本篇論文主要是探討三(膦-亞胺)胺配位子[N(N-P)3] 與過渡金屬化合物的配位反應研究。利用自組裝方式使[N(N-P)3]配位子與具有四面體配位的銅金屬原子和平面四方配位的鈀金屬原子進一步形成{N(N-P)3-[Cu]3-(P-N)3N}(BF4)3及{N(N-P)3-[Pd]3-(P-N)3N }(BF4)6的三核有機金屬籠型化合物。除此之外，我們也合成出N(N-P)3-[PdCl2]3的三核有機金屬化合物和N(N-P)3-[Os3(CO)10]3的三核有機金屬簇化合物，這些結構特殊的超分子化合物。

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目錄
頁數
第壹章 緒論
1.1 前言..................................................1
1.2 無機超分子結構時所運用的作用力........................2
1.3 半穩定性質............................................9
1.4 POOP和PSSP多重配位子之雙核金屬大環化合物.............12
1.5 TPST多重配位子之籠型化合物...........................15
1.6 研究動機.............................................18

第貳章 結果與討論
2.1 配位子N{CH2CH2N=CH(o-C6H4)PPh2}3(簡稱N(N-P)3N【1】
的製備...............................................20
2.2.1 N(N-P)3配位子【1】與CpCo(COD)的反應探討............25
2.2.2 N(N-P)3配位子【1】與CpCo(CO)2的反應探討............26
2.3 N(N-P)3-[PdCl2]3【2】的合成與鑑定....................28
2.4.1 [N(N-P)3-(Cu)3-(P-N)3N][BF4] 3【3】的合成..........32
2.4.2 N(N-P)3配位子與[Cu(NCMe)4][BF4]進行兩階段反應探討..37
2.4.3 N(N-P)3配位子與[Cu(NCMe)4][BF4]以1比1進行反應探討..42
2.5.1 [N(N-P)3-(Pd)3-(P-N)3N][BF4]6【4】的合成...........46
2.5.2 N(N-P)3配位子與[Pd(NCMe)4][BF4]2進行兩階段反應探討.52
2.6 N(N-P)3-[Os3(CO)10]3【5】的合成......................55
2.7 N(N-P)3配位子與Cp2Mo(CO)4的反應探討..................61

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