本研究旨在將光催化分解氣相污染物技術與活性碳紙纖濾網(ACCF)吸附技術加以結合，利用活性碳富集氣相污染物之特性，快速將氣相污染物吸附，再利用光催化分解技術更有效率的將氣相污染物予以分解。
本研究所選擇之氣相污染物為丙酮，選擇兩種市售TiO2光觸媒(光觸媒Ⅰ及光觸媒Ⅱ)以含浸法塗覆於活性碳紙纖，並採用批次式光催化氧化反應系統進行吸附反應和光催化反應。實驗探討之操作參數包括丙酮初始濃度(4.1~10.2 μM)、反應溫度(40℃~70℃)及水氣含量(以相對濕度%表示)(0~20%)。光催化反應器上方置放四支20W近紫外光燈管(λ=365 nm)為光源，內部則放置披覆TiO2之ACCF，丙酮則以氣密式注射針筒(gasket syringe)注入，進行批次光催化氧化反應實驗。反應物及產物分析係分別以氣相層析儀/電子捕捉偵測器(GC/ECD)、氣相層析儀/火燄離子加以偵測器配合甲烷轉換器(GC/FID-Methaneizer)偵測並定量之，最後進一步建立反應動力模式。
由光觸媒篩選之結果得知，本研究所採用之兩種光觸媒中，以光觸媒Ⅱ之光催化效應較佳，製備之光觸媒活性碳纖濾網之粒徑範圍介於20~70 nm，屬於奈米微粒，產物以CO和CO2為主，礦化率高達98%。另就操作參數實驗結果得知，提高丙酮初始濃度，不利於活性碳紙纖濾網吸附丙酮，但對於丙酮之反應速率影響不大；提高反應溫度，雖不利於ACCF之吸附，但整體而言有助於丙酮之光催化分解速率，對產物CO和CO2之生成和礦化率皆有幫助；水氣的添加會降低ACCF吸附丙酮之能力，並導致丙酮光催化分解效率略為降低，顯示水氣的存在會與丙酮造成競爭吸附而佔據光觸媒表面之活化位址，使光催化丙酮效率逐漸降低。因此，本研究顯示TiO2/ACPF可藉由活性碳紙纖之吸附能力，提高丙酮的質傳速度，提升光觸媒分解破壞效率及使用價值，並藉由光觸媒之催化分解，使活性碳紙纖不致吸附飽和而具長效性，且提升光觸媒處理效率，並能有效延長活性碳紙纖之使用時間。
此外，本研究應用相互競爭且反應之雙分子Langmuir- Hinshelwood (L-H)反應動力模式，建立丙酮之反應動力模式，模擬在不同反應溫度、丙酮初始濃度及水氣含量下，光催化氧化丙酮之反應情形模式推導，模擬結果顯示，實驗值與模擬值均相當吻合，同時也成功模擬光催化氧化丙酮反應速率。因此，氣相丙酮在TiO2表面的光催化反應速率可使用L-H 反應動力模式加以描述。

This study combined photocatalytic technology with activated carbon cellulose-paper filter (ACCF) adsorption to decompose gaseous pollutants. Gaseous pollutants were initially adsorbed by activated carbon and could be further decomposed by photocatalytic technology.
This study selected acetone (CH3COCH3) as gaseous pollutants. Two market available photocatalysts (photocatalystsⅠandⅡ) were coated on ACCF by impregnation to decompose acetone in a batch photocatlytic reactor. Operating parameters investigated in this study included initial acetone concentration (4.1~10.2 μM), reaction temperature (40~70℃), and water vapor (0~20 %). The incident UV light of 365 nm was irradiated by a 20-watt low-pressure mercury lamp placing above the batch photocatalytic reactor. The ACCF coated with TiO2 was placed at the center of the photocatalytic reactor. Acetone was injected into the reactor by a gasket syringe to conduct the photocatalytic tests. Reactants and products were analyzed quantitatively by a gas chromatography with an electron capture detector (GC/DCD) and a flame ionization detector followed by a methaneizer (GC/FID-Methaneizer). Finally, a Langmiur-Hinshewood (L-H) kinetic model was proposed to describe the rate of photocatalytic reaction.
Results obtained from the photocatalytic tests indicated that photocatalystⅡ was better than photocatalystⅠ for the decomposition of acetone. Experimental results indicated that the size range of self-produced TiO2 photocatalyst by sol-gel was 20~70 nm. The end products were mainly CO and CO2, which resulted in the mineralization ratio up to 98%. Results obtained from the operating parameter tests revealed that the increase of initial acetone concentration enhanced the amount of acetone adsorbed on ACCF, which however did not increase the reaction rate of acetone. Although the increase of reaction temperature could reduce the amount of acetone adsorbed on ACCF, the decomposition rate of acetone could be promoted, so as the yield rate and mineralization ratio of products (CO and CO2). The increase of water vapor could slightly decrease the amount of acetone adsorbed on ACCF. The competitive adsorption phenomenon between acetone and water molecules on active sites could decelerate the decomposion of acetone. Moreover, the ACCF would not be saturated since the adsorbed acetone could be further decomposed quickly by the photocatalysts, which made the TiO2/ACCF more effective on removing acetone and lasted longer than the conventional ACCF.
Finally, a modified bimolecular Langmuir-Hinshelwood kinetic model was developed to investigate the influences of initial acetone concentration reaction, temperature, and relative humidity on the promotion and inhibition for the photocatalytic oxidation of acetone. The modified L-H kinetic model could successfully simulate the photocatalytic reaction rate of acetone. Thus, the reaction rate of acetone over TiO2/ACCF could be described by the modified L-H kinetic model.

頁次
謝誌………………………………………………………………….. I
中文摘要…………………………………………………………….. II
英文摘要...………………………………………………………....... IV
目錄…….………………………………………….…………............ VI
表目錄..….………………………………………….……….............. IX
圖目錄….…………………………………………………………..... X
第一章　前言………………………………………………….……. 1-1
1-1 研究緣起……………………………………...……...…….. 1-1
1-2 研究目的…………………………………………..……….. 1-4
1-3 研究範圍…………………………………………..……….. 1-5
第二章　文獻回顧….………………………………………………. 2-1
2-1 光觸媒之發展趨勢及應用………………………..……….. 2-1
2-2 光催化反應原理及特性…………………...………………. 2-2
2-2-1 光催化反應基本原理…………………………………. 2-2
2-2-2 光觸媒表面吸附現象…………………………………. 2-6
2-3 光觸媒種類及特性…………………………….................... 2-8
2-3-1 光觸媒種類……………………………………………. 2-8
2-3-2 二氧化鈦結構及特性…………………………………. 2-10
2-3-3 二氧化鈦之製備方法…………………………………. 2-13
2-4 活性碳紙纖濾網…………………………………………… 2-17
2-4-1 活性碳紙纖濾網之製備及組成………………………. 2-17
2-4-2 活性碳紙纖濾網之特性…………………...………….. 2-17
2-5 活性碳及二氧化鈦之協同作用.…………………..………. 2-19
2-6 影響光催化反應參數……………………………………… 2-20
2-6-1 光強度的影響……………………………….………… 2-20
2-6-2 溫度的影響……………………………………………. 2-21
2-6-3 水氣含量的影響………………………………………. 2-22
2-7 丙酮之特性及危害……………………………………….... 2-24
2-8 光催化反應動力模式……………………………………… 2-25
2-8-1 光催化反應動力步驟…………………………………. 2-25
2-8-2 等溫吸附線……………………………………............. 2-27
2-8-3 反應動力模式……………………………………......... 2-28
第三章　研究方法………………………………………………….. 3-1
3-1 實驗材料及製備方法…………………………………….... 3-1
3-1-1 實驗材料………………………………………………. 3-1
3-1-2 二氧化鈦光觸媒塗覆方法……………………………. 3-4
3-2 實驗設備…………………………………………………… 3-5
3-2-1 光催化反應系統………………………………………. 3-5
3-2-2 反應物及產物分析系統………………………………. 3-6
3-3 光催化分解實驗規劃……………………………………… 3-6
3-3-1 操作參數及範圍………………………………………. 3-6
3-3-2 反應器測漏測試………………………………………. 3-7
3-3-3 均相光反應測試…….………………………………… 3-7
3-3-4 不照光紙纖吸附測試…………………………………. 3-8
3-3-5 不照光載體吸附試……………………………………. 3-8
3-4 分析方法…………………………………………………… 3-8
3-4-1 二氧化鈦特性之分析…………………………………. 3-8
3-4-2 反應物及產物分析……………………………………. 3-9
3-4-3 品保與品管…………..………………………………... 3-11
第四章　結果與討論….…...................................………………….. 4-1
4-1 光觸媒基本特性分析結果………………………………… 4-1
4-1-1 表面結構分析結果……………………………………. 4-1
4-1-2 比表面積分析結果……………………………………. 4-5
4-1-3 晶相分析結果…………………………………………. 4-5
4-2 實驗系統測試結果…………………...……………………. 4-8
4-2-1 反應器測漏測試結果…………………………………. 4-9
4-2-2 均相光反應測試結果……………………….………… 4-9
4-2-3 不照光反應器吸附測試結果…………………………. 4-11
4-2-4 不照光活性碳紙纖吸附測試結果…………..………... 4-11
4-2-5 不同載體對於丙酮吸附與光催化作用測試結果……. 4-12
4-3 操作參數對光催化分解丙酮之影響…………………….... 4-13
4-3-1 丙酮初始濃度對光催化分解丙酮之影響……….…… 4-13
4-3-2 反應溫度對光催化分解丙酮之影響…………….…… 4-21
4-3-3 水氣含量對光催化分解丙酮之影響…………….…… 4-29
4-4 產物分析結果……………...……………………….……… 4-37
4-4-1 操作條件對光催化分解丙酮產物之影響………….… 4-37
4-4-2 產物之碳平衡…………...…………………….………. 4-40
4-5 光催化反應動力模式之解析…………...………….……… 4-43
第五章　結論與建議……………………..………………………… 5-1
5-1 結論………………………...……………………………... 5-1
5-2 建議……………………………………………………….. 5-3
參考文獻........................................................................................ R-1
附錄A 反應物及產物之分析圖譜……………………………….. A-1
附錄B 反應物及產物之檢量線………………………………….. B-1

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