Lin, “Silica-Encapsulated Gd3+-Aggregated Gold Nanoclusters for In Vitro and In Vivo Multimodal Cancer Imaging”, Chem. Eur. J. 20 (2014).
34.Plusquellic D. F., Siegrist K, Heilweil E.J. and Esenturk O. ‘‘Applications of terahertz spectroscopy in biosystems’’ , C. Phys. Chem. 8, 2412 (2007).
35.Takehito Suzuki, Koyuru Takayama, Satoshi Yamauchi, Yoh Imai, and Masayoshi Tonouchi ‘‘Measurement of Water Absorption Coefficient using Terahertz Time-Domain Spectroscopy’’, Proc. IRMMW-THz 09, M5E27. 0371 (2009).
36. K. Yamamoto, M. H. Kabir and K. Tominaga‘‘Terahertz time-domain spectroscopy of sulfur-containing biomolecules’’, J. Opt. Soc. Am. B. Vol. 22, No. 11,2417 (2005).
37. 林彥辰‘‘利用脈衝雷射蒸鍍法製備碲化鉍薄膜與兆赫波時域頻譜之研究’’國立交通大學電子物理系所碩士論文 (2012).
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