含磷硫多牙配位基在化學上多用於催化及酵素模擬上。而本文使
用四牙配位基三-3-三甲基矽烷-2-硫酚磷基(H3L3)和三-2-硫酚磷基
(H3L1)，三牙配位基二-2-硫酚磷苯基(H2L2)，來和一系列的鍺與錫
金屬鹽類反應來作相關之研究。
在本論文中探討，H3L1配位基和四氯化錫反應，我們得到三錫橋接甲氧基及氧基的特殊的錯合物；H2L2配位基和四氯化鍺和四氯化錫反應，則得到具有ML2型態的晶體。H3L3配位基方面，除了光譜鑑定外，也得到鍺金屬錯合物的結晶，其結果為五配位雙三角錐結構。

The polydentate ligands containing both thiolato and phosphino groups have been used in catalysis and enzyme mimetic studies. We have synthesized two tetradentate thiophosphine ligands : tris(2-thiophenyl)-
phosphine（H3L1） and tris(3-trimethylsilyl-2-thiophenyl)phosphine (H3L3) and one tridentate thiophosphine ligand (bis(2-thiophenyl)-
phenylphosphine（H2L2）. These ligands formed a series of germanium and tin metal complexes.
We are thus exploring a range of syntheses of tin and germanium complexes. The ligand H3L1 react with SnCl4 to give trimeric tin units with bridging methoxyl group and oxo group. The ligand H2L2 react with SnCl4 or GeCl4 to give ML2 type complexes. H3L3 with germanium and tin metal complexes were synthesized and characterised by NMR spectra and mass spectra. We also obtained crystal structure of complexes GeCl(L3) and GeEt(L3). The structure was trigonal bipyramidal.

謝誌 i
授權書 ii
提要 iii
目錄 v
圖目錄 vii
表目錄 ix
附錄 x
壹、 緒論 1
一、前言 1
二、含

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