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博碩士論文 etd-0908109-155557 詳細資訊
Title page for etd-0908109-155557
論文名稱
Title
切片式螢光成像:研究光誘發動態過程之通用方法
Sliced fluorescence imaging: a versatile method to study photo-induced dynamic processes
系所名稱
Department
化學系
Department of Chemistry
畢業學年期
Year, semester
98 學年度 第 1 學期
The fall semester of Academic Year 98
語文別
Language
英文
English
學位類別
Degree
博士
Ph.D.
頁數
Number of pages
81
研究生
Author
陳昱煒
Yu-wei Chen
指導教授
Advisor
陳國美
Kuo-mei Chen
召集委員
Convenor
劉國平
Kopin Liu
口試委員
Advisory Committee
林金全, 蔣昭明, 丁尚武
King-chuen Lin; Chao-ming Chiang; Shang-wu Ding
口試日期
Date of Exam
2009-08-26
繳交日期
Date of Submission
2009-09-08
關鍵字
Keywords
切片式螢光成像
Sliced fluorescence imaging
統計
Statistics
本論文已被瀏覽 5804 次，被下載 1330 次
The thesis/dissertation has been browsed 5804 times, has been downloaded 1330 times.
中文摘要
為了降低在光誘發實驗中柱狀陣列光解中心所造成的影像模糊，建立一套新穎螢光成像實驗方法，研究流動環境中光解動態學及碰撞鬆弛過程。本實驗採用雷射誘發螢光偵測方法執行光解碎片的切片式成像技術。迥異於傳統步驟，光解雷射沿成像偵測器的觀測方向射入，並於偵測器前安置一塊擋板阻擋光解雷射。垂直於光解雷射方向的切片式影像，就等於來自於單一光解中心的光解產物螢光影像之二維投影。為闡明切片式螢光成像之廣泛適用性，本論文報導碘化氰光解產生之氰基光解碎片，具狀態選定螢光成像實驗結果。
Abstract
To reduce the image blurring which originates from contributions of a cylindrical array of photolysis events in a photo-induced experiment, a variant of fluorescence imaging techniques has been developed to study photodissociation dynamics and collisional relaxation processes in the bulk. The experimental arrangement utilizes sliced imaging techniques of photofragments by the laser-induced fluorescence detection scheme. An unconventional procedure is employed to guide the photolysis laser in the viewing direction of the imaging detector with a proper obstruction. The sliced image in the direction perpendicular to the photolysis laser is equivalent to a two-dimensional projection of the fluorescence image of photoproducts from a single photolysis center. Experimental images of state-selected CN photofragments from the ICN photodissociation are presented to illustrate the versatility of the present method.
目次 Table of Contents
Chapter 1. Introduction 01
1. 1 Background 01
1. 2 Time-of-flight mass spectrometry 03
1. 3 Doppler spectroscopy 07
1. 4 Ion imaging 09
1. 5 Fluorescence imaging 12
Chapter 2. Photodissociation of ICN 14
Chapter 3. Sliced fluorescence imaging experiments 18
3. 1 Introduction 18
3. 2 Design concept 21
3. 3 Apparatus setup and experimental procedures 23
3. 4 Imaging processing and convolution fitting 26
3. 5 Results 32
3. 6 Discussion 36


Chapter 4. Conclusions and prospective 41
References 45
Figures 56
Table 1 76
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