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博碩士論文 etd-0818103-142841 詳細資訊
Title page for etd-0818103-142841
論文名稱
Title
鎂鋰混合金屬錯何物對二氧化碳固定之研究
The Study of CO2 Fixation on The Magnesium-Lithium Mixed Metal Complexes
系所名稱
Department
化學系
Department of Chemistry
畢業學年期
Year, semester
91 學年度 第 2 學期
The spring semester of Academic Year 91
語文別
Language
英文
English
學位類別
Degree
碩士
Master
頁數
Number of pages
101
研究生
Author
陳欣億
Shin-Yi Chen
指導教授
Advisor
張祖辛
none
召集委員
Convenor
蔣燕南
none
口試委員
Advisory Committee
楊國清, 張宗仁
none; Chung-Cheng Chang
口試日期
Date of Exam
2003-07-28
繳交日期
Date of Submission
2003-08-18
關鍵字
Keywords
二氧化碳固定、鋰鎂化合物
CO2 Fixation, Mixed Metal Complexes
統計
Statistics
本論文已被瀏覽 5681 次，被下載 2060 次
The thesis/dissertation has been browsed 5681 times, has been downloaded 2060 times.
中文摘要
Mg(NPh2)2 與LiNR2 (R= SiMe3, NiPr, NiBu)反應皆得到相同產物，經由1H-NMR及X-ray單晶結構繞射解析證實此產物為[Mg(NPh2)3(THF)][Li(THF)4] ，二氧化碳與[Mg(NPh2)3(THF)] [Li(THF)4]反應得到含有四個鋰的化合物，經由1H-NMR， 13C-NMR， IR, ，X-ray單晶結構繞射解析證實此產物為Li4(O2CNPh2)4(THF)4。
Abstract
The reaction of Mg(NPh2)2 with LiNR2 (R= SiMe3, NiPr, NiBu) generated the same product, [Mg(NPh2)3(THF)][Li(THF)4] which was identified by 1H-NMR and X-ray crystallography. The magnesium-lithium mixed metal complex reacted with excess carbon dioxide in the ice bath to generate the tetralithium complex, Li4(O2CNPh2)4(THF)4 which was identified by 1H-NMR, 13C-NMR, IR, and X-ray crystallography.
目次 Table of Contents
Table of Contents
Abstract i
Table of Content ii
List of Figure iv
1. Experiment Section 01
1.1 Chemicals 01
1.2 Purification 02
1.3 Apparatus and Technique 03
1.4 Preparation 08
2. Introduction 14
2.1 Fixation of Carbon Dioxide 15
2.1.1 Natural Fixation 15
2.1.2 Industrial Fixation 16
2.1.3 Hydrogenation of Carbon Dioxide 19
2.2 Bonding Types of Metal-CO2 Complexes 21
2.2.1 Complexes with Adduct CO2 Ligands 25
2.2.2 Complexes with Bridging CO2 Ligands 29
2.3 Reactions of Main-Group Elements with CO2 36
2.4 Direct Insertion of CO2 to Bimetal Complexes 42
2.5 Aim of Our Research 49
3. Results and Discussion 50
3.1 Identification and X-ray Crystallography Analysis 50
3.1.1 Reaction of Mg(NPh2)2 with LiNiPr2 50
3.1.2 Reaction of [Mg(NPh2)3(THF)]─[Li (THF)4]+ with CO2 52
3.2 Discussion 59
4. Conclusion 63
5. Reference 64
6. 1H, 13C-NMR, IR-Spectrums 68
7. Appendix 71
參考文獻 References
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